锂金属负极人造保护膜的研究进展

doi:10.3866/PKU.WHXB202008078

物理化学学报 >> 2021, Vol. 37 >> Issue (2): 2008078.doi: 10.3866/PKU.WHXB202008078

所属专题：金属锂负极

锂金属负极人造保护膜的研究进展

刘冬冬, 陈超, 熊训辉()

华南理工大学环境与能源学院，广州 510006

收稿日期:2020-08-25 录用日期:2020-09-21 发布日期:2020-10-12
通讯作者: 熊训辉 E-mail:esxxiong@scut.edu.cn
作者简介:熊训辉，教授，博士生导师。主要从事有色金属能源材料的可控制备及储能机理研究
基金资助:
国家自然科学基金(51874142);中央高校基本科研基金(2019JQ09);广东特支计划“科技创新青年拔尖人才”项目(2019TQ05L903);中国科协青年托举人才项目(2019QNRC001)

Research Progress on Artificial Protective Films for Lithium Metal Anodes

Dongdong Liu, Chao Chen, Xunhui Xiong()

School of Environment and Energy, South China University of Technology, Guangzhou 510006, China

Received:2020-08-25 Accepted:2020-09-21 Published:2020-10-12
Contact: Xunhui Xiong E-mail:esxxiong@scut.edu.cn
About author:Xunhui Xiong, Email: esxxiong@scut.edu.cn. Tel.: +86-20-39381203
Supported by:
the National Natural Science Foundation of China(51874142);the Fundamental Research Funds for the Central Universities(2019JQ09);the Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program(2019TQ05L903);the Young Elite Scientists Sponsorship Program by CAST(2019QNRC001)

摘要/Abstract

摘要：

金属锂因其具有极高的理论容量(3860 mAh·g^-1)、最低的电极电位(-3.04 V vs.标准氢电极)和低的密度(0.534 g·cm^-3)，被认为是最具潜力的负极材料。但循环过程中不可控的枝晶生长及不稳定的固体电解质相界面膜所引起的安全隐患和电池库伦效率低等问题严重阻碍了锂金属负极的发展。通过在电极表面构建人造保护膜可以有效调控锂离子沉积行为，因此人造保护膜的构建是一种简单高效抑制锂枝晶生长的策略。本综述将从聚合物保护膜、无机保护膜、有机-无机复合保护膜和合金保护膜总结了人造保护膜的构建方法、抑制锂枝晶生长机理，为促进高比能锂金属电池的商业化应用提供借鉴参考作用。

关键词: 金属锂, 负极, 枝晶, 人造保护膜, 高比能

Abstract:

In the early 1990s, Sony launched the first commercial lithium ion battery (LIB), which achieved great success in energy storage systems. The current commercially used insertion anode, graphite, is approaching its capacity limit (~372 mAh·g^-1), and is inadequate to satisfy the ever-increasing energy demand for power grids and large-scale energy storage systems. In order to address this challenge, lithium metal anodes have been the focus of considerable research effort in recent years, and are regarded as the most promising anode materials because of their extremely high theoretical capacity (3860 mAh·g^-1), lowest electrode potential (-3.04 V vs. standard hydrogen electrode), and low density (0.534 g·cm^-3). For example, the theoretical energy densities of lithium-sulfur batteries and lithium-air batteries are as high as 2567 and 3505 Wh·kg^-1, respectively. However, the uncontrollable dendrite growth during cycling leads to low coulombic efficiency and puncture of the separator, causing a short circuit or even explosion of the battery, thereby seriously hindering the development of the lithium metal anode. Many solutions have been proposed to inhibit dendrite growth, including the use of electrolyte additives, solid electrolytes, and artificial protective films. During charging and discharging, the solid electrolyte interphase (SEI) plays an important role in lithium metal anodes. However, the infinite volume changes of the electrode during plating/stripping processes result in breakage of the SEI film, which continuously consumes the electrolyte and lithium metal. Designing an artificial interface on the surface of lithium metal anodes has been considered as a simple and efficient strategy to control lithium deposition behavior, and is achieved by precoating a protective layer on the surface of lithium metal. An ideal artificial protective film should possess high ionic conductivity, chemical stability, and excellent mechanical strength, in order to prevent side reactions between lithium metal and the electrolyte and realize dendrite-free lithium metal anodes with a long cycle life and high coulombic efficiencies. In this paper, the research progress on artificial protective films for lithium metal anodes in recent years is reviewed. Further, the structural characteristics and preparation methods of various protective films are introduced in detail, including polymer protective films, inorganic protective films, organic-inorganic composite protective films, and alloy protective films. The mechanisms of various protective films toward the suppression of dendrite growth are summarized. Existing challenges and future research directions are also proposed, which together provide a reference for promoting the use of lithium metal in high-energy batteries.

Key words: Lithium metal, Anode, Dendrite, Artificial protective film, High energy density

刘冬冬, 陈超, 熊训辉. 锂金属负极人造保护膜的研究进展[J]. 物理化学学报, 2021, 37(2), 2008078. doi: 10.3866/PKU.WHXB202008078

Dongdong Liu, Chao Chen, Xunhui Xiong. Research Progress on Artificial Protective Films for Lithium Metal Anodes[J]. Acta Phys. -Chim. Sin. 2021, 37(2), 2008078. doi: 10.3866/PKU.WHXB202008078

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB202008078

https://www.whxb.pku.edu.cn/CN/Y2021/V37/I2/2008078

图/表 11

图1

图2

图3

图4

图5

图6

图7

图8

图9

图10

图11

参考文献 100

1	Evarts E. C. Nature 2015, 526, S93. doi: 10.1038/526S93a
2	Janek J. ; Zeier W. G. Nat. Energy 2016, 1, 16141. doi: 10.1038/nenergy.2016.141
3	Li P. ; Hwang J. Y. ; Sun Y. K. ACS Nano 2019, 13, 2624. doi: 10.1021/acsnano.9b00169
4	Cheng X. B. ; Zhang R. ; Zhao C. Z. ; Zhang Q. Chem. Rev. 2017, 117, 10403. doi: 10.1021/acs.chemrev.7b00115
5	Sun Y. ; Ma P. ; Liu L. ; Chen J. ; Zhang X. ; Lang J. ; Yan X. Sol. RRL 2018, 2, 1800223. doi: 10.1002/solr.201800223
6	Sun Y. ; Yan X. Sol. RRL 2017, 1, 1700002. doi: 10.1002/solr.201700002
7	Tarascon J. M. ; Armand M. Nature 2001, 414, 359. doi: 10.1038/35104644
8	Xu W. ; Wang J. ; Ding F. ; Chen X. ; Nasybulin E. ; Zhang Y. ; Zhang J. G. Energy Environ. Sci. 2014, 7, 513. doi: 10.1039/C3EE40795K
9	Niu C. ; Pan H. ; Xu W. ; Xiao J. ; Zhang J. G. ; Luo L. ; Wang C. ; Mei D. ; Meng J. ; Wang X. ; et al Nat. Nanotechnol. 2019, 14, 594. doi: 10.1038/s41565-019-0427-9
10	Bruce P. G. ; Freunberger S. A. ; Hardwick L. J. ; Tarascon J. M. Nat. Mater. 2012, 11, 19. doi: 10.1038/nmat3191
11	Bruce P. G. ; Hardwick L. J. ; Abraham K. M. MRS Bull. 2011, 36, 506. doi: 10.1557/mrs.2011.157
12	Xu X. ; Wang S. ; Wang H. ; Hu C. ; Jin Y. ; Liu J. ; Yan H. J. Energy Chem. 2018, 27, 513. doi: 10.1016/j.jechem.2017.11.010
13	Zhang X. Q. ; Zhao C. Z. ; Huang J. Q. ; Zhang Q. Engineering 2018, 4, 831. doi: 10.1016/j.eng.2018.10.008
14	Lin D. ; Liu Y. ; Cui Y. Nat. Nanotechnol. 2017, 12, 194. doi: 10.1038/nnano.2017.16
15	Feng Y. ; Zhang C. ; Li B. ; Xiong S. ; Song J. J. Mater. Chem. A 2019, 7, 6090. doi: 10.1039/C8TA10779C
16	Qie L. ; Zu C. ; Manthiram A. Adv. Energy Mater. 2016, 6, 1502459. doi: 10.1002/aenm.201502459
17	Zhang Y. ; Luo W. ; Wang C. ; Li Y. ; Chen C. ; Song J. ; Dai J. ; Hitz E. M. ; Xu S. ; Yang C. ; et al Proc. Natl. Acad. Sci. 2017, 114, 3584. doi: 10.1073/pnas.1618871114
18	Chazalviel J. N. Phys. Rev. A 1990, 42, 7355. doi: 10.1103/PhysRevA.42.7355
19	Brissot C. ; Rosso M. ; Chazalviel J. N. ; Lascaud S. J. Power Sources 1999, 81–82, 925. doi: 10.1016/S0378-7753(98)00242-0
20	Ding F. ; Xu W. ; Graff G. L. ; Zhang J. ; Sushko M. L. ; Chen X. ; Shao Y. ; Engelhard M. H. ; Nie Z. ; Xiao J. ; et al J. Am. Chem. Soc. 2013, 135, 4450. doi: 10.1021/ja312241y
21	Enze L. J. Phys. D: Appl. Phys. 1986, 19, 1. doi: 10.1088/0022-3727/19/1/005
22	Liu F. F. ; Zhang Z. W. ; Ye S. F. ; Yao Y. ; Yu Y. Acta Phys. -Chim. Sin. 2021, 37, 2006021.
	刘凡凡; 张志文; 叶淑芬; 姚雨; 余彦. 物理化学学报, 2021, 37, 2006021. doi: 10.3866/PKU.WHXB202006021
23	Kushima A. ; So K. P. ; Su C. ; Bai P. ; Kuriyama N. ; Maebashi T. ; Fujiwara Y. ; Bazant M. Z. ; Li J. Nano Energy 2017, 32, 271. doi: 10.1016/j.nanoen.2016.12.001
24	Jäckle M. ; Groß A. J. Chem. Phys. 2014, 141, 174710. doi: 10.1063/1.4901055
25	Wang D. ; Zhang W. ; Zheng W. ; Cui X. ; Rojo T. ; Zhang Q. Adv. Sci. 2017, 4, 1600168. doi: 10.1002/advs.201600168
26	Yamaki J. ; Tobishima S. ; Hayashi K. ; Saito K. ; Nemoto Y. ; Arakawa M. J. Power Sources 1998, 74, 219. doi: 10.1016/S0378-7753(98)00067-6
27	Wang G. ; Xiong X. ; Xie D. ; Fu X. ; Ma X. ; Li Y. ; Liu Y. ; Lin Z. ; Yang C. ; Liu M. Energy Storage Mater. 2019, 23, 701. doi: 10.1016/j.ensm.2019.02.026
28	Fu X. ; Wang G. ; Dang D. ; Liu Q. ; Xiong X. ; Wu C. J. Mater. Chem. A 2019, 7, 25003. doi: 10.1039/C9TA09068A
29	Ran Q. ; Sun T. Y. ; Han C. Y. ; Zhang H. N. ; Yan J. ; Wang J. L. Acta Phys. -Chim. Sin. 2020, 36, 1912068.
	冉琴; 孙天霷; 韩冲宇; 张浩楠; 颜剑; 汪靖伦. 物理化学学报, 2020, 36, 1912068. doi: 10.3866/PKU.WHXB201912068
30	Luo C. ; Ji X. ; Chen J. ; Gaskell K. J. ; He X. ; Liang Y. ; Jiang J. ; Wang C. Angew. Chem. 2018, 130, 8703. doi: 10.1002/ange.201804068
31	Zhang B. ; Tan R. ; Yang L. ; Zheng J. ; Zhang K. ; Mo S. ; Lin Z. ; Pan F. Energy Storage Mater. 2018, 10, 139. doi: 10.1016/j.ensm.2017.08.015
32	Luo W. ; Gong Y. ; Zhu Y. ; Fu K. K. ; Dai J. ; Lacey S. D. ; Wang C. ; Liu B. ; Han X. ; Mo Y. ; et al J. Am. Chem. Soc. 2016, 138, 12258. doi: 10.1021/jacs.6b06777
33	Gu J. ; Zhu Q. ; Shi Y. ; Chen H. ; Zhang D. ; Du Z. ; Yang S. ACS Nano 2020, 14, 891. doi: 10.1021/acsnano.9b08141
34	Xu B. ; Zhai H. ; Liao X. ; Qie B. ; Mandal J. ; Gong T. ; Tan L. ; Yang X. ; Sun K. ; Cheng Q. ; et al Energy Storage Mater. 2019, 17, 31. doi: 10.1016/j.ensm.2018.11.035
35	Kim M. S. ; Ryu J. H. ; Deepika ; Lim Y. R. ; Nah I. W. ; Lee K. R. ; Archer L. A. ; Il Cho W. Nat. Energy 2018, 3, 889. doi: 10.1038/s41560-018-0237-6
36	Liu Y. ; Lin D. ; Yuen P. Y. ; Liu K. ; Xie J. ; Dauskardt R. H. ; Cui Y. Adv. Mater. 2017, 29, 1605531. doi: 10.1002/adma.201605531
37	Deng K. ; Han D. ; Ren S. ; Wang S. ; Xiao M. ; Meng Y. J. Mater. Chem. A 2019, 7, 13113. doi: 10.1039/C9TA02407G
38	Zhang C. ; Lyu R. ; Lv W. ; Li H. ; Jiang W. ; Li J. ; Gu S. ; Zhou G. ; Huang Z. ; Zhang Y. ; et al Adv. Mater. 2019, 31, 1904991. doi: 10.1002/adma.201904991
39	Chi S. ; Liu Y. ; Song W. ; Fan L. ; Zhang Q. Adv. Funct. Mater. 2017, 27, 1700348. doi: 10.1002/adfm.201700348
40	Luo L. ; Li J. ; Yaghoobnejad Asl H. ; Manthiram A. Adv. Mater. 2019, 31, 1904537. doi: 10.1002/adma.201904537
41	Wang M. Q. ; Peng Z. ; Lin H. ; Li Z. D. ; Liu J. ; Ren Z. M. ; He H. Y. ; Wang D. Y. Acta Phys. -Chim. Sin. 2021, 37, 2007016.
	王木钦; 彭哲; 林欢; 李振东; 刘健; 任重民; 何海勇; 王德宇. 物理化学学报, 2021, 37, 2007016. doi: 10.3866/PKU.WHXB202007016
42	Chen X. ; Hou T. Z. ; Li B. ; Yan C. ; Zhu L. ; Guan C. ; Cheng X. B. ; Peng H. J. ; Huang J. Q. ; Zhang Q. Energy Storage Mater. 2017, 8, 194. doi: 10.1016/j.ensm.2017.01.003
43	Tao R. ; Bi X. ; Li S. ; Yao Y. ; Wu F. ; Wang Q. ; Zhang C. ; Lu J. ACS Appl. Mater. Interfaces 2017, 9, 7003. doi: 10.1021/acsami.6b13859
44	Huang G. ; Han J. ; Zhang F. ; Wang Z. ; Kashani H. ; Watanabe K. ; Chen M. Adv. Mater. 2019, 31, 1805334. doi: 10.1002/adma.201805334
45	Liu S. ; Zhang X. ; Li R. ; Gao L. ; Luo J. Energy Storage Mater. 2018, 14, 143. doi: 10.1016/j.ensm.2018.03.004
46	Cheng X. ; Zhang R. ; Zhao C. ; Wei F. ; Zhang J. G. ; Zhang Q. Adv. Sci. 2016, 3, 1500213. doi: 10.1002/advs.201500213
47	Rui K. ; Wen Z. ; Lu Y. ; Jin J. ; Shen C. Adv. Energy Mater. 2015, 5, 1401716. doi: 10.1002/aenm.201401716
48	Zheng J. ; Engelhard M. H. ; Mei D. ; Jiao S. ; Polzin B. J. ; Zhang J. G. ; Xu W. Nat. Energy 2017, 2, 17012. doi: 10.1038/nenergy.2017.12
49	Yan K. ; Lee H. W. ; Gao T. ; Zheng G. ; Yao H. ; Wang H. ; Lu Z. ; Zhou Y. ; Liang Z. ; Liu Z. ; et al Nano Lett. 2014, 14, 6016. doi: 10.1021/nl503125u
50	Chen L. ; Connell J. G. ; Nie A. ; Huang Z. ; Zavadil K. R. ; Klavetter K. C. ; Yuan Y. ; Sharifi-Asl S. ; Shahbazian-Yassar R. ; Libera J. A. ; et al J. Mater. Chem. A 2017, 5, 12297. doi: 10.1039/C7TA03116E
51	Kushima A. ; So K. P. ; Su C. ; Bai P. ; Kuriyama N. ; Maebashi T. ; Fujiwara Y. ; Bazant M. Z. ; Li J. Nano Energy 2017, 32, 271. doi: 10.1016/j.nanoen.2016.12.001
52	Zheng G. ; Wang C. ; Pei A. ; Lopez J. ; Shi F. ; Chen Z. ; Sendek A. D. ; Lee H. W. ; Lu Z. ; Schneider H. ; et al ACS Energy Lett. 2016, 1, 1247. doi: 10.1021/acsenergylett.6b00456
53	Choi S. M. ; Kang I. S. ; Sun Y. K. ; Song J. H. ; Chung S. M. ; Kim D. W. J. Power Sources 2013, 244, 363. doi: 10.1016/j.jpowsour.2012.12.106
54	Zhu J. ; Li P. ; Chen X. ; Legut D. ; Fan Y. ; Zhang R. ; Lu Y. ; Cheng X. ; Zhang Q. Energy Storage Mater. 2019, 16, 426. doi: 10.1016/j.ensm.2018.06.023
55	Bai M. ; Xie K. ; Yuan K. ; Zhang K. ; Li N. ; Shen C. ; Lai Y. ; Vajtai R. ; Ajayan P. ; Wei B. Adv. Mater. 2018, 30, 1801213. doi: 10.1002/adma.201801213
56	Wang G. ; Xiong X. ; Xie D. ; Fu X. ; Lin Z. ; Yang C. ; Zhang K. ; Liu M. ACS Appl. Mater. Interfaces 2019, 11, 4962. doi: 10.1021/acsami.8b18101
57	Zhou D. ; Liu R. ; He Y. ; Li F. ; Liu M. ; Li B. ; Yang Q. ; Cai Q. ; Kang F. Adv. Energy Mater. 2016, 6, 1502214. doi: 10.1002/aenm.201502214
58	Jang E. K. ; Ahn J. ; Yoon S. ; Cho K. Y. Adv. Funct. Mater. 2019, 29, 1905078. doi: 10.1002/adfm.201905078
59	Zhang Z. ; Zhang L. ; Liu Y. ; Yang T. ; Wang Z. ; Yan X. ; Yu C. J. Mater. Chem. A 2019, 7, 23173. doi: 10.1039/C9TA08415K
60	Liang X. ; Pang Q. ; Kochetkov I. R. ; Sempere M. S. ; Huang H. ; Sun X. ; Nazar L. F. Nat. Energy 2017, 2, 17119. doi: 10.1038/nenergy.2017.119
61	Wang G. ; Xiong X. ; Lin Z. ; Zheng J. ; Fenghua Z. ; Li Y. ; Liu Y. ; Yang C. ; Tang Y. ; Liu M. Nanoscale 2018, 10, 10018. doi: 10.1039/C8NR01995A
62	Wu H. ; Yao Z. ; Wu Q. ; Fan S. ; Yin C. ; Li C. J. Mater. Chem. A 2019, 7, 22257. doi: 10.1039/C9TA09146G
63	Sun Y. ; Zhao Y. ; Wang J. ; Liang J. ; Wang C. ; Sun Q. ; Lin X. ; Adair K. R. ; Luo J. ; Wang D. ; et al Adv. Mater. 2019, 31, 1806541. doi: 10.1002/adma.201806541
64	Wu H. ; Wu Q. ; Chu F. ; Hu J. ; Cui Y. ; Yin C. ; Li C. J. Power Sources 2019, 419, 72. doi: 10.1016/j.jpowsour.2019.02.033
65	Wang G. ; Chen C. ; Chen Y. ; Kang X. ; Yang C. ; Wang F. ; Liu Y. ; Xiong X. Angew. Chem. Int. Ed. 2020, 59, 2055. doi: 10.1002/anie.201913351
66	Lopez J. ; Pei A. ; Oh J. Y. ; Wang G. J. N. ; Cui Y. ; Bao Z. J. Am. Chem. Soc. 2018, 140, 11735. doi: 10.1021/jacs.8b06047
67	Monroe C. ; Newman J. J. Electrochem. Soc. 2003, 150, A1377. doi: 10.1149/1.1606686
68	Stone G. M. ; Mullin S. A. ; Teran A. A. ; Hallinan D. T. ; Minor A. M. ; Hexemer A. ; Balsara N. P. J. Electrochem. Soc. 2012, 159, A222. doi: 10.1149/2.030203jes
69	Pei A. ; Zheng G. ; Shi F. ; Li Y. ; Cui Y. Nano Lett. 2017, 17, 1132. doi: 10.1021/acs.nanolett.6b04755
70	Huang S. ; Zhang W. ; Ming H. ; Cao G. ; Fan L. Z. ; Zhang H. Nano Lett. 2019, 19, 1832. doi: 10.1021/acs.nanolett.8b04919
71	Cui Y. Acta Phys. -Chim. Sin. 2019, 35, 661.
	崔屹. 物理化学学报, 2019, 35, 661. doi: 10.3866/PKU.WHXB201809053
72	Xiang H. ; Chen J. ; Li Z. ; Wang H. J. Power Sources 2011, 196, 8651. doi: 10.1016/j.jpowsour.2011.06.055
73	He M. ; Zhang X. ; Jiang K. ; Wang J. ; Wang Y. ACS Appl. Mater. Interfaces 2015, 7, 738. doi: 10.1021/am507145h
74	Wang G. ; Xiong X. ; Zou P. ; Fu X. ; Lin Z. ; Li Y. ; Liu Y. ; Yang C. ; Liu M. Chem. Eng. J. 2019, 378, 122243. doi: 10.1016/j.cej.2019.122243
75	Kozen A. C. ; Lin C. F. ; Pearse A. J. ; Schroeder M. A. ; Han X. ; Hu L. ; Lee S. B. ; Rubloff G. W. ; Noked M. ACS Nano 2015, 9, 5884. doi: 10.1021/acsnano.5b02166
76	Kazyak E. ; Wood K. N. ; Dasgupta N. P. Chem. Mater. 2015, 27, 6457. doi: 10.1021/acs.chemmater.5b02789
77	Umeda G. A. ; Menke E. ; Richard M. ; Stamm K. L. ; Wudl F. ; Dunn B. J. Mater. Chem. 2011, 21, 1593. doi: 10.1039/C0JM02305A
78	Ma G. ; Wen Z. ; Wu M. ; Shen C. ; Wang Q. ; Jin J. ; Wu X. Chem. Commun. 2014, 50, 14209. doi: 10.1039/C4CC05535G
79	Zhao J. ; Liao L. ; Shi F. ; Lei T. ; Chen G. ; Pei A. ; Sun J. ; Yan K. ; Zhou G. ; Xie J. ; et al J. Am. Chem. Soc. 2017, 139, 11550. doi: 10.1021/jacs.7b05251
80	Lin Y. ; Wen Z. ; Liu J. ; Wu D. ; Zhang P. ; Zhao J. J. Energy Chem. 2021, 55, 129. doi: 10.1016/j.jechem.2020.07.003
81	Li N. ; Yin Y. ; Yang C. ; Guo Y. Adv. Mater. 2016, 28, 1853. doi: 10.1002/adma.201504526
82	Lin L. ; Liang F. ; Zhang K. ; Mao H. ; Yang J. ; Qian Y. J. Mater. Chem. A 2018, 6, 15859. doi: 10.1039/C8TA05102J
83	Liu F. ; Wang L. ; Zhang Z. ; Shi P. ; Feng Y. ; Yao Y. ; Ye S. ; Wang H. ; Wu X. ; Yu Y. Adv. Funct. Mater. 2020, 30, 2001607. doi: 10.1002/adfm.202001607
84	Herbert E. G. ; Tenhaeff W. E. ; Dudney N. J. ; Pharr G. M. Thin Solid Films 2011, 520, 413. doi: 10.1016/j.tsf.2011.07.068
85	Wang W. ; Yue X. ; Meng J. ; Wang J. ; Wang X. ; Chen H. ; Shi D. ; Fu J. ; Zhou Y. ; Chen J. ; et al Energy Storage Mater. 2019, 18, 414. doi: 10.1016/j.ensm.2018.08.010
86	Zhang Y. J. ; Liu X. Y. ; Bai W. Q. ; Tang H. ; Shi S. J. ; Wang X. L. ; Gu C. D. ; Tu J. P. J. Power Sources 2014, 266, 43. doi: 10.1016/j.jpowsour.2014.04.147
87	Zheng G. ; Lee S. W. ; Liang Z. ; Lee H. W. ; Yan K. ; Yao H. ; Wang H. ; Li W. ; Chu S. ; Cui Y. Nat. Nanotechnol. 2014, 9, 618. doi: 10.1038/nnano.2014.152
88	Bai M. ; Xie K. ; Yuan K. ; Zhang K. ; Li N. ; Shen C. ; Lai Y. ; Vajtai R. ; Ajayan P. ; Wei B. Adv. Mater. 2018, 30, 1801213. doi: 10.1002/adma.201801213
89	Xu R. ; Zhang X. ; Cheng X. ; Peng H. ; Zhao C. ; Yan C. ; Huang J. Adv. Funct. Mater. 2018, 28, 1705838. doi: 10.1002/adfm.201705838
90	Wu C. ; Guo F. ; Zhuang L. ; Ai X. ; Zhong F. ; Yang H. ; Qian J. ACS Energy Lett. 2020, 5, 1644. doi: 10.1021/acsenergylett.0c00804
91	Liu X. ; Liu J. ; Qian T. ; Chen H. ; Yan C. Adv. Mater. 2020, 32, 1902724. doi: 10.1002/adma.201902724
92	Zhang Y. ; Wang G. ; Tang L. ; Wu J. ; Guo B. ; Zhu M. ; Wu C. ; Dou S. X. ; Wu M. J. Mater. Chem. A 2019, 7, 25369. doi: 10.1039/C9TA09523C
93	Kim H. ; Lee J. T. ; Lee D. C. ; Oschatz M. ; Cho W. Il ; Kaskel S. ; Yushin G. Electrochem. Commun. 2013, 36, 38. doi: 10.1016/j.elecom.2013.09.002
94	Jiang Y. ; Jiang J. ; Wang Z. ; Han M. ; Liu X. ; Yi J. ; Zhao B. ; Sun X. ; Zhang J. Nano Energy 2020, 70, 104504. doi: 10.1016/j.nanoen.2020.104504
95	Obrovac M. N. ; Chevrier V. L. Chem. Rev. 2014, 114, 11444. doi: 10.1021/cr500207g
96	He G. ; Li Q. ; Shen Y. ; Ding Y. Angew. Chem. Int. Ed. 2019, 58, 18466. doi: 10.1002/anie.201911800
97	Wang H. ; Li Y. ; Li Y. ; Liu Y. ; Lin D. ; Zhu C. ; Chen G. ; Yang A. ; Yan K. ; Chen H. ; et al Nano Lett. 2019, 19, 1326. doi: 10.1021/acs.nanolett.8b04906
98	Yang C. ; Yao Y. ; He S. ; Xie H. ; Hitz E. ; Hu L. Adv. Mater. 2017, 29, 1702714. doi: 10.1002/adma.201702714
99	Guo F. ; Wu C. ; Chen H. ; Zhong F. ; Ai X. ; Yang H. ; Qian J. Energy Storage Mater. 2020, 24, 635. doi: 10.1016/j.ensm.2019.06.010
100	Wu L. ; He G. ; Ding Y. J. Mater. Chem. A 2019, 7, 25415. doi: 10.1039/C9TA09464D

[1]	祝鑫彤, 曹斌, 闫崇, 唐城, 陈爱兵, 张强. 锂离子电池石墨负极包覆研究进展[J]. 物理化学学报, 2025, 41(9): 100096 - .
[2]	马千里, 宋天兵, 何天乐, 张熙荣, 熊焕明. 硫掺杂的碳点作为双功能电解液添加剂实现高性能水系锌离子电池[J]. 物理化学学报, 2025, 41(9): 100106 - .
[3]	金彩云, 吴泽轩, 李国鹏, 罗战, 李念武. 用于金属锂电池的磷腈基阻燃人工界面层[J]. 物理化学学报, 2025, 41(8): 100094 - .
[4]	林学宇, 王瑞琦, 董武杰, 黄富强. 高性能双金属氧化物负极的理性设计及储锂特性[J]. 物理化学学报, 2025, 41(3): 100021 - .
[5]	郭宇, 黄志伟, 胡雨青, 李俊哲, 徐杰. 钠离子电池中铁基异质结构负极材料的最新研究进展[J]. 物理化学学报, 2025, 41(3): 100022 - .
[6]	李尚华, 李玛琳, 迟茜文, 尹心, 罗招娣, 于吉红. 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑[J]. 物理化学学报, 2025, 41(1): 100003 - .
[7]	张景硕, 翟越, 赵子云, 何家兴, 魏伟, 肖菁, 吴士超, 杨全红. 锂离子电池硅基负极用功能粘结剂的研究进展[J]. 物理化学学报, 2024, 40(6): 2306006 - .
[8]	肖雪, 李佳纯, 孟祥桐, 邱介山. 硫掺杂碳包覆Fe_0.95S_1.05纳米球复合材料的储钠性能[J]. 物理化学学报, 2024, 40(6): 2307006 - .
[9]	刘建东, 李鑫, 吴达雄, 王华平, 黄俊达, 马建民. 优化Li\|\|NCM811电池电解液溶剂化和电极电解液界面的阴离子受体添加剂策略[J]. 物理化学学报, 2024, 40(6): 2306039 - .
[10]	刘泽宇, 黄文泽, 肖阳, 张俊东, 孔伟进, 武鹏, 赵辰孜, 陈爱兵, 张强. 全固态无负极锂金属电池纳米化复合集流体构筑[J]. 物理化学学报, 2024, 40(3): 2305040 - .
[11]	李亚捷, 陈斌, 王依平, 邢辉, 赵伟, 张更, 施思齐. 定制电解液或隔膜实现锂离子各向异性输运从而抑制枝晶生长：相场模拟研究[J]. 物理化学学报, 2024, 40(3): 2305053 - .
[12]	杨帆, 刘争, 汪达, 许冠南, 张业龙, 彭章泉. P-Bi₂Te₃/MXene超结构钾离子电池负极制备及其性能[J]. 物理化学学报, 2024, 40(2): 2303006 - .
[13]	许涛, 孙伟, 孔天赐, 周杰, 钱逸泰. 稳定界面助力石墨实现超长储钾性能[J]. 物理化学学报, 2024, 40(2): 2303021 - .
[14]	胡雪晨, 夏求应, 岳钒, 何欣怡, 梅正浩, 王金石, 夏晖, 黄晓东. LiNbO₃负极薄膜电化学性能及全固态薄膜锂离子电池应用[J]. 物理化学学报, 2024, 40(2): 2309046 - .
[15]	夏求应, 蔡雨, 刘威, 王金石, 吴川智, 昝峰, 徐璟, 夏晖. 锂负极失效的全固态薄膜锂电池的直接回收再利用[J]. 物理化学学报, 2023, 39(8): 2212051 -0 .

锂金属负极人造保护膜的研究进展

Research Progress on Artificial Protective Films for Lithium Metal Anodes

RichHTML

PDF

赞

可视化

摘要/Abstract

引用本文

使用本文

图/表 11

参考文献 100

相关文章 15

Metrics

推荐阅读 0