可充电池的磁共振研究

doi:10.3866/PKU.WHXB201905004

摘要/Abstract

摘要：

快速增长的对安全能源的需求，促使科研工作者不断探索高能量密度的可充锂离子电池(LIBs)。发展原位表征技术能更好地研究电池工作中的锂离子镶嵌机制和电池失效因素。固体核磁共振(NMR)能有效的测试短程化学环境：通过对¹H、^{6, 7}Li、¹¹B、¹³C、¹⁷O、¹⁹F、²³Na和³¹P等同位素来探测电池材料的微观结构。除了魔角旋转(MAS)高分辨NMR谱图研究电池材料的精细结构之外，核磁共振还能无损地捕获、研究电池材料在充放电循环中的演化。因此，原位核磁共振NMR及成像(MRI)可拓展到电池充放电循环中的锂离子的动态演化以及锂离子浓度的时空分布信息。互为补充地，电子顺磁共振(EPR)及成像(EPRI)能有效地跟踪和捕获电极过渡金属、阴氧离子(O₂^n-)的氧化还原过程。这些实时捕获的动态信息能更好地指导电极材料的构效、微观设计和电池组装的改进，最终获得优异的电化学性能。

关键词: 固体核磁共振, 电子顺磁共振, 磁共振成像, 锂离子电池, 原位表征, 构效关系, 动态演化

Abstract:

The fast-growing demand for safe energy storages with high power and energy density drives the continuous improvement of rechargeable Li-ion batteries (LIBs). In situ characterization is a potential way to understand the mechanism (metaphases, diffusion, kinetics, inhomogeneity etc.) of battery under operation conditions. Solid-state nuclear magnetic resonance (SS-NMR) is very sensitive to the local environment of ¹H, ^{6, 7}Li, ¹¹B, ¹³C, ¹⁷O, ¹⁹F, ²³Na, and ³¹P isotopes, which are widely used in battery materials, regardless of their ordering degree. In addition to providing well-resolved spectra obtained under fast magic angle spinning (MAS), NMR can effectively serve as a non-invasive tool to capture the evolution of electrodes/electrolyte upon charge/discharge electrochemical cycling. Subsequently, in situ NMR and imaging (MRI) have been developed for extending toward temporal and spatial dimensions in working batteries. Complementarily, highly sensitive electron paramagnetic resonance (EPR) and imaging (EPRI) have been employed to track and map the redox of transition metals and oxygen species (O₂ⁿ⁻) within electrodes. The insights gained from in situ NMR/EPR and their imaging can serve as a guide for the structural design of energy storage materials and the fabrication of batteries with optimized performance. As such, this review summarizes the applications of both NMR and EPR in the field of battery community. In particular, we first introduce the combination of fast magic angle spinning and phase-adjusted sideband separation (pjMATPASS) to obtain highly resolved spectra for extreme broad signal mediated by unpaired electrons, which is usually found in battery materials, as well as isotope-oriented NMR to determine the Li pathway in the composite electrolyte by the aid of ⁶Li replacing ⁷Li in their transport pathway. Secondly, we introduce the combination of NMR/MRI measurement while battery under electrochemical cycling by (1) briefly summarizing the advantages and disadvantages of home-made cells (coin cell, bag cell, and cylindrical cell) developed for in situ NMR study; (2) using different isotopes for conducting in situ NMR on batteries: ⁷Li, ²³Na, and ³¹P spectra; and (3) performing in situ MRI on electrolytes and electrodes with and without chemical shift information (CSI, S-ISIS, and stray-field MRI). Furthermore, in situ EPR determines and quantifies the evolution of active Li microstructure, transition metals, and oxygen species together with in situ EPRI mapping of the concentration of the paramagnetic center within a functioning battery. Finally, we point out the limitations and perspective of in situ NMR and EPR for cycling batteries in real-time. This review will provide illuminating insights on the magnetic technologies in the battery community and pave a way for carrying out NMR/EPR on functional materials.

Key words: Solid-state NMR, Electron paramagnetic resonance, Magnetic imaging, Lithium ion battery, In situ characterization, Structure-function relationship, Dynamic evolution

史永超, 唐明学. 可充电池的磁共振研究[J]. 物理化学学报, 2020, 36(4), 1905004. doi: 10.3866/PKU.WHXB201905004

Yongchao Shi, Mingxue Tang. NMR/EPR Investigation of Rechargeable Batteries[J]. Acta Physico-Chimica Sinica 2020, 36(4), 1905004. doi: 10.3866/PKU.WHXB201905004

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB201905004

https://www.whxb.pku.edu.cn/CN/Y2020/V36/I4/1905004

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参考文献 91

1	Armand, M.; Tarascon, J. M. 2008, 451 (7179), 652. doi: 10.1038/451652a
2	Kuhn A. ; Köhler J. ; Lotsch B. V. Phys. Chem. Chem. Phys. 2013, 15 (28), 11620. doi: 10.1039/c3cp51985f
3	Feng X. Y. ; Li X. ; Tang M. ; Gan A. ; Hu Y. Y. J. Power Sources 2017, 354, 172. doi: 10.1016/j.jpowsour.2017.04.032
4	Li X. ; Tang M. ; Feng X. ; Hung I. ; Rose A. ; Chien P. H. ; Gan Z. ; Hu Y. Y. Chem. Mater. 2017, 29 (19), 8282. doi: 10.1021/acs.chemmater.7b02589
5	Arbi K. ; Hoelzel M. ; Kuhn A. ; García-Alvarado F. ; Sanz J. Phys. Chem. Chem. Phys. 2014, 16 (34), 18397. doi: 10.1039/C4CP02938K
6	Arbi K. ; Bucheli W. ; Jiménez R. ; Sanz J. J. Eur. Ceram. Soc. 2015, 35 (5), 1477. doi: 10.1016/j.jeurceramsoc.2014.11.023
7	Feng X. ; Tang M. ; O'Neill S. ; Hu Y. Y. J. Mater. Chem. A 2018, 6 (44), 22240. doi: 10.1039/C8TA05433A
8	Wilkening M. ; Heitjans P. ChemPhysChem 2012, 13 (1), 53. doi: 10.1002/cphc.201100580
9	Bottke P. ; Rettenwander D. ; Schmidt W. ; Amthauer G. ; Wilkening M. Chem. Mater. 2015, 27 (19), 6571. doi: 10.1021/acs.chemmater.5b02231
10	Britton M. M. ; Bayley P. M. ; Howlett P. C. ; Davenport A. J. ; Forsyth M. J. Phys. Chem. Lett. 2013, 4 (17), 3019. doi: 10.1021/jz401415a
11	Ilott A. J. ; Mohammadi M. ; Schauerman C. M. ; Ganter M. J. ; Jerschow A. Nat. Commun. 2018, 9 (1), 1776. doi: 10.1038/s41467-018-04192-x
12	Messinger R. J. ; Ménétrier M. ; Salager E. ; Boulineau A. ; Duttine M. ; Carlier D. ; Ateba Mba J. M. ; Croguennec L. ; Masquelier C. ; Massiot D. ; et al Chem. Mater. 2015, 27 (15), 5212. doi: 10.1021/acs.chemmater.5b01234
13	Shadike Z. ; Zhao E. ; Zhou Y. N. ; Yu X. ; Yang Y. ; Hu E. ; Bak S. ; Gu L. ; Yang X. Q. Adv. Energy Mater. 2018, 8 (17), 1702588. doi: 10.1002/aenm.201702588
14	Daza P. C. C. ; Meneses R. A. M. ; de Almeida Ferreira J. L. ; Araujo J. A. ; Rodrigues A. C. M. ; da Silva C. R. M. Ceram. Int. 2018, 44 (2), 2138. doi: 10.1016/j.ceramint.2017.10.166
15	Hammad Fawey M. ; Chakravadhanula V. S. K. ; Reddy M. A. ; Rongeat C. ; Scherer T. ; Hahn H. ; Fichtner M. ; Kübel C. Microsc. Res. Tech. 2016, 79 (7), 615. doi: 10.1002/jemt.22675
16	Shang T. ; Wen Y. ; Xiao D. ; Gu L. ; Hu Y. S. ; Li H. Adv. Energy Mater. 2017, 7 (23), 1700709. doi: 10.1002/aenm.201700709
17	Lacivita V. ; Artrith N. ; Ceder G. Chem. Mater. 2018, 30 (20), 7077. doi: 10.1021/acs.chemmater.8b02812
18	Ilott A. J. ; Chandrashekar S. ; Klöckner A. ; Chang H. J. ; Trease N. M. ; Grey C. P. ; Greengard L. ; Jerschow A. J. Magn. Reson. 2014, 245, 143. doi: 10.1016/j.jmr.2014.06.013
19	Harks P. P. R. M. L. ; Mulder F. M. ; Notten P. H. L. J. Power Sources 2015, 288, 92. doi: 10.1016/j.jpowsour.2015.04.084
20	Pecher O. ; Carretero-González J. ; Griffith K. J. ; Grey C. P. Chem. Mater. 2017, 29 (1), 213. doi: 10.1021/acs.chemmater.6b03183
21	Zhang Z. R. ; Yang Y. ; Liu H. S. Prog. Chem. 2013, 15 (1), 18.
	张忠如; 杨勇; 刘汉三. 化学进展, 2013, 15 (1), 18.
22	Zhong G. M. ; Hou X. ; Chen S. S. ; Yang Y. Chin. Sci. Bull. 2013, 58 (32), 3287. doi: 10.1360/972013-878
	钟贵明; 侯旭; 陈守顺; 杨勇. 科学通报, 2013, 58 (32), 3287. doi: 10.1360/972013-878
23	Zhong G. M. ; Liu Z. G. ; Wang D. W. ; Li Q. ; Fu R. Q. ; Yang Y. J. Electrochem. 2016, 22 (3), 231. doi: 10.13208/j.electrochem.151246
	钟贵明; 刘子庚; 王大为; 李琦; 傅日强; 杨勇. 电化学, 2016, 22 (3), 231. doi: 10.13208/j.electrochem.151246
24	Liu X. S. ; Xiang Y. X. ; Zhong G. M. ; Li Q. ; Zheng S. X. ; Fu R. Q. ; Yang Y. Chin. J. Power Sources 2019, 43 (1), 5.
	刘湘思; 向宇轩; 钟贵明; 李琦; 郑时尧; 傅日强; 杨勇. 电源技术, 2019, 43 (1), 5.
25	Li C. ; Shen M. ; Hu B. Acta Phys. -Chim. Sin. 2020, 36 (4), 1902019. doi: 10.3866/PKU.WHXB201902019
	李超; 沈明; 胡炳文. 物理化学学报, 2020, 36 (4), 1902019. doi: 10.3866/PKU.WHXB201902019
26	Hain H. ; Scheuermann M. ; Heinzmann R. ; Wünsche L. ; Hahn H. ; Indris S. Z. Für Anorg. Allg. Chem. 2012, 638 (10), 1581. doi: 10.1002/zaac.201204029
27	Murakami M. ; Noda Y. ; Koyama Y. ; Takegoshi K. ; Arai H. ; Uchimoto Y. ; Ogumi Z. J. Phys. Chem. C 2014, 118 (28), 15375. doi: 10.1021/jp5039909
28	Salager E. ; Sarou-Kanian V. ; Sathiya M. ; Tang M. ; Leriche J. B. ; Melin P. ; Wang Z. ; Vezin H. ; Bessada C. ; Deschamps M. ; et al Chem. Mater. 2014, 26 (24), 7009. doi: 10.1021/cm503280s
29	Hung I. ; Zhou L. ; Pourpoint F. ; Grey C. P. ; Gan Z. J. Am. Chem. Soc. 2012, 134 (4), 1898. doi: 10.1021/ja209600m
30	Zheng J. ; Tang M. ; Hu Y. Y. Angew. Chem. Int. Ed. 2016, 55 (40), 12538. doi: 10.1002/anie.201607539
31	Zheng J. ; Hu Y. Y. ACS Appl. Mater. Interfaces 2018, 10 (4), 4113. doi: 10.1021/acsami.7b17301
32	Li S. H. ; Li J. ; Zheng A. M. ; Deng F. Acta Phys. -Chim. Sin. 2017, 33 (2), 270. doi: 10.3866/PKU.WHXB201611022
	李申慧; 李静; 郑安民; 邓风. 物理化学学报, 2017, 33 (2), 270. doi: 10.3866/PKU.WHXB201611022
33	Shi F. ; Hu L. ; Ren J. ; Yang Q. Acta Phys. -Chim. Sin. 2020, 36 (4), 1902018. doi: 10.3866/PKU.WHXB201902018
	石峰; 胡丽丽; 任进军; 杨秋红. 物理化学学报, 2020, 36 (4), 1902018. doi: 10.3866/PKU.WHXB201902018
34	Liu X. ; Wang Q. ; Wang C. ; Xu J. ; Deng F. Acta Phys. -Chim. Sin. 2020, 36 (4), 1905035. doi: 10.3866/PKU.WHXB201905035
	刘小龙; 王强; 王超; 徐君; 邓风. 物理化学学报, 2020, 36 (4), 1905035. doi: 10.3866/PKU.WHXB201905035
35	Ji, Y.; Liang, L.; Guo, C.; Polenova, T.; Hou, G. Acta Phys. -Chim. Sin. 2020, 36 (4), 1905029.
	纪毅,梁力鑫, Guo C.,包信和, Polenova T.,侯广进.物理化学学报, 2020, 36 (4), 1905029. doi: 10.3866/PKU.WHXB201905029
36	Li Y. ; Wu X. ; Liu C. ; Wang M. ; Song B. ; Yu G. ; Yang G. ; Hou W. ; Gong X. ; Peng L. Acta Phys. -Chim. Sin. 2020, 36 (4), 1905021. doi: 10.3866/PKU.WHXB201905021
	李玉红; 吴新平; 刘聪; 王萌; 宋本腾; 郁桂云; 杨刚; 侯文华; 龚学庆; 彭路明. 物理化学学报, 2020, 36 (4), 1905021. doi: 10.3866/PKU.WHXB201905021
37	Ji W. ; Shen R. ; Yang R. ; Yu G. ; Guo X. ; Peng L. ; Ding W. J. Mater. Chem. A 2014, 2 (3), 699. doi: 10.1039/C3TA13708B
38	Wang D. ; Zhong G. ; Pang W. K. ; Guo Z. ; Li Y. ; McDonald M. J. ; Fu R. ; Mi J. X. ; Yang Y. Chem. Mater. 2015, 27 (19), 6650. doi: 10.1021/acs.chemmater.5b02429
39	Xiang Y. X. ; Zheng G. ; Zhong G. ; Wang D. ; Fu R. ; Yang Y. Solid State Ion. 2018, 318, 19. doi: 10.1016/j.ssi.2017.11.025
40	Jiang Y. ; Yan X. ; Ma Z. ; Mei P. ; Xiao W. ; You Q. ; Zhang Y. Polymers 2018, 10 (11), 1237. doi: 10.3390/polym10111237
41	Yan X. ; Peng B. ; Hu B. ; Chen Q. Polymer 2016, 99, 44. doi: 10.1016/j.polymer.2016.06.056
42	Gao L. ; Chen J. ; Liu Y. ; Yamauchi Y. ; Huang Z. ; Kong X. J. Mater. Chem. A 2018, 6 (25), 12012. doi: 10.1039/C8TA03436B
43	Gerald, R. E.; Klingler, R. J.; Rathke, J. W.; Sand, G.; Woelk, K. In Situ Imaging of Charge Carriers in an Electrochemical Cell. In Spatially Resolved Magnetic Resonance; Blmler, P., Blmich, B., Botto, R., Fukushima, E., Eds.; Wiley-VCH Verlag GmbH: Weinheim, Germany, 1998; pp 111–119.
44	Bhattacharyya R. ; Key B. ; Chen H. ; Best A. S. ; Hollenkamp A. F. ; Grey C. P. Nat. Mater. 2010, 9 (6), 504. doi: 10.1038/nmat2764
45	Grey C. P. ; Tarascon J. M. Nat. Mater. 2017, 16 (1), 45. doi: 10.1038/nmat4777
46	Krachkovskiy S. A. ; Bazak J. D. ; Werhun P. ; Balcom B. J. ; Halalay I. C. ; Goward G. R. J. Am. Chem. Soc. 2016, 138 (25), 7992. doi: 10.1021/jacs.6b04226
47	Abbrent S. ; Greenbaum S. Curr. Opin. Colloid Interface Sci. 2013, 18 (3), 228. doi: 10.1016/j.cocis.2013.03.008
48	Chandrashekar S. ; Trease N. M. ; Chang H. J. ; Du L. S. ; Grey C. P. ; Jerschow A. Nat. Mater. 2012, 11 (4), 311. doi: 10.1038/nmat3246
49	Tang J. A. ; Dugar S. ; Zhong G. ; Dalal N. S. ; Zheng J. P. ; Yang Y. ; Fu R. Sci. Rep. 2013, 3 (1), 1408. doi: 10.1038/srep02596
50	Tang M. ; Sarou-Kanian V. ; Melin P. ; Leriche J. B. ; Ménétrier M. ; Tarascon J. M. ; Deschamps M. ; Salager E. Nat. Commun. 2016, 7 (1), 13284. doi: 10.1038/ncomms13284
51	Zhong G. ; Bai J. ; Duchesne P. N. ; McDonald M. J. ; Li Q. ; Hou X. ; Tang J. A. ; Wang Y. ; Zhao W. ; Gong Z. ; et al Chem. Mater. 2015, 27 (16), 5736. doi: 10.1021/acs.chemmater.5b02290
52	Li C. ; Shen M. ; Lou X. ; Hu B. J. Phys. Chem. C 2018, 122 (48), 27224. doi: 10.1021/acs.jpcc.8b09151
53	Ii R. E. G. ; Klingler R. J. ; Sandı G. ; Johnson C. S. ; Scanlon L. G. ; Rathke J. W. J. Power Sources 2000, 89 (2), 237. doi: 10.1016/S0378-7753(00)00435-3
54	Chevallier F. ; Letellier M. ; Morcrette M. ; Tarascon J. M. ; Frackowiak E. ; Rouzaud J. N. ; Béguin F. Electrochem. Solid-State Lett. 2003, 6 (11), A225. doi: 10.1149/1.1612011
55	Letellier M. ; Chevallier F. ; Clinard C. ; Frackowiak E. ; Rouzaud J. N. ; Béguin F. ; Morcrette M. ; Tarascon J. M. J. Chem. Phys. 2003, 118 (13), 6038. doi: 10.1063/1.1556092
56	Letellier M. ; Chevallier F. ; Morcrette M. Carbon 2007, 45 (5), 1025. doi: 10.1016/j.carbon.2006.12.018
57	Poli F. ; Kshetrimayum J. S. ; Monconduit L. ; Letellier M. Electrochem. Commun. 2011, 13 (12), 1293. doi: 10.1016/j.elecom.2011.07.019
58	Klett M. ; Giesecke M. ; Nyman A. ; Hallberg F. ; Lindström R. W. ; Lindbergh G. ; Furó I. J. Am. Chem. Soc. 2012, 134 (36), 14654. doi: 10.1021/ja305461j
59	Trease N. M. ; Zhou L. ; Chang H. J. ; Zhu B. Y. ; Grey C. P. Solid State Nucl. Magn. Reson. 2012, 42, 62. doi: 10.1016/j.ssnmr.2012.01.004
60	Chevallier F. ; Poli F. ; Montigny B. ; Letellier M. Carbon 2013, 61, 140. doi: 10.1016/j.carbon.2013.04.078
61	Krachkovskiy S. A. ; Pauric ; Allen. D. ; Halalay I. C. ; Goward G. R. J. Phys. Chem. Lett. 2013, 4 (22), 3940. doi: 10.1021/jz402103f
62	Shimoda K. ; Murakami M. ; Takamatsu D. ; Arai H. ; Uchimoto Y. ; Ogumi Z. Electrochimica Acta 2013, 108, 343. doi: 10.1016/j.electacta.2013.06.120
63	Romanenko K. ; Forsyth M. ; O'Dell L. A. J. Magn. Reson. 2014, 248, 96. doi: 10.1016/j.jmr.2014.09.017
64	Chang H. J. ; Ilott A. J. ; Trease N. M. ; Mohammadi M. ; Jerschow A. ; Grey C. P. J. Am. Chem. Soc. 2015, 137 (48), 15209. doi: 10.1021/jacs.5b09385
65	Chang H. J. ; Trease N. M. ; Ilott A. J. ; Zeng D. ; Du L. S. ; Jerschow A. ; Grey C. P. J. Phys. Chem. C 2015, 119 (29), 16443. doi: 10.1021/acs.jpcc.5b03396
66	Klamor S. ; Zick K. ; Oerther T. ; Schappacher F. M. ; Winter M. ; Brunklaus G. Phys. Chem. Chem. Phys. 2015, 17 (6), 4458. doi: 10.1039/C4CP05021E
67	Sethurajan A. K. ; Krachkovskiy S. A. ; Halalay I. C. ; Goward G. R. ; Protas B. J. Phys. Chem. B 2015, 119 (37), 12238. doi: 10.1021/acs.jpcb.5b04300
68	Romanenko K. ; Jin L. ; Howlett P. ; Forsyth M. Chem. Mater. 2016, 28 (8), 2844. doi: 10.1021/acs.chemmater.6b00797
69	Kayser S. A. ; Mester A. ; Mertens A. ; Jakes P. ; Eichel R. A. ; Granwehr J. Phys. Chem. Chem. Phys. 2018, 20 (20), 13765. doi: 10.1039/C8CP01067F
70	Chien P. H. ; Feng X. ; Tang M. ; Rosenberg J. T. ; O'Neill S. ; Zheng J. ; Grant S. C. ; Hu Y. Y. J. Phys. Chem. Lett. 2018, 9 (8), 1990. doi: 10.1021/acs.jpclett.8b00240
71	Key B. ; Bhattacharyya R. ; Morcrette M. ; Seznéc V. ; Tarascon J. M. ; Grey C. P. J. Am. Chem. Soc. 2009, 131 (26), 9239. doi: 10.1021/ja8086278
72	Bayley P. M. ; Trease N. M. ; Grey C. P. J. Am. Chem. Soc. 2016, 138 (6), 1955. doi: 10.1021/jacs.5b12423
73	Britton M. M. Spectrosc. 2017, 101, 51. doi: 10.1016/j.pnmrs.2017.03.001
74	Krachkovskiy S. A. ; Foster J. M. ; Bazak J. D. ; Balcom B. J. ; Goward G. R. J. Phys. Chem. C 2018, 122 (38), 21784. doi: 10.1021/acs.jpcc.8b06563
75	Ilott A. J. ; Trease N. M. ; Grey C. P. ; Jerschow A. Nat. Commun. 2014, 5 (1), 4536. doi: 10.1038/ncomms5536
76	Gourier D. ; Tranchant A. ; Baffier N. ; Messina R. Electrochim. Acta 1992, 37 (15), 2755. doi: 10.1016/0013-4686(92)85203-W
77	Alcántara R. ; Lavela P. ; Tirado J. L. ; Zhecheva E. ; Stoyanova R. J. Electroanal. Chem. 1998, 454 (1–2), 173. doi: 10.1016/S0022-0728(98)00278-2
78	Stoyanova R. K. ; Zhecheva E. N. ; Gorova M. Y. J. Mater. Chem. 2000, 10 (6), 1377. doi: 10.1039/A909066E
79	Alcántara R. ; Ortiz G. F. ; Lavela P. ; Tirado J. L. ; Stoyanova R. ; Zhecheva E. Chem. Mater. 2006, 18 (9), 2293. doi: 10.1021/cm060060p
80	Zhecheva E. ; Stoyanova R. ; Shinova E. Mater. Sci. 2007, 42 (10), 3343. doi: 10.1007/s10853-006-0744-x
81	Jakes P. ; Erdem E. ; Ozarowski A. ; Tol J. ; van Buckan R. ; Mikhailova D. ; Ehrenberg H. ; Eichel R. A. Phys. Chem. Chem. Phys. 2011, 13 (20), 9344. doi: 10.1039/C0CP02048F
82	Stoyanova R. ; Ivanova S. ; Zhecheva E. ; Samoson A. ; Simova S. ; Tzvetkova P. ; Barra A. L. Phys. Chem. Chem. Phys. 2014, 16 (6), 2499. doi: 10.1039/C3CP54438A
83	Pal D. ; Abdi S. H. ; Shukla M. J. Mater. Sci. Mater. Electron. 2015, 26 (9), 6647. doi: 10.1007/s10854-015-3265-z
84	Sathiya M. ; Rousse G. ; Ramesha K. ; Laisa C. P. ; Vezin H. ; Sougrati M. T. ; Doublet M. L. ; Foix D. ; Gonbeau D. ; Walker W. ; et al Nat. Mater. 2013, 12 (9), 827. doi: 10.1038/nmat3699
85	Senguttuvan P. ; Rousse G. ; Arroyo y de Dompablo M. E. ; Vezin H. ; Tarascon J. M. ; Palacín M. R. J. Am. Chem. Soc. 2013, 135 (10), 3897. doi: 10.1021/ja311044t
86	Sathiya M. ; Leriche J. B. ; Salager E. ; Gourier D. ; Tarascon J. M. ; Vezin H. Nat. Commun. 2015, 6 (1), 6276. doi: 10.1038/ncomms7276
87	Wandt J. ; Marino C. ; Gasteiger H. A. ; Jakes P. ; Eichel R. A. ; Granwehr J. Energy Environ. Sci. 2015, 8 (4), 1358. doi: 10.1039/C4EE02730B
88	Tang M. ; Dalzini A. ; Li X. ; Feng X. ; Chien P. H. ; Song L. ; Hu Y. Y. J. Phys. Chem. Lett. 2017, 8 (17), 4009. doi: 10.1021/acs.jpclett.7b01425
89	Niemöller A. ; Jakes P. ; Eichel R. A. ; Granwehr J. Sci. Rep. 2018, 8 (1), 14331. doi: 10.1038/s41598-018-32112-y
90	Wandt J. ; Jakes P. ; Granwehr J. ; Eichel R. A. ; Gasteiger H. A. Mater. Today 2018, 21 (3), 231. doi: 10.1016/j.mattod.2017.11.001
91	Blanc F. ; Leskes M. ; Grey C. P. Acc. Chem. Res. 2013, 46 (9), 1952. doi: 10.1021/ar400022u

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