水热法制备NiS/Cd1-xZnxS及其高效光催化产氢性能

doi:10.3866/PKU.WHXB201411175

物理化学学报 >> 2015, Vol. 31 >> Issue (1): 153-158.doi: 10.3866/PKU.WHXB201411175

水热法制备NiS/Cd_1-xZn_xS及其高效光催化产氢性能

林彩芳, 陈小平, 陈澍, 上官文峰

上海交通大学燃烧与环境技术中心, 上海 200240

收稿日期:2014-10-08 修回日期:2014-11-17 发布日期:2014-12-25
通讯作者: 上官文峰 E-mail:shangguan@sjtu.edu.cn
基金资助:
国家高技术研究发展计划项目(863) (2012AA051501)和上海市科委国际合作项目(12160705700)资助

Preparation of NiS-Modified Cd_1-xZn_xS by a Hydrothermal Method and Its Use for the Efficient Photocatalytic H₂ Evolution

LIN Cai-Fang, CHEN Xiao-Ping, CHEN Shu, SHANGGUAN Wen-Feng

Research Center for Combustion and Environment Technology, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Received:2014-10-08 Revised:2014-11-17 Published:2014-12-25
Contact: SHANGGUAN Wen-Feng E-mail:shangguan@sjtu.edu.cn
Supported by:
The project was supported by the National High Technology Research and Development Programof China (863) (2012AA051501) and International Cooperation Project of Shanghai Municipal Science and Technology Commission, China (12160705700).

摘要/Abstract

摘要：

利用水热法制备NiS负载的Cd_1-xZn_xS光催化剂. 结果表明: 在0.35 mol·L^-1 Na₂SO₃ 和0.25 mol·L^-1 Na₂S牺牲剂下, 0.5% (摩尔分数, y) NiS/Cd_0.3Zn_0.7S (1840 μmol·h^-1)获得最好活性,是Cd_0.3Zn_0.7S (884 μmol·h^-1)的2.1倍, 高于0.5% (质量分数, w) Pt (1390 μmol·h^-1) 的产氢活性. 测得其在λ=420 nm附近的表观量子效率为36.8%. X射线衍射(XRD)、紫外-可见漫反射光谱(UV-Vis DRS)、透射电子显微镜(TEM)以及X射线光电子能谱(XPS)的表征结果表明, NiS作为产氢活性位, 转移光生电子,因此提高了光催化产氢活性.

关键词: Cd_1-xZn_xS, NiS, 水热法, 光催化活性, 产氢

Abstract:

NiS-modified Cd_1-xZn_xS has been prepared using a simple hydrothermal method. Notably, the H₂ evolution rate of 0.5% (y, molar fraction) NiS/Cd_0.3Zn_0.7S(1840 μmol·h^-1) was found to be 2.1- and 1.3-fold greater than those of Cd_0.3Zn_0.7S(884 μmol·h^-1) and 0.5% (w, mass fraction) Pt (1390 μmol·h^-1), respectively, when 0.35 mol·L^-1 Na₂SO₃ and 0.25 mol·L^-1 Na₂Swere used as sacrificial agents. The apparent quantumefficiency of 0.5% (y) NiS/Cd_0.3Zn_0.7S at 420 nm was 36.8%. The characterization of this material by X-ray diffraction (XRD), ultraviolet-visible diffuse reflection spectroscopy (UV-Vis DRS), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS) showed that the NiS particles provided the active sites required for H₂ evolution and transferring the photo generated electrons, and therefore enhanced the photocatalytic activity of the catalyst towards H₂ production.

Key words: Cd_1-xZn_xS, NiS, Hydrothermal method, Photocatalytic activity, Hydrogen production

林彩芳, 陈小平, 陈澍, 上官文峰. 水热法制备NiS/Cd_1-xZn_xS及其高效光催化产氢性能[J]. 物理化学学报, 2015, 31(1): 153-158.

LIN Cai-Fang, CHEN Xiao-Ping, CHEN Shu, SHANGGUAN Wen-Feng. Preparation of NiS-Modified Cd_1-xZn_xS by a Hydrothermal Method and Its Use for the Efficient Photocatalytic H₂ Evolution[J]. Acta Phys. -Chim. Sin., 2015, 31(1): 153-158.

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB201411175

https://www.whxb.pku.edu.cn/CN/Y2015/V31/I1/153

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水热法制备NiS/Cd_1-xZn_xS及其高效光催化产氢性能

Preparation of NiS-Modified Cd_1-xZn_xS by a Hydrothermal Method and Its Use for the Efficient Photocatalytic H₂ Evolution

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水热法制备NiS/Cd1-xZnxS及其高效光催化产氢性能

Preparation of NiS-Modified Cd1-xZnxS by a Hydrothermal Method and Its Use for the Efficient Photocatalytic H2 Evolution

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水热法制备NiS/Cd_1-xZn_xS及其高效光催化产氢性能

Preparation of NiS-Modified Cd_1-xZn_xS by a Hydrothermal Method and Its Use for the Efficient Photocatalytic H₂ Evolution