面向金属离子电池研究的固体核磁共振和电子顺磁共振方法

doi:10.3866/PKU.WHXB201902019

摘要/Abstract

摘要：

电池，尤其是锂离子电池的快速发展极大改变了我们的生活。从移动电子设备到新能源汽车再到电网储能，电池应用于多个领域且目前在能量密度和功率密度方面难以被取代。电池技术的向前发展要求我们对其电化学反应机理有完整的认识，这需要来自不同领域研究人员的交叉碰撞。磁共振波谱技术包括核磁共振波谱(NMR)和电子顺磁共振波谱(EPR)，前者适合于研究Li、Na、P、O等电池材料中常见的轻元素，后者适合于研究Co、Mn、Fe、V等电池材料中常见的过渡金属。加上它们具有对样品无损、对结晶度无要求、能够定量分析等优点，NMR和EPR在过去三十年的电池研究中不断进步，日益成为电池表征的重要角色。本文从磁共振方法的角度出发，首先概述了固体NMR和EPR中的主要相互作用及其哈密顿表达形式，接着概述了固体NMR和EPR常用的重要方法及其在金属离子电池研究领域的代表性应用。本文有助于让我们直观地了解磁共振技术本身在金属离子电池研究领域的重要价值，并有望为解决利用固体NMR和EPR进行电池研究的过程遇到的困难提供指导。

关键词: 固体核磁共振, 电子顺磁共振, 锂离子电池, 钠离子电池, 充放电机理, 构效关系, 局域结构

Abstract:

The rapid development of batteries, especially lithium-ion batteries, has dramatically changed our daily lives. From portable electronics to electric vehicles and smart grids, batteries are extensively used in many fields and are difficult to be replaced in terms of their excellent energy and power densities. The advancement of battery technology requires the thorough understanding of electrochemical reaction mechanisms, which strongly depends on the collaboration of researchers from different fields. Magnetic resonance spectroscopy includes the important techniques of nuclear magnetic resonance (NMR) and electron paramagnetic resonance (EPR), and the former is suitable for studying light elements commonly found in batteries including Li, Na, P and O, while the latter is suitable for studying heavier transition metals such as Co, Mn, Fe and V. In addition, NMR and EPR are capable of quantitatively analysis in a nondestructive manner regardless of sample crystallinity. Hence, NMR and EPR spectroscopies have allowed for significant research progress and have become increasingly important for battery research over the past three decades. Herein, we will provide our perspective of magnetic resonance methods and first summarize the main interactions and the Hamiltonian forms of solid-state NMR and EPR (dipole-dipole interaction, electric quadrupole interaction, chemical shift, and hyperfine interaction). Subsequently, we summarize the important and frequently-used methods of solid-state NMR and EPR spectroscopies and introduce their representative applications in metal ion battery research (mainly lithium- and sodium-ion batteries). Specifically, we introduce the basic principles and representative applications of (ⅰ) MQMAS (multiple-quantum magic angle spinning), (ⅱ) pjMATPASS (MAT = magic-angle turning, PASS = phase-adjusted sideband separation, and pj = projection), (ⅲ) WURST-CPMG (WURST = wide band uniform rate smooth truncation, CPMG = Carr-Purcell Meiboom-Gil), (ⅳ) 2D homonuclear correlation and exchange (2D EXSY), (ⅴ) 2D homonuclear correlation based on dipole coupling (i.e. RFDR), (ⅵ) perpendicular mode EPR, (ⅶ) parallel mode EPR, (ⅷ) in situ NMR, and (ⅸ) in situ EPR. In addition, we briefly introduce representative applications of 2D heteronuclear correlation (i.e. CP-HETCOR), pulsed field gradient NMR, spin-lattice relaxation (SLR), spin alignment echo (SAE), DFT calculations, and dynamic nuclear polarization (DNP). Previous reviews regarding the application of magnetic resonance technology in battery research are almost all reported in terms of the classification of battery materials. In other words, they are written from the perspective of applications in cathode, anode, and electrolyte research. Herein, we summarize from the perspective of solid-state NMR and EPR methods, which may be beneficial for the readers to fully understand the value of these important technologies. We believe this review can serve as a guide to solve challenges related to using solid-state NMR and EPR spectroscopies in battery research.

Key words: Solid-state NMR, Electron paramagnetic resonance, Lithium-ion battery, Sodium-ion battery, Charge-discharge mechanism, Structure-function ralationship, Local structure

李超, 沈明, 胡炳文. 面向金属离子电池研究的固体核磁共振和电子顺磁共振方法[J]. 物理化学学报, 2020, 36(4), 1902019. doi: 10.3866/PKU.WHXB201902019

Chao Li, Ming Shen, Bingwen Hu. Solid-State NMR and EPR Methods for Metal Ion Battery Research[J]. Acta Physico-Chimica Sinica 2020, 36(4), 1902019. doi: 10.3866/PKU.WHXB201902019

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB201902019

https://www.whxb.pku.edu.cn/CN/Y2020/V36/I4/1902019

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参考文献 136

1	Li M. ; Lu J. ; Chen Z. ; Amine K. Adv. Mater. 2018, 30, 1800561. doi: 10.1002/adma.201800561
2	Larcher D. ; Tarascon J. M. Nat. Chem. 2015, 7, 19. doi: 10.1038/nchem.2085
3	Goodenough J. B. ; Park K. S. J. Am. Chem. Soc. 2013, 135, 1167. doi: 10.1021/ja3091438
4	Yang Z. ; Zhang W. ; Shen Y. ; Yuan L. X. ; Huang Y. H. Acta Phys. -Chim. Sin. 2016, 32, 1062. doi: 10.3866/PKU.WHXB201603231
	杨泽; 张旺; 沈越; 袁利霞; 黄云辉. 物理化学学报, 2016, 32, 1062. doi: 10.3866/PKU.WHXB201603231
5	Goodenough J. B. Energy Storage Mater. 2015, 1, 158. doi: 10.1016/j.ensm.2015.07.001
6	Tarascon J. M. Nat. Chem. 2010, 2, 510. doi: 10.1038/nchem.680
7	Choi J. W. ; Aurbach D. Nat. Rev. Mater. 2016, 1, 16013. doi: 10.1038/natrevmats.2016.13
8	Slater M. D. ; Kim D. ; Lee E. ; Johnson C. S. Adv. Funct. Mater. 2013, 23, 947. doi: 10.1002/adfm.201200691
9	Fang C. ; Huang Y. ; Zhang W. ; Han J. ; Deng Z. ; Cao Y. ; Yang H. Adv. Energy Mater. 2016, 6, 1501727. doi: 10.1002/aenm.201501727
10	Wang P. F. ; You Y. ; Yin Y. X. ; Guo Y. G. Adv. Energy Mater. 2018, 8, 1701912. doi: 10.1002/aenm.201701912
11	Fang Y. J. ; Chen Z. X. ; Ai X. P. ; Yang H. X. ; Cao Y. L. Acta Phys. -Chim. Sin. 2017, 33, 211. doi: 10.3866/PKU.WHXB201610111
	方永进; 陈重学; 艾新平; 杨汉西; 曹余良. 物理化学学报, 2017, 33, 211. doi: 10.3866/PKU.WHXB201610111
12	Wu X. ; Leonard D. P. ; Ji X. Chem. Mater. 2017, 29, 5031. doi: 10.1021/acs.chemmater.7b01764
13	Li C. ; Hu X. ; Hu B. Electrochim. Acta 2017, 253, 439. doi: 10.1016/j.electacta.2017.09.090
14	Zhang Z. ; Dong S. ; Cui Z. ; Du A. ; Li G. ; Cui G. Small Methods 2018, 2, 1800020. doi: 10.1002/smtd.201800020
15	Wang M. ; Jiang C. ; Zhang S. ; Song X. ; Tang Y. ; Cheng H. M. Nat. Chem. 2018, 10, 667. doi: 10.1038/s41557-018-0045-4
16	Lin M. C. ; Gong M. ; Lu B. ; Wu W. ; Wang D. Y. ; Guan. M. ; Angell M. ; Chen C. ; Yang. J. ; Hwang B. J. ; et al Nature 2015, 520, 324. doi: 10.1038/nature14340
17	Kim D. J. ; Yoo D. J. ; Otley M. T. ; Prokofjevs A. ; Pezzato C. ; Owczarek M. ; Lee S. J. ; Choi J. W. ; Stoddart J. F. Nat. Energy 2018, 4, 51. doi: 10.1038/s41560-018-0291-0
18	Grey C. P. ; Tarascon J. M. Nat. Mater. 2017, 16, 45. doi: 10.1038/nmat4777
19	Lu J. ; Wu T. ; Amine K. Nat. Energy 2017, 2, 17011. doi: 10.1038/nenergy.2017.11
20	Pecher O. ; Carretero-González J. ; Griffith K. J. ; Grey C. P. Chem. Mater. 2017, 29, 213. doi: 10.1021/acs.chemmater.6b03183
21	Grey C. P. ; Dupre N. Chem. Rev. 2004, 104, 4493. doi: 10.1021/cr020734p
22	Zhong G. ; Liu Z. ; Wang D. ; Li Q. ; Fu R. ; Yang. Y. J. Electrochem. 2016, 22, 231. doi: 10.13208/j.electrochem.151246
	钟贵明; 刘子庚; 王大为; 李琦; 傅日强; 杨勇. 电化学, 2016, 22, 231. doi: 10.13208/j.electrochem.151246
23	Duer, M. J. Solid-State Nmr Spectroscopy: Principles and Applications; Blackwell Sci., London, 2002.
24	Pigliapochi R. ; Pell A. J. ; Seymour I. D. ; Grey C. P. ; Ceresoli D. ; Kaupp M. Phys. Rev. B 2017, 95, 054412. doi: 10.1103/PhysRevB.95.054412
25	Frydman L. ; Harwood J. S. J. Am. Chem. Soc. 1995, 117, 5367. doi: 10.1021/ja00124a023
26	Hrobárik P. ; Reviakine R. ; Arbuznikov A. V. ; Malkina O. L. ; Malkin V. G. ; Köhler F. H. ; Kaupp M. J. Chem. Phys. 2007, 126, 024107. doi: 10.1063/1.2423003
27	Amoureux J. P. ; Fernandez C. ; Steuernagel S. J. Magn. Reson. A 1996, 123, 116. doi: 10.1006/jmra.1996.0221
28	Gan Z. ; Kwak H. T. J. Magn. Reson. 2004, 168, 346. doi: 10.1016/j.jmr.2004.03.021
29	Gan Z. J. Am. Chem. Soc. 2000, 122, 3242. doi: 10.1021/ja9939791
30	Morita R. ; Gotoh K. ; Fukunishi M. ; Kubota K. ; Komaba S. ; Nishimura N. ; Yumura T. ; Deguchi K. ; Ohki S. ; Shimizu T. ; et al J. Mater. Chem. A 2016, 4, 13183. doi: 10.1039/C6TA04273B
31	Li C. ; Shen M. ; Hu B. ; Lou X. ; Zhang X. ; Tong W. ; Hu B. J. Mater. Chem. A 2018, 6, 8340. doi: 10.1039/C8TA00568K
32	Li C. ; Shen M. ; Lou X. ; Hu B. J. Phys. Chem. C 2018, 122, 27224. doi: 10.1021/acs.jpcc.8b09151
33	Reeve Z. E. M. ; Franko C. J. ; Harris K. J. ; Yadegari H. ; Sun X. ; Goward G. R. J. Am. Chem. Soc. 2017, 139, 595. doi: 10.1021/jacs.6b11333
34	Hung I. ; Zhou L. ; Pourpoint F. ; Grey C. P. ; Gan Z. J. Am. Chem. Soc. 2012, 134, 1898. doi: 10.1021/ja209600m
35	Clement R. J. ; Pell A. J. ; Middlemiss D. S. ; Strobridge F. C. ; Miller J. K. ; Whittingham M. S. ; Emsley L. ; Grey C. P. ; Pintacuda G. J. Am. Chem. Soc. 2012, 134, 17178. doi: 10.1021/ja306876u
36	Li X. ; Tang M. ; Feng X. ; Hung I. ; Rose A. ; Chien P. H. ; Gan Z. ; Hu Y. Y. Chem. Mater. 2017, 29, 8282. doi: 10.1021/acs.chemmater.7b02589
37	Xu J. ; Lee D. H. ; Clément R. J. ; Yu X. ; Leskes M. ; Pell A. J. ; Pintacuda G. ; Yang X. Q. ; Grey C. P. ; Meng Y. S. Chem. Mater. 2014, 26, 1260. doi: 10.1021/cm403855t
38	Clément R. J. ; Xu J. ; Middlemiss D. S. ; Alvarado J. ; Ma C. ; Meng Y. S. ; Grey C. P. J. Mater. Chem. A 2017, 5, 4129. doi: 10.1039/c6ta09601h
39	Hung I. ; Gan Z. J. Magn. Reson. 2010, 204, 150. doi: 10.1016/j.jmr.2010.02.004
40	Gan Z. J. Am. Chem. Soc. 1992, 114, 8307. doi: 10.1021/ja00047a062
41	Antzutkin O. N. ; Shekar S. C. ; Levitt M. H. J. Magn. Reson., Series A 1995, 115, 7. doi: 10.1006/jmra.1995.1142
42	Lee J. ; Kitchaev D. A. ; Kwon D. H. ; Lee C. W. ; Papp J. K. ; Liu Y. S. ; Lun Z. ; Clément R. ; Shi T. ; McCloskey B. D. ; et al Nature 2018, 556, 185. doi: 10.1038/s41586-018-0015-4
43	Lee J. ; Urban A. ; Li X. ; Su D. ; Hautier G. ; Ceder G. Science 2014, 343, 519. doi: 10.1126/science.1246432
44	Xu S. ; Wang G. ; Biswal B. P. ; Addicoat M. ; Paasch S. ; Sheng W. ; Zhuang X. ; Brunner E. ; Heine T. ; Berger R. ; et al Angew. Chem. Int. Ed. 2019, 58, 849. doi: 10.1002/anie.201812685
45	O'Dell L. A. ; Schurko R. W. Chem. Phys. Lett. 2008, 464, 97. doi: 10.1016/j.cplett.2008.08.095
46	MacGregor A. W. ; O'Dell L. A. ; Schurko R. W. J. Magn. Reson. 2011, 208, 103. doi: 10.1016/j.jmr.2010.10.011
47	Hung I. ; Gan Z. J. Magn. Reson. 2010, 204, 256. doi: 10.1016/j.jmr.2010.03.001
48	Harris K. J. ; Reeve Z. E. M. ; Wang D. ; Li X. ; Sun X. ; Goward G. R. Chem. Mater. 2015, 27, 3299. doi: 10.1021/acs.chemmater.5b00323
49	Peng B. ; Shen M. ; Amoureux J. P. ; Hu B. Solid State Nucl. Magn. Reson. 2016, 78, 1. doi: 10.1016/j.ssnmr.2016.05.002
50	Takegoshi K. ; Nakamura S. ; Terao T. J. Chem. Phys. 2003, 118, 2325. doi: 10.1063/1.1534105
51	Takegoshi K. ; Nakamura S. ; Terao T. Chem. Phys. Lett. 2001, 344, 631. doi: 10.1016/S0009-2614(01)00791-6
52	Hu B. ; Lafon O. ; Trébosc J. ; Chen Q. ; Amoureux J. P. J. Magn. Reson. 2011, 212, 320. doi: 10.1016/j.jmr.2011.07.011
53	Hu B. ; Trébosc J. ; Lafon O. ; Chen Q. ; Masuda Y. ; Takegoshi K. ; Amoureux J. P. ChemPhysChem 2012, 13, 3585. doi: 10.1002/cphc.201200548
54	Cahill L. S. ; Chapman R. P. ; Britten J. F. ; Goward G. R. J. Phys. Chem. B 2006, 110, 7171- 7177. doi: 10.1021/jp057015+
55	Langer J. ; Smiley D. L. ; Bain A. D. ; Goward G. R. ; Wilkening M. J. Phys. Chem. C 2016, 120, 3130. doi: 10.1021/acs.jpcc.5b09894
56	Bain A. D. Prog. Nucl. Magn. Reson. Spectrosc. 2003, 43, 63. doi: 10.1016/j.pnmrs.2003.08.001
57	Davis L. J. M. ; He X. J. ; Bain A. D. ; Goward G. R. Solid State Nuclear Magnetic Resonance 2012, 42, 26. doi: 10.1016/j.ssnmr.2012.01.002
58	Davis L. J. M. ; Heinmaa I. ; Goward G. R. Chem. Mater. 2010, 22, 769. doi: 10.1021/cm901402u
59	Smiley D. L. ; Davis L. J. M. ; Goward G. R. J. Phys. Chem. C 2013, 117, 24181. doi: 10.1021/jp407510h
60	Hu Y. Y. ; Liu Z. ; Nam K. W. ; Borkiewicz O. J. ; Cheng J. ; Hua X. ; Dunstan M. T. ; Yu X. ; Wiaderek K. M. ; Du L. S. ; et al Nat. Mater. 2013, 12, 1130. doi: 10.1038/nmat3784
61	Kuhn A. ; Dupke S. ; Kunze M. ; Puravankara S. ; Langer T. ; Pöttgen R. ; Winter M. ; Wiemhöfer H. D. ; Eckert H. ; Heitjans P. J. Phys. Chem. C 2014, 118, 28350. doi: 10.1021/jp505386u
62	Smiley D. L. ; Goward G. R. Chem. Mater. 2016, 28, 7645. doi: 10.1021/acs.chemmater.6b02539
63	Zheng J. ; Tang M. ; Hu Y. Y. Angew. Chem. Int. Ed. 2016, 55, 12538. doi: 10.1002/anie.201607539
64	van Wullen L. ; Echelmeyer T. ; Meyer H. W. ; Wilmer D. Phys. Chem. Chem. Phys. 2007, 9, 3298. doi: 10.1039/b703179c
65	Wang D. ; Zhong G. ; Pang W. K. ; Guo Z. ; Li Y. ; McDonald M. J. ; Fu R. ; Mi J. X. ; Yang Y. Chem. Mater. 2015, 27, 6650. doi: 10.1021/acs.chemmater.5b02429
66	Liu Q. ; Li C. ; Wei L. ; Shen M. ; Yao Y. ; Hu B. ; Chen Q. Polymer 2014, 55, 5454. doi: 10.1016/j.polymer.2014.08.055
67	Cadars S. ; Sein J. ; Duma L. ; Lesage A. ; Pham T. N. ; Baltisberger J. H. ; Brown S. P. ; Emsley L. J. Magn. Reson. 2007, 188, 24. doi: 10.1016/j.jmr.2007.05.016
68	Fayon F. ; Le Saout G. ; Emsley L. ; Massiot D. Chem. Commun. 2002, 1702. doi: 10.1039/B205037B
69	Feike M. ; Demco D. E. ; Graf R. ; Gottwald J. ; Hafner S. ; Spiess H. W. J. Magn. Reson., Series A 1996, 122, 214. doi: 10.1006/jmra.1996.0197
70	Bennett A. E. ; Griffin R. G. ; Ok J. H. ; Vega S. J. Chem. Phys. 1992, 96, 8624. doi: 10.1063/1.462267
71	Shen M. ; Hu B. ; Lafon O. ; Trébosc J. ; Chen Q. ; Amoureux J. P. J. Magn. Reson. 2012, 223, 107. doi: 10.1016/j.jmr.2012.07.013
72	Nishiyama Y. ; Zhang R. ; Ramamoorthy A. J. Magn. Reson. 2014, 243, 25. doi: 10.1016/j.jmr.2014.03.004
73	Wang Q. ; Hu B. ; Lafon O. ; Trébosc J. ; Deng F. ; Amoureux J. P. J. Magn. Reson. 2009, 200, 251. doi: 10.1016/j.jmr.2009.07.009
74	Hu B. ; Wang Q. ; Lafon O. ; Trébosc J. ; Deng F. ; Amoureux J. P. J. Magn. Reson. 2009, 198, 41. doi: 10.1016/j.jmr.2009.01.002
75	Wang Q. ; Hu B. ; Fayon F. ; Trébosc J. ; Legein C. ; Lafon O. ; Deng F. ; Amoureux J. P. Phys. Chem. Chem. Phys. 2009, 11, 10391. doi: 10.1039/B914468D
76	Messinger R. J. ; Ménétrier M. ; Salager E. ; Boulineau A. ; Duttine M. ; Carlier D. ; Mba J. M. A. ; Croguennec L. ; Masquelier C. ; Massiot D. ; et al Chem. Mater. 2015, 27, 5212. doi: 10.1021/acs.chemmater.5b01234
77	Michan A. L. ; Divitini G. ; Pell A. J. ; Leskes M. ; Ducati C. ; Grey C. P. J. Am. Chem. Soc. 2016, 138, 7918. doi: 10.1021/jacs.6b02882
78	Michan A. L. ; Leskes M. ; Grey C. P. Chem. Mater. 2016, 28, 385. doi: 10.1021/acs.chemmater.5b04408
79	Neuberger S. ; Culver S. P. ; Eckert H. ; Zeier W. G. ; Auf der Gunne J. S. Dalton Trans. 2018, 47, 11691. doi: 10.1039/c8dt02619j
80	Pecquenard B. ; Gourier D. ; Baffier N. Solid State Ionics 1995, 78, 287. doi: 10.1016/0167-2738(95)00099-R
81	Massarotti V. ; Capsoni D. ; Bini M. ; Azzoni C. B. ; Paleari A. J. Solid State Chem. 1997, 128, 80. doi: 10.1006/jssc.1996.7158
82	Stoyanova R. ; Gorova M. ; Zhecheva E. J. Phys. Chem. Solids 2000, 61, 609. doi: 10.1016/S0022-3697(99)00244-9
83	Sathiya M. ; Rousse. G. ; Ramesha K. ; Laisa C. P. ; Vezin H. ; Sougrati M. T. ; Doublet M. L. ; Foix D. ; Gonbeau D. ; Walker W. ; et al Nat. Mater. 2013, 12, 827. doi: 10.1038/nmat3699
84	Liao Y. ; Li C. ; Lou X. ; Hu X. ; Ning Y. ; Yuan F. ; Chen B. ; Shen M. ; Hu B. Electrochimica Acta 2018, 271, 608. doi: 10.1016/j.electacta.2018.03.100
85	Li C. ; Lou X. ; Shen M. ; Hu X. ; Yan W. ; Zou Y. ; Tong W. ; Hu B. Energy Storage Materials 2017, 7, 195. doi: 10.1016/j.ensm.2017.02.002
86	Li C. ; Lou X. ; Yang Q. ; Zou Y. ; Hu B. Chem. Eng. J. 2017, 326, 10008. doi: 10.1016/j.cej.2017.06.048
87	Ning Y. ; Lou X. ; Li C. ; Hu X. ; Hu B. Chem. -Euro. J. 2017, 23, 15984. doi: 10.1002/chem.201703077
88	Hendrich M. P. ; Debrunner P. G. Biophys. J. 1989, 56, 489. doi: 10.1016/S0006-3495(89)82696-7
89	Petasis D. T. ; Hendrich M. P. Methods in Enzymology 2015, 563, 171. doi: 10.1016/bs.mie.2015.06.025
90	Chevallier F. ; Letellier M. ; Morcrette M. ; Tarascon J. M. ; Frackowiak E. ; Rouzaud J. N. ; Bexguin F. Electrochem. Solid-State Lett. 2003, 6, A225. doi: 10.1149/1.1612011
91	Poli F. ; Wong A. ; Kshetrimayum J. S. ; Monconduit L. ; Letellier M. Chem. Mater. 2016, 28, 1787. doi: 10.1021/acs.chemmater.5b04802
92	Shimoda K. ; Murakami M. ; Komatsu H. ; Arai H. ; Uchimoto Y. ; Ogumi Z. J. Phys. Chem. C 2015, 119, 13472. doi: 10.1021/acs.jpcc.5b03273
93	Jung H. ; Allan P. K. ; Hu Y. Y. ; Borkiewicz O. J. ; Wang X. L. ; Han W. Q. ; Du L. S. ; Pickard C. J. ; Chupas P. J. ; Chapman K. W. ; et al Chem. Mater. 2015, 27, 1031. doi: 10.1021/cm504312x
94	Bayley P. M. ; Trease N. M. ; Grey C. P. J. Am. Chem. Soc. 2016, 138, 1955. doi: 10.1021/jacs.5b12423
95	Feng X. ; Tang M. ; O'Neill S. ; Hu Y. Y. J. Mater. Chem. A 2018, 6, 22240. doi: 10.1039/c8ta05433a
96	Letellier M. ; Chevallier F. ; Béguin F. J. Phys. Chem. Solids 2006, 67, 1228. doi: 10.1016/j.jpcs.2006.01.088
97	Liu Z. ; Hu Y. Y. ; Dunstan M. T. ; Huo H. ; Hao X. ; Zou H. ; Zhong G. ; Yang Y. ; Grey C. P. Chem. Mater. 2014, 26, 2513. doi: 10.1021/cm403728w
98	Salager E. ; Kanian V. S. ; Sathiya M. ; Tang M. ; Leiche J. B. ; Melin P. ; Wang Z. ; Vezin H. ; Bessada C. ; Deschamps M. ; et al Chem. Mater. 2014, 26, 7009. doi: 10.1021/cm503280s
99	Shimoda K. ; Murakami M. ; Takamatsu D. ; Arai H. ; Uchimoto Y. ; Ogumi Z. Electrochim. Acta 2013, 108, 343. doi: 10.1016/j.electacta.2013.06.120
100	Stratford J. M. ; Allan P. K. ; Pecher O. ; Chater P. A. ; Grey C. P. Chem Commun 2016, 52, 12430. doi: 10.1039/c6cc06990h
101	Key B. ; Bhattacharyya R. ; Morcrette M. ; Seznéc V. ; Tarascon J. M. ; Grey C. P. J. Am. Chem. Soc. 2009, 131, 9239. doi: 10.1021/ja8086278
102	Zhou L. ; Leskes M. ; Liu T. ; Grey C. P. Angew. Chem. Int. Ed. 2015, 54, 14782. doi: 10.1002/anie.201507632
103	Poli F. ; Kshetrimayum J. S. ; Monconduit L. ; Letellier M. Electrochem. Commun. 2011, 13, 1293. doi: 10.1016/j.elecom.2011.07.019
104	Sathiya M. ; Leriche J. B. ; Salager E. ; Gourier D. ; Tarascon J. M. ; Vezin H. Nat. Commun. 2015, 6, 6276. doi: 10.1038/ncomms7276
105	Tang M. ; Dalzini A. ; Li X. ; Feng X. ; Chien P. H. ; Song L. ; Hu Y. Y. J. Phys. Chem. Lett. 2017, 8, 4009. doi: 10.1021/acs.jpclett.7b01425
106	Wandt J. ; Marino C. ; Gasteiger H. A. ; Jakes P. ; Eichel R. A. ; Granwehr J. Energy Environ. Sci. 2015, 8, 1358. doi: 10.1039/c4ee02730b
107	Wandt J. ; Jakes P. ; Granwehr J. ; Eichel R. A. ; Gasteiger H. A. Mater. Today 2018, 21, 231. doi: 10.1016/j.mattod.2017.11.001
108	Pines A. ; Gibby M. G. ; Waugh J. S. J. Chem. Phys. 1973, 59, 569. doi: 10.1063/1.1680061
109	Hartmann S. R. ; Hahn E. L. Phys. Rev. 1962, 128, 2042. doi: 10.1103/PhysRev.128.2042
110	Lesage A. ; Emsley L. J. Magn. Reson. 2001, 148, 449. doi: 10.1006/jmre.2000.2249
111	Wang Q. ; Trébosc J. ; Li Y. ; Xu J. ; Hu B. ; Feng N. ; Chen Q. ; Lafon O. ; Amoureux J. P. ; Deng F. Chem. Commun. 2013, 49, 6653. doi: 10.1039/C3CC42961J
112	Trebosc J. ; Hu B. ; Amoureux J. P. ; Gan Z. J. Magn. Reson. 2007, 186, 220. doi: 10.1016/j.jmr.2007.02.015
113	Gan Z. J. Magn. Reson. 2007, 184, 39. doi: 10.1016/j.jmr.2006.09.016
114	Hu B. ; Trébosc J. ; Amoureux J. P. J. Magn. Reson. 2008, 192, 112. doi: 10.1016/j.jmr.2008.02.004
115	Cavadini S. ; Lupulescu A. ; Antonijevic S. ; Bodenhausen G. J. Am. Chem. Soc. 2006, 128, 7706. doi: 10.1021/ja0618898
116	Peng B. ; Yao Y. ; Chen Q. ; Hu B. Annual Rep. NMR Spectros. 2014, 85, 1. doi: 10.1016/bs.arnmr.2014.12.002
117	Lee H. H. ; Park Y. ; Shin K. H. ; Lee K. T. ; Hong S. Y. ACS Appl. Mater. Interfaces 2014, 6, 19118. doi: 10.1021/am505090p
118	Peng C. ; Ning G. H. ; Su J. ; Zhong G. ; Tang W. ; Tian B. ; Su C. ; Yu D. ; Zu L. ; Yang J. ; et al Nat. Energy 2017, 2, 17074. doi: 10.1038/nenergy.2017.74
119	Griffith K. J. ; Wiaderek K. M. ; Cibin G. ; Marbella L. E. ; Grey C. P. Nature 2018, 559, 556. doi: 10.1038/s41586-018-0347-0
120	Xiang Y. X. ; Zheng G. ; Zhong G. ; Wang D. ; Fu R. ; Yang Y. Solid State Ionics 2018, 318, 19. doi: 10.1016/j.ssi.2017.11.025
121	Engelke S. ; Marbella L. E. ; Trease N. M. ; De Volder M. ; Grey C. P. Phys. Chem. Chem. Phys. 2019, 21, 4538. doi: 10.1039/c8cp07776b
122	Prutsch D. ; Gadermaier B. ; Brandstätter H. ; Pregartner V. ; Stanje B. ; Wohlmuth D. ; Epp V. ; Rettenwander D. ; Hanzu I. ; Wilkening H. M. R. Chem. Mater. 2018, 30, 7575. doi: 10.1021/acs.chemmater.8b02753
123	Liang X. ; Wang L. ; Jiang Y. ; Wang J. ; Luo H. ; Liu C. ; Feng J. Chem. Mater. 2015, 27, 5503. doi: 10.1021/acs.chemmater.5b01384
124	Kuhn A. ; Sreeraj P. ; Pottgen R. ; Wiemhofer H. D. ; Wilkening M. ; Heitjans P. J. Am. Chem. Soc. 2011, 133, 11018. doi: 10.1021/ja2020108
125	Wilkening M. ; Heitjans P. ChemPhysChem 2012, 13, 53. doi: 10.1002/cphc.201100580
126	Pigliapochi R. ; Seymour I. D. ; Merlet C. ; Pell A. J. ; Murphy D. T. ; Schmid S. ; Grey C. P. Chem. Mater. 2018, 30, 817. doi: 10.1021/acs.chemmater.7b04314
127	Middlemiss D. S. ; Ilott A. J. ; Clément R. l. J. ; Strobridge F. C. ; Grey C. P. Chem. Mater. 2013, 25, 1723. doi: 10.1021/cm400201t
128	Castets A. ; Carlier D. ; Zhang Y. ; Boucher F. ; Ménétrier M. J. Phys. Chem. C 2012, 116, 18002. doi: 10.1021/jp302549s
129	Liu Y. ; Zeng L. ; Xu C. ; Geng F. ; Shen M. ; Yuan Q. ; Hu B. Chem. Phys. Lett. 2019, 736, 136779. doi: 10.1016/j.cplett.2019.136779
130	Liu Z. ; Lee J. ; Xiang G. ; Glass H. F. J. ; Keyzer E. N. ; Dutton S. E. ; Grey C. P. Chem. Commun. 2017, 53, 743. doi: 10.1039/C6CC08430C
131	Lee J. ; Seymour I. D. ; Pell A. J. ; Dutton S. E. ; Grey C. P. Phys. Chem. Chem. Phys. 2017, 19, 613. doi: 10.1039/C6CP06338A
132	Canepa P. ; Bo S. H. ; Sai Gautam G. ; Key B. ; Richards W. D. ; Shi T. ; Tian Y. ; Wang Y. ; Li J. ; Ceder G. Nat. Commun. 2017, 8, 1759. doi: 10.1038/s41467-017-01772-1
133	Leroy C. ; Bryce D. L. Prog. Nucl. Magn. Reson. Spectrosc. 2018, 109, 160. doi: 10.1016/j.pnmrs.2018.08.002
134	Leskes M. ; Kim G. ; Liu T. ; Michan A. L. ; Aussenac F. ; Dorffer P. ; Paul S. ; Grey C. P. J. Phys. Chem. Lett. 2017, 8, 1078. doi: 10.1021/acs.jpclett.6b02590
135	Chakrabarty T. ; Goldin N. ; Feintuch A. ; Houben L. ; Leskes M. ChemPhysChem 2018, 19, 2139. doi: 10.1002/cphc.201800462
136	Wolf T. ; Kumar S. ; Singh H. ; Chakrabarty T. ; Aussenac F. ; Frenkel A. I. ; Major D. T. ; Leskes M. J. Am. Chem. Soc. 2018, 141, 451. doi: 10.1021/jacs.8b11015

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