物理化学学报 >> 2006, Vol. 22 >> Issue (06): 756-760.doi: 10.3866/PKU.WHXB20060622

研究简报 上一篇    下一篇

阴离子对银胶凝聚作用的影响

张爱平;方炎   

  1. 首都师范大学, 北京市纳米光电子学重点实验室, 北京 100037
  • 收稿日期:2005-12-19 修回日期:2006-01-20 发布日期:2006-05-31
  • 通讯作者: 张爱平 E-mail:a.p.zhang@163.com

The Effect of Anions on Silver Colloids Aggregation

ZHANG Ai-Ping;FANG Yan   

  1. Beijing Key Laboratory for Nanophotonics and Nanostructure, Capital Normal University, Beijing 100037, P. R. China
  • Received:2005-12-19 Revised:2006-01-20 Published:2006-05-31
  • Contact: ZHANG Ai-Ping E-mail:a.p.zhang@163.com

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摘要： 借助紫外-可见吸收光谱、透射电子显微镜和拉曼光谱技术, 研究了几种阴离子(OH−、CO32−、SO42−、NO3−)对黄银胶的存在状态的影响. 研究发现, 阴离子的加入会引起胶体的凝聚和聚集体外形的改变, 造成吸收光谱长波区新峰和异常拉曼光谱信号的出现. 比较这些实验现象, 再结合相应的理论分析, 揭示了不同的阴离子和胶体间不同的作用方式和造成这些差别的可能原因.

关键词: 银溶胶, 阴离子, 紫外-可见光吸收谱, 拉曼光谱

Abstract: The aggregation effect of yellow silver colloids caused by adding some anions has been investigated with UV-Vis absorption, transmission electron microscopy (TEM), and Raman spectra. It was found that colloidal aggregation and shape changing occurred when anions were added, in addition, an absorption peak at much longer wavelength and an exceptional Raman signals appeared. The experimental results indicated that the effects of various anions were different from each other, and the possible mechanism was discussed.

Key words: Silver colloids, Anion, UV-Vis absorption spectra, Raman spectra