P-Bi2Te3/MXene超结构钾离子电池负极制备及其性能

doi:10.3866/PKU.WHXB202303006

物理化学学报 >> 2024, Vol. 40 >> Issue (2): 2303006.doi: 10.3866/PKU.WHXB202303006

P-Bi₂Te₃/MXene超结构钾离子电池负极制备及其性能

杨帆¹, 刘争¹, 汪达¹, 许冠南², 张业龙¹, 彭章泉^1,3

1 五邑大学应用物理与材料学院, 广东江门 529020;
2 澳门大学应用物理及材料工程研究院, 澳门 999078;
3 中国科学院大连化学物理研究所, 谱学电化学与锂离子电池实验室, 辽宁大连 116023

收稿日期:2023-03-02 修回日期:2023-03-31 发布日期:2023-04-13
通讯作者: 张业龙,Email:zhangyelong2008@126.com;彭章泉,Email:zqpeng@dicp.ac.cn E-mail:zhangyelong2008@126.com;zqpeng@dicp.ac.cn
基金资助:
国家自然科学基金(22005223,21975187),广东省基础与应用基础研究基金(2019A1515012161),五邑大学青年科研基金(2019Td01),五邑大学高层次人才科研启动项目(2018RC50),五邑大学港澳联合研发基金(2019WGALH10)资助

Preparation and Properties of P-Bi₂Te₃/MXene Superstructure-based Anode for Potassium-Ion Battery

Fan Yang¹, Zheng Liu¹, Da Wang¹, KwunNam Hui², Yelong Zhang¹, Zhangquan Peng^1,3

1 School of Applied Physics and Materials, Wuyi University, Jiangmen 529020, Guangdong Province, China;
2 Institute of Applied Physics and Materials Engineering, University of Macau, Macau SAR 999078, China;
3 Laboratory of Spectro-electrochemistry and Li-ion Batteries, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, China

Received:2023-03-02 Revised:2023-03-31 Published:2023-04-13
Supported by:
The project was supported by the National Natural Science Foundation of China (22005223, 21975187), the Guangdong Basic and Applied Basic Research Foundation (2019A1515012161), the Science Foundation for Young Teachers of Wuyi University (2019Td01), the Science Foundation for High-Level Talents of Wuyi University (2018RC50), and the Wuyi University-Hong Kong-Macao Joint Research Project (2019WGALH10).

摘要/Abstract

摘要： Bi₂Te₃钾离子电池负极存在结构不稳定性和电化学反应动力学缓慢问题。本研究在手风琴状MXene基底上生长棒状Bi₂Te₃，随后利用P掺杂制备了高性能P-Bi₂Te₃/MXene超结构。这种新型负极具有丰富的Te空位和良好的自适应特性，展现出优异的循环稳定性(在0.2 A∙g^-1电流密度下200次循环后可逆容量为323.1 mAh∙g^-1)和出色的倍率能力(20 A∙g^-1时可逆容量为67.1 mAh∙g^-1)。动力学分析和非原位表征表明，该超结构具有优异的赝电容特性、出色的K⁺离子扩散能力以及可逆的嵌入反应和转化反应机理。

关键词: 钾离子电池, 负极, Bi₂Te₃, MXene, P掺杂

Abstract: With increasing global energy demand and stricter environmental protection requirements, energy storage technology has become a research hotspot in the global energy field. New types of energy storage devices continue to emerge owing to the continuous development of cost-effective energy storage technology. Among them, potassium-ion batteries have received widespread attention as a new type of alkali metal ion battery because of their high capacity and low cost and are considered one of the future development directions. However, the research on potassium-ion batteries is still in its infancy, with many challenges to overcome regarding practical applications. A key factor affecting the performance of potassium-ion batteries is the anode material, as it not only affects the manufacturing costs but also directly affects the power density and energy density of the battery. Traditional anode materials for lithium-ion batteries cannot meet the requirements of potassium-ion batteries. Therefore, developing high-performance anode materials suitable for potassium-ion batteries is an important research direction at present. The charge and discharge rate and cycling life of potassium-ion batteries also need further improvements. Currently, the low-rate performance, short cycle life, and unsatisfactory practical capacities limit their practical application and commercialization. However, the future of potassium-ion batteries remains promising. Upon resolving the aforementioned issues, potassium-ion batteries will have diverse application prospects, such as electric vehicles, energy storage stations, and smart grids, providing important support for solving energy problems. Therefore, the research and development of potassium-ion batteries are an important direction in the global energy field. Current research efforts are primarily focused on exploring novel anode materials with exceptional ratability and cyclability. In this regard, we synthesized a new type of anode material based on bismuth telluride (Bi₂Te₃) and experimentally studied its applicability in potassium-ion batteries. The performance of Bi₂Te₃ anode for potassium-ion batteries has been limited by its structural instability and slow electrochemical reaction kinetics. In this study, rod-like Bi₂Te₃ was grown on accordion-like MXene, followed by P-doping to obtain a high-performance P-Bi₂Te₃/MXene superstructure. This novel anode had abundant Te vacancies and good self-auto adjustable function, providing excellent cycling stability (323.1 mAh·g^-1 after 200 cycles at 0.2 A·g^-1) and outstanding rate capability (67.1 mAh·g^-1 at 20 A·g^-1). Kinetic analysis and ex situ characterization indicate that the superstructure exhibits superior pseudocapacitive properties, high electrical conductivity, favorable diffusion capability, and reversible insertion and conversion reaction mechanism.

Key words: Potassium ion battery, Anode, Bi₂Te₃, MXene, P doping

杨帆, 刘争, 汪达, 许冠南, 张业龙, 彭章泉. P-Bi₂Te₃/MXene超结构钾离子电池负极制备及其性能[J]. 物理化学学报, 2024, 40(2), 2303006. doi: 10.3866/PKU.WHXB202303006

Fan Yang, Zheng Liu, Da Wang, KwunNam Hui, Yelong Zhang, Zhangquan Peng. Preparation and Properties of P-Bi₂Te₃/MXene Superstructure-based Anode for Potassium-Ion Battery[J]. Acta Phys. -Chim. Sin. 2024, 40(2), 2303006. doi: 10.3866/PKU.WHXB202303006

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB202303006

https://www.whxb.pku.edu.cn/CN/Y2024/V40/I2/2303006

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P-Bi₂Te₃/MXene超结构钾离子电池负极制备及其性能

Preparation and Properties of P-Bi₂Te₃/MXene Superstructure-based Anode for Potassium-Ion Battery

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