多面体状Cu2O修饰片状BiOI的S型异质结构筑及光催化水蒸气中CO2转化性能研究

doi:10.3866/PKU.WHXB202210003

摘要/Abstract

摘要：

过量的CO₂排放引起了一系列的环境问题。利用光催化技术将CO₂转为高附加值化合物不仅可以减小碳排放也可以缓解能源短缺。其中高效光催化剂开发是光催化技术的关键之一。纳米结构调控和异质结构筑是两种有效地提升材料光催化CO₂转化活性的方法。特别是，由还原型和氧化型催化剂组成的新型S型传导异质结，其在两组分之间不同的费米能级作用下，实现高效的光生载流子的分离。S型的电荷传导不仅可以有效的抑制光生载流子的复合，同时，聚集了大量具有较强催化氧化和还原能力的光生空穴与电子。Cu₂O和BiOI材料作为典型的还原型和氧化型催化剂，因其都具有良好的可见光吸收能力和适合的能带结构，可以应用于还原CO₂和氧化H₂O的耦合反应。我们利用电沉积的方法，在FTO导电玻璃基底表面构筑了多面体Cu₂O/片状BiOI的复合材料。我们利用粉末X射线衍射(XRD)，X射线光电子能谱(XPS)，紫外线光电子能谱(UPS)，场发射扫描电镜(SEM)和场发射投射电镜(TEM)技术对材料结构、形貌和组成进行了系统的探索和解析。¹³C/¹⁸O同位素标记实验证实，该复合材料可以实现可见光(波长 > 400 nm)驱动下水蒸气气氛中CO₂的快速转化。最优样品BiOI/Cu₂O-1500在光照11 h后，反应产物CO，CH₄，H₂和O₂的产量可以分别达到53.03，30.75，8.49和82.73 μmol∙m⁻²。在8次循环实验中，催化产物产量有小幅下降，但其主要产物CO，CH₄和O₂的产量仍然可以分别达到27.38，34.08和75.52 μmol∙m⁻²。循环前后使用催化剂的XRD和XPS结果表明，该复合材料具有良好的结构稳定性。催化实验结果表明，BiOI/Cu₂O异质结的形成提升了催化剂的光催化性能关键之一。固体漫反射光谱(DRS)和XPS测试结果表明异质结的能带结构为交错型，进一步利用UPS技术探索材料费米能级，进而确定异质结内内建电场方向。根据原位XPS测试结果证实，BiOI/Cu₂O异质结内光生电子采用S型模式分离传输。由此可见，S型异质结可以高效的分离和利用光生载流子。此外，我们通过原位红外(in situ FTIR)技术在催化剂表面发现了HCO₃⁻，CO₃²⁻，HCOO⁻和•CH₃等活性物质并推测其催化机理。该研究为S型载流子传输模式的探索提供了实验结果，同时为高效还原CO₂光催化剂提供了一定的借鉴。

关键词: S型, 光催化剂, CO₂还原, BiOI/Cu₂O, 片状

Abstract:

Excessive CO₂ emissions have led to serious environmental problems. The photocatalytic reduction of CO₂ to value-added chemicals is a promising strategy to reduce carbon emissions and alleviate the energy crisis simultaneously. Photocatalysts is crucial in the reduction process. Nanostructure engineering and heterojunction construction have been identified as prospective approaches to develop efficient photocatalysts for CO₂ reduction. Step-scheme (S-scheme) heterojunctions are novel systems composed of a reduction catalyst and an oxidation catalyst. In these systems, the charge separation at the interface between the two catalysts could be enhanced by an internal electric field directed from the reduction photocatalyst to the oxidation photocatalyst on account of their matched Fermi levels (E_f). The S-scheme transfer mode can not only efficaciously inhibit the recombination of photoinduced carriers but also accumulate electrons and holes with greater redox potential. Cu₂O and BiOI materials, as typical reduction and oxidation catalysts, are endowed with efficient visible-light absorption and favorable band position for catalyzing the coupling reaction of CO₂ reduction and H₂O oxidation. In this study, a series of S-scheme catalysts consisting of polyhedral Cu₂O-modified BiOI flakes were synthesized onto a fluorine-doped tin oxide substrate via the electrodeposition method. The structure, morphology, and surface composition of the as-obtained samples were then studied using X-ray diffractometry (XRD), X-ray photoelectron spectroscopy (XPS), ultraviolet photoelectron spectroscopy (UPS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) measurements. ¹³C/¹⁸O isotope tracer experiments indicated that the BiOI/Cu₂O composite achieved CO₂ conversion with water vapor under visible-light irradiation (λ > 400 nm). The CO, CH₄, H₂, and O₂ yields of the optimal BiOI/Cu₂O-1500 catalyst reached 53.03, 30.75, 8.49, and 82.73 μmol∙m⁻², respectively, after 11 h of visible-light illumination. The photocatalytic activity of BiOI/Cu₂O-1500 slightly decreased at the eighth cycling, but its CO, CH₄, and O₂ yields still reached 27.38, 34.08, and 75.52 μmol∙m⁻², respectively. The XPS and XRD results confirmed the excellent cycling stability of the catalysts, and analysis using the XPS core-level (CL) alignment method revealed that a staggered band structure was formed in the BiOI/Cu₂O heterojunction. The direction of the built-in electric field in the heterojunction was determined using UPS measurements, and the S-scheme mechanism of charge transfer was verified via the in situ XPS results. In addition, the production of HCO₃⁻, CO₃²⁻, HCOO⁻, and •CH₃ species during CO₂ reduction was confirmed using in situ diffuse reflectance Fourier transform spectrometry, and a possible mechanism of CO₂ conversion under water vapor was proposed. Benefiting from its S-scheme BiOI/Cu₂O heterojunction, the prepared catalyst showed improved photoinduced charge separation, and its photogenerated carriers with strong redox ability were preserved, thereby leading to enhanced photocatalytic performance.

Key words: S-scheme, Photocatalyst, CO₂ reduction, BiOI/Cu₂O, Sheet

点击下载补充材料PDF格式文件

王吉超, 乔秀, 史维娜, 贺景, 陈军, 张万庆. 多面体状Cu₂O修饰片状BiOI的S型异质结构筑及光催化水蒸气中CO₂转化性能研究[J]. 物理化学学报, 2023, 39(6), 2210003. doi: 10.3866/PKU.WHXB202210003

Ji-Chao Wang, Xiu Qiao, Weina Shi, Jing He, Jun Chen, Wanqing Zhang. S-Scheme Heterojunction of Cu₂O Polytope-Modified BiOI Sheet for Efficient Visible-Light-Driven CO₂ Conversion under Water Vapor[J]. Acta Phys. -Chim. Sin. 2023, 39(6), 2210003. doi: 10.3866/PKU.WHXB202210003

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB202210003

https://www.whxb.pku.edu.cn/CN/Y2023/V39/I6/2210003

图/表 6

Fig 1

Fig 2

Fig 3

Fig 4

Fig 5

Fig 6

参考文献 60

1	Chang, X.; Wang, T.; Gong, J. Energy Environ. Sci. 2016, 9 (7),2177. doi: 10.1039/c6ee00383d
2	Xu, Z.-T.; Xie, K. Chin. J. Struct. Chem. 2021, 40 (1),31. doi: 10.14102/j.cnki.0254–5861.2011–2744
3	Fu, J.; Jiang, K.; Qiu, X.; Yu, J.; Liu, M. Mater. Today 2020, 32, 222. doi: 10.1016/j.mattod.2019.06.009
4	Fung, C.-M.; Tang, J.-Y.; Tan, L.-L.; Mohamed, A. R.; Chai, S.-P. Mater. Today Sustain. 2020, 9, 100037. doi: 10.1016/j.mtsust.2020.100037
5	Pan, R.; Liu, J.; Zhang, J. ChemNanoMat 2021, 7 (7),737. doi: 10.1002/cnma.202100087
6	Wang, Z.; Hong, J.; Ng, S. -F.; Liu, W.; Huang, J.; Chen, P.; Ong, W. -J. Acta Phys. -Chim. Sin. 2021, 37, 2011033.
	王则鉴, 洪佳佳, Ng Sue-Faye, 刘雯, 黄俊杰, 陈鹏飞, Ong, W. -J. 物理化学学报, 2021, 37, 2011033. doi: 10.3866/PKU.WHXB202011033
7	He, K.; Shen, R.; Hao, L.; Li, Y.; Zhang, P.; Jiang, J.; Xin, L. Acta Phys. -Chim. Sin. 2022, 38, 2201021.
	何科林, 沈荣晨, 郝磊, 李佑稷, 张鹏, 江吉周, 李鑫物理化学学报, 2022, 38, 2201021. doi: 10.3866/PKU.WHXB202201021
8	Li, N.; Peng, J.; Shi, Z.; Zhang, P.; Li, X. Chin. J. Catal. 2022, 43 (7),1906. doi: 10.1016/s1872-2067(21)64018-4
9	Liu, S.-H.; Li, Y.; Ding, K.-N.; Chen, W.-K.; Zhang, Y.-F.; Lin, W. Chin. J. Struct. Chem. 2020, 39 (12),2068. doi: 10.14102/j.cnki.0254–5861.2011–3005
10	Zhou, Y.; Wang, Z.; Huang, L.; Zaman, S.; Lei, K.; Yue, T.; Li, Z. A.; You, B.; Xia, B. Y. Adv. Energy Mater. 2021, 11 (8),2003159. doi: 10.1002/aenm.202003159
11	Ahmad, I.; Shukrullah, S.; Naz, M. Y.; Ahmad, M.; Ahmed, E.; Liu, Y.; Hussain, A.; Iqbal, S.; Ullah, S. Adv. Colloid Interface Sci. 2022, 304, 102661. doi: 10.1016/j.cis.2022.102661
12	Wu, J.; Wang, S.; Qi, J.; Li, D.; Zhang, Z.; Liu, G.; Feng, Y. Mater. Today Energy 2022, 28, 101065. doi: 10.1016/j.mtener.2022.101065
13	Ye, L.; Jin, X.; Ji, X.; Liu, C.; Su, Y.; Xie, H.; Liu, C. Chem. Eng. J. 2016, 291, 39. doi: 10.1016/j.cej.2016.01.032
14	Lan, M.; Wang, M.; Zheng, N.; Dong, X.; Wang, Y.; Gao, J. J. Ind. Eng. Chem. 2022, 108, 109. doi: 10.1016/j.jiec.2021.12.031
15	Li, H.; Wang, D.; Miao, C.; Xia, F.; Wang, Y.; Wang, Y.; Liu, C.; Che, G. J. Environ. Chem. Eng. 2022, 10 (4),108201. doi: 10.1016/j.jece.2022.108201
16	Li, Y.; Luo, H.; Bao, Y.; Guo, S.; Lei, D.; Chen, Y. Sol. RRL 2021, 2100051. doi: 10.1002/solr.202100051
17	Liu, X.; Xiao, J.; Ma, S.; Shi, C.; Pan, L.; Zou, J. J. ChemNanoMat 2021, 7 (7),684. doi: 10.1002/cnma.202100105
18	Huang, H.; Xiao, K.; He, Y.; Zhang, T.; Dong, F.; Du, X.; Zhang, Y. Appl. Catal. B 2016, 199, 75. doi: 10.1016/j.apcatb.2016.06.020
19	Zhong, S.; Wang, B.; Zhou, H.; Li, C.; Peng, X.; Zhang, S. J. Alloy. Compd. 2019, 806, 401. doi: 10.1016/j.jallcom.2019.07.223
20	Wang, X.; Zhou, C.; Yin, L.; Zhang, R.; Liu, G. ACS Sustainable Chem. Eng. 2019, 7 (8),7900. doi: 10.1021/acssuschemeng.9b00548
21	Yang, X.; Chen, Z.; Zhao, W.; Liu, C.; Qian, X.; Chang, W.; Sun, T.; Shen, C.; Wei, G. J. Alloys Compd. 2021, 864, 15874. doi: 10.1016/j.jallcom.2021.158784
22	Alzamly, A.; Bakiro, M.; Ahmed, S. H.; Sallabi, S. M.; Al Ajeil, R. A.; Alawadhi, S. A.; Selem, H. A.; Al Meshayei, S. S. M.; Khaleel, A.; Al-Shamsi, N.; et al. J. Photochem. Photobiol. A 2019, 375, 30. doi: 10.1016/j.jphotochem.2019.01.031
23	Hou, J.; Jiang, K.; Shen, M.; Wei, R.; Wu, X.; Idrees, F.; Cao, C. Sci. Rep. 2017, 7 (1),11665. doi: 10.1038/s41598-017-12266-x
24	Bhosale, A. H.; Narra, S.; Bhosale, S. S.; Diau, E. W. J. Phys. Chem. Lett. 2022, 7987. doi: 10.1021/acs.jpclett.2c02153
25	Han, S.; Li, B.; Huang, L.; Xi, H.; Ding, Z.; Long, J. Chin. J. Struct. Chem. 2022, 41, 2201007. doi: 10.14102/j.cnki.0254-5861.2021-0026
26	Li, D.; Huang, Y.; Li, S.; Wang, C.; Li, Y.; Zhang, X.; Liu, Y. Chin. J. Catal. 2020, 41 (1),154. doi: 10.1016/s1872-2067(19)63475-3
27	Cheng, L.; Zhang, D.; Liao, Y.; Fan, J.; Xiang, Q. Chin. J. Catal. 2021, 42 (1),131. doi: 10.1016/s1872-2067(20)63623-3
28	Liu, Y.; Yu, F.; Wang, F.; Bai, S.; He, G. Chin. J. Struct. Chem. 2022, 41, 2201034. doi: 10.14102/j.cnki.0254-5861.2021-0046
29	Li, X.; Yu, J.; Jaroniec, M.; Chen, X. Chem. Rev. 2019, 119 (6),3962. doi: 10.1021/acs.chemrev.8b00400
30	Fu, J.; Xu, Q.; Low, J.; Jiang, C.; Yu, J. Appl. Catal. B 2019, 243, 556. doi: 10.1016/j.apcatb.2018.11.011
31	Xu. Q.; Zhang, L.; Cheng, B.; Fan, J.; Yu, J. Chem 2020, 6 (7),1543. doi: 10.1016/j.chempr.2020.06.010
32	Zhang, J.; Zhang, L.; Wang, W.; Yu, J. J. Chem. Phys. Lett. 2022, 13 (36),8462. doi: 10.1021/acs.jpclett.2c02125
33	Zhang, L.; Zhang, J.; Yu, H.; Yu, J. Adv. Mater. 2022, 34 (11),2107668. doi: 10.1002/adma.202107668
34	Wageh, S.; Al-Ghamdi, A, A.; Liu, L. Acta Phys. -Chim. Sin. 2021, 37 (6),2010024.
	Wageh, S.; Al-Ghamdi, A, A.; 刘丽君物理化学学报, 2021, 37 (6),2010024. doi: 10.3866/PKU.WHXB202010024
35	Li, Y.; Zhang, M.; Zhou, L.; Yang, S.; Wu, Z.; Ma, Y. Acta Phys. -Chim. Sin. 2021, 37 (6),2009030.
	李云锋, 张敏, 周亮, 杨思佳, 武占省, 马玉花物理化学学报, 2021, 37 (6),2009030. doi: 10.3866/PKU.WHXB202009030
36	Huang, Y.; Mei, F.; Zhang, J.; Dai, K.; Dawson, G. Acta Phys. -Chim. Sin. 2022, 38 (7),2108028.
	黄悦, 梅飞飞, 张金锋, 代凯, Dawson, G. 物理化学学报, 2022, 38 (7),2108028. doi: 10.3866/PKU.WHXB202108028
37	Li, S.; Cai, M.; Liu, Y.; Zhang, J.; Wang, C.; Zang, S.; Li, Y.; Zhang, P.; Li, X. Inorg. Chem. Front. 2022, 9 (11),2479. doi: 10.1039/d2qi00317a
38	Bai, J.; Shen, R.; Jiang, Z.; Zhang, P.; Li, Y.; Li, X. Chin. J. Catal. 2022, 43 (2),359. doi: 10.1016/s1872-2067(21)63883-4
39	Zhu, B.; Hong, X.; Tang, L.; Liu, Q.; Tang, H. Acta Phys. -Chim. Sin. 2022, 38 (7),2111008.
	朱弼辰, 洪小洋, 唐丽永, 刘芹芹, 唐华物理化学学报, 2022, 38 (7),2111008. doi: 10.3866/PKU.WHXB202111008
40	Zhang, B.; Wang, D.; Jiao, S.; Xu, Z.; Liu, Y.; Zhao, C.; Pan, J.; Liu, D.; Liu, G.; Jiang, B.; et al. Chem. Eng. J. 2022, 446, 137138. doi: 10.1016/j.cej.2022.137138
41	Xiao, Y.; Ji, Z.; Zou, C.; Xu, Y.; Wang, R.; Wu, J.; Liu, G.; He, P.; Wang, Q.; Jia, T. Appl. Surf. Sci. 2021, 556, 149767. doi: 10.1016/j.apsusc.2021.149767
42	Wang, J.; Li, S.; Yang, K.; Zhang, T.; Jiang, S.; Li, X.; Li, B. ACS Appl. Nano Mater. 2022, 5 (5),6736. doi: 10.1021/acsanm.2c00760
43	Wang, Z.; Cheng, B.; Zhang, L.; Yu, J.; Li, Y.; Wageh, S.; Al-Ghamdi, A. A. Chin. J. Catal. 2022, 43 (7),1657. doi: 10.1016/S1872-2067(21)64010-X
44	Guo, Y.; Dai, M.; Zhu, Z.; Chen, Y.; He, H.; Qin, T. Appl. Surf. Sci. 2019, 480, 601. doi: 10.1016/j.apsusc.2019.02.246
45	Jiang, H.; Katsumata, K.-I.; Hong, J.; Yamaguchi, A.; Nakata, K.; Terashima, C.; Matsushita, N.; Miyauchi, M.; Fujishima, A. Appl. Catal. B 2018, 224, 783. doi: 10.1016/j.apcatb.2017.11.011
46	Jiang, Y.; Xia, T.; Shen, L.; Ma, J.; Ma, H.; Sun, T.; Lv, F.; Zhu, N. ACS Catal. 2021, 11 (5),2949. doi: 10.1021/acscatal.0c04797
47	Li, L.; Zhang, R.; Vinson, J.; Shirley, E. L.; Greeley, J. P.; Guest, J. R.; Chan, M. K. Y. Chem. Mater. 2018, 30, 1912. doi: 10.1021/acs.chemmater.7b04803
48	Liu, B.; Yao, X.; Zhang, Z.; Li, C.; Zhang, J.; Wang, P.; Zhao, J.; Guo, Y.; Sun, J.; Zhao, C. ACS Appl. Mater. Interfaces 2021, 13 (33),39165. doi: 10.1021/acsami.1c03850
49	Mandal, L.; Yang, K. R.; Motapothula, M. R.; Ren, D.; Lobaccaro, P.; Patra, A.; Sherburne, M.; Batista, V. S.; Yeo, B. S.; Ager, J. W.; et al. ACS Appl. Mater. Interfaces 2018, 10 (10),8574. doi: 10.1021/acsami.7b15418
50	Zhang, Y.; Wang, Q.; Liu, D.; Wang, Q.; Li, T.; Wang, Z. Appl. Surf. Sci. 2020, 521, 146434. doi: 10.1016/j.apsusc.2020.146434
51	Ponnaiah, S. K.; Prakash, P.; Arumuganathan, T.; Jeyaprabha, B. J. Photochem. Photobiol. A 2019, 380, 111860. doi: 10.1016/j.jphotochem.2019.111860
52	Cai, J.; Xiao, Y.; Tursun, Y.; Abulizi, A. Mater. Sci. Semicond. Process. 2022, 149, 106891. doi: 10.1016/j.mssp.2022.106891
53	Chen, D.; Yang, J.; Zhu, Y.; Zhang, Y.; Zhu, Y. Appl. Catal. B 2018, 233, 202. doi: 10.1016/j.apcatb.2018.04.004
54	Shi, W.; Wang, J. C.; Chen, A.; Xu, X.; Wang, S.; Li, R.; Zhang, W.; Hou, Y. Nanomaterials 2022, 12 (13),2284. doi: 10.3390/nano12132284
55	Nogueira, A. C.; Gomes, L. E.; Ferencz, J. A. P.; Rodrigues, J. E. F. S.; Gonçalves, R. V.; Wender, H. J. Phys. Chem. C 2019, 123 (42),25680. doi: 10.1021/acs.jpcc.9b06907
56	Kramm, B.; Laufer, A.; Reppin, D.; Kronenberger, A.; Hering, P.; Polity, A.; Meyer, B. K. Appl. Phys. Lett. 2012, 100 (9),094102. doi: 10.1063/1.3685719
57	Huang, Z.; Wu, J.; Ma, M.; Wang, J.; Wu, S.; Hu, X.; Yuan, C.; Zhou, Y. New J. Chem. 2022, 46 (35),16889. doi: 10.1039/d2nj02725a
58	Su, F.; Chen, Y.; Wang, R.; Zhang, S.; Liu, K.; Zhang, Y.; Zhao, W.; Ding, C.; Xie, H.; Ye, L. Sustainable Energy Fuels 2021, 5 (4),1034. doi: 10.1039/d0se01561j
59	Kang, S.; Li, Z.; Xu, Z.; Zhang, Z.; Sun, J.; Bian, J.; Bai, L.; Qu, Y.; Jing, L. Catal. Sci. Technol. 2022, 12 (15),4817. doi: 10.1039/d2cy00713d
60	Li, N.; Wang, B.; Si, Y.; Xue, F.; Zhou, J.; Lu, Y.; Liu, M. ACS Catal. 2019, 9 (6),5590. doi: 10.1021/acscatal.9b00223

[1]	徐涵煜, 宋雪旦, 张青, 于畅, 邱介山. 理论研究Cu@C₂N催化剂表面上水分子对电催化CO₂还原反应机理的影响[J]. 物理化学学报, 2024, 40(1): 2303040 - .
[2]	昝忠奇, 李喜宝, 高晓明, 黄军同, 罗一丹, 韩露. 0D/2D碳氮量子点(CNQDs)/BiOBr复合的S型异质结高效光催化降解和产H₂O₂[J]. 物理化学学报, 2023, 39(6): 2209016 - .
[3]	吴新鹤, 陈郭强, 王娟, 李金懋, 王国宏. S-Scheme异质结光催化产氢研究进展[J]. 物理化学学报, 2023, 39(6): 2212016 -0 .
[4]	张怡宁, 高明, 陈松涛, 王会琴, 霍鹏伟. Ag/CN/ZnIn₂S₄ S型异质结等离子体光催化剂的制备及其增强光还原CO₂研究[J]. 物理化学学报, 2023, 39(6): 2211051 - .
[5]	罗铖, 龙庆, 程蓓, 朱必成, 王临曦. Pt-C₃N₄/BiOCl S型异质结应用于光催化CO₂还原的理论计算研究[J]. 物理化学学报, 2023, 39(6): 2212026 - .
[6]	张珂瑜, 李云锋, 袁仕丹, 张洛红, 王倩. S型异质结H₂O₂光催化剂的研究进展[J]. 物理化学学报, 2023, 39(6): 2212010 - .
[7]	刘真, 孟祥福, 古万苗, 查珺, 闫楠, 尤青, 夏楠, 王辉, 伍志鲲. 组合掺杂引入新型、多种镉配位方式增强金纳米团簇的电催化性能[J]. 物理化学学报, 2023, 39(12): 2212064 - .
[8]	张利君, 吴有林, Tsubaki Noritatsu, 靳治良. CeO₂-Cu₂O 2D/3D S型异质结界面促进有序电荷转移以实现高效光催化析氢[J]. 物理化学学报, 2023, 39(12): 2302051 - .
[9]	万宇彤, 方帆, 孙瑞雪, 张杰, 常焜. 金属氧化物半导体用于光热催化CO₂加氢反应：最新进展和展望[J]. 物理化学学报, 2023, 39(11): 2212042 - .
[10]	谢垚, 张启涛, 孙宏丽, 滕镇远, 苏陈良. 聚合物半导体光催化合成过氧化氢：光氧化还原中心的空间分离和协同利用[J]. 物理化学学报, 2023, 39(11): 2301001 - .
[11]	黄悦, 梅飞飞, 张金锋, 代凯, Graham Dawson. 一维/二维W₁₈O₄₉/多孔g-C₃N₄梯形异质结构建及其光催化析氢性能研究[J]. 物理化学学报, 2022, 38(7): 2108028 - .
[12]	刘珊池, 王凯, 杨梦雪, 靳治良. Mn_0.2Cd_0.8S@CoAl LDH S-型异质结构建及其光催化析氢性能研究[J]. 物理化学学报, 2022, 38(7): 2109023 - .
[13]	朱弼辰, 洪小洋, 唐丽永, 刘芹芹, 唐华. 二维/一维BiOBr_0.5Cl_0.5/WO₃ S型异质结助力光催化CO₂还原[J]. 物理化学学报, 2022, 38(7): 2111008 - .
[14]	韩高伟, 徐飞燕, 程蓓, 李佑稷, 余家国, 张留洋. 反蛋白石结构ZnO@PDA用于增强光催化产H₂O₂性能[J]. 物理化学学报, 2022, 38(7): 2112037 - .
[15]	王文亮, 张灏纯, 陈义钢, 史海峰. 具有光催化与光芬顿反应协同作用的2D/2D α-Fe₂O₃/g-C₃N₄ S型异质结用于高效降解四环素[J]. 物理化学学报, 2022, 38(7): 2201008 - .

多面体状Cu₂O修饰片状BiOI的S型异质结构筑及光催化水蒸气中CO₂转化性能研究

S-Scheme Heterojunction of Cu₂O Polytope-Modified BiOI Sheet for Efficient Visible-Light-Driven CO₂ Conversion under Water Vapor

RichHTML

PDF

赞

可视化

摘要/Abstract

支持信息

引用本文

使用本文

图/表 6

参考文献 60

相关文章 15

Metrics

推荐阅读 0