红磷纳米颗粒嵌入花状CeO2分级S型异质结高效光催化产氢

doi:10.3866/PKU.WHXB202405019

物理化学学报 >> 2024, Vol. 40 >> Issue (11): 2405019.doi: 10.3866/PKU.WHXB202405019

所属专题：太阳燃料制备

红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢

安晨烨¹, 阿比都维力∙司坎代尔¹, 郭雪¹, 朱玉坤¹^,*(), 唐华¹^,*(), 杨东江¹^,²^,*()

¹ 青岛大学环境工程学院, 山东青岛 266071
² 宁波工程学院, 微纳材料与器件创新研究院, 浙江宁波 315211

收稿日期:2024-05-23 修回日期:2024-06-21 录用日期:2024-06-24 发布日期:2024-10-14
通讯作者: Email: yukunzhu@qdu.edu.cn (朱玉坤)tanghua@qdu.edu.cn (唐华)d.yang@qdu.edu.cn (杨东江)

Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production

Chenye An¹, Sikandaier Abiduweili¹, Xue Guo¹, Yukun Zhu¹^,*(), Hua Tang¹^,*(), Dongjiang Yang¹^,²^,*()

¹ School of Environmental Science and Engineering, Qingdao University, Qingdao 266071, Shandong Province, China
² Institute of Micro/Nano Materials and Devices, Ningbo University of Technology, Ningbo 315211, Zhejiang Province, China

Received:2024-05-23 Revised:2024-06-21 Accepted:2024-06-24 Published:2024-10-14
Contact: Email: yukunzhu@qdu.edu.cn (Yukun Zhu)tanghua@qdu.edu.cn (Hua Tang)d.yang@qdu.edu.cn (Dongjiang Yang)
Supported by:
the National Natural Science Foundation of China(52102362); the National Natural Science Foundation of China(22378219); the National Natural Science Foundation of China(52302097); Taishan Scholar Program of Shandong Province(ts201712030); Taishan Scholar Program of Shandong Province(tsqn201909102); Taishan Scholar Program of Shandong Province(tstp20230665); Shandong Provincial Natural Science Foundation(ZR2021QB022); Shandong Provincial Natural Science Foundation(ZR2021ME012); Shandong Provincial Natural Science Foundation(ZR2022QE036); Technology Support Program for Youth Innovation Team of Shandong Universities(2023KJ225)

1. WHXB202405019-Si-6p.pdf(1024KB)

摘要/Abstract

摘要：

利用两种能带结构相匹配的半导体设计异质结，是实现太阳能驱动光催化制氢的重要策略之一。特别是S型异质结能够显著加速光生载流子的空间分离和迁移，同时保持较强的氧化还原能力。本文采用化学气相沉积工艺成功合成了红磷(RP)修饰的CeO₂(CeO₂/RP)的分级S型复合材料。在模拟太阳光照射下，优化的CeO₂/RP S型异质结表现出了高效的光催化产氢速率，达到297.8 μmol∙h^-1∙g^-1，分别是纯CeO₂和RP的8.8倍和5.7倍。这种高效的光催化制氢能力主要归因于界面上P—O—Ce键的存在，提供了有效的电荷转移通道，以及CeO₂和RP之间形成的内置电场。光生电荷转移路径遵循S型机制，内建电场促使CeO₂导带上的光生电子与RP价带上的光生空穴复合，从而使具有较高氧化还原电位的光生电子和空穴分别保留在RP的导带和CeO₂的价带上。这项工作为开发具有优异光催化制氢性能的S型异质结光催化系统提供了新的见解和方法。

关键词: 红磷, 二氧化铈, S型异质结, 产氢, 光催化

Abstract:

Designing heterojunctions using two semiconductors with aligned band structures is a promising strategy for solar energy-driven photocatalytic hydrogen production. Particularly, S-scheme heterojunctions exhibit significant promise for accelerating spatial separation and migration of photoexcited charge carriers while maintaining strong redox capacity. Herein, a hierarchical S-scheme composite of red phosphorus (RP) nanoparticles decorated flower-like CeO₂ (CeO₂/RP) was synthesized via the chemical vapor deposition process. Under simulated solar light irradiation, the optimized CeO₂/RP S-scheme heterojunction exhibited a highly efficient photocatalytic hydrogen production rate of 297.8 μmol·h^-1·g^-1, which is approximately 8.8 and 5.7 times greater than that of pure CeO₂ and RP, respectively. After decoration with RP, the optical absorption of CeO₂/RP is greatly expanded to the visible light region. The effective photocatalytic performance can be primarily attributed to the presence of interfacial P-O-Ce bonds providing charge transfer pathways, as well as the development of a built-in electric field between CeO₂ and RP at the intimate interface. The photogenerated electrons follow an S-scheme mechanism, the electric field drives directional charge transfer from the conduction band (CB) of CeO₂ to the valence band (VB) of RP upon exposure to light, thus enabling the retention of photoexcited electrons and holes with higher redox potential at the CB of RP and the VB of CeO₂, respectively. This work provides a novel vision in the fabrication of S-scheme photocatalytic heterojunction systems with great photocatalytic hydrogen production performance.

Key words: Red phosphorus, CeO₂, S-scheme heterojunction, Hydrogen production, Photocatalyst

安晨烨, 阿比都维力∙司坎代尔, 郭雪, 朱玉坤, 唐华, 杨东江. 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢[J]. 物理化学学报, 2024, 40(11), 2405019. doi: 10.3866/PKU.WHXB202405019

Chenye An, Sikandaier Abiduweili, Xue Guo, Yukun Zhu, Hua Tang, Dongjiang Yang. Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production[J]. Acta Phys. -Chim. Sin. 2024, 40(11), 2405019. doi: 10.3866/PKU.WHXB202405019

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB202405019

https://www.whxb.pku.edu.cn/CN/Y2024/V40/I11/2405019

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红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢

Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production

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