具有0D/2D界面的InOOH/ZnIn2S4空心球S型异质结用于增强光催化CO2转化性能

doi:10.3866/PKU.WHXB202407002

物理化学学报 >> 2024, Vol. 40 >> Issue (11): 2407002.doi: 10.3866/PKU.WHXB202407002

所属专题：太阳燃料制备

具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能

蔡佳星¹^,†, 徐文迪³^,†, 迟浩强⁴, 刘倩¹, 高娃¹^,*(), 史丽³^,*(), 刘敬祥¹^,⁵^,*(), 邹志刚⁴, 周勇²^,⁴^,*()

¹ 天津工业大学物理科学与技术学院, 天津 300387
² 安徽工业大学化学与环境工程学院, 安徽芜湖 241000
³ 南京邮电大学有机电子与信息显示国家重点实验室, 先进材料研究所(IAM), 南京 210023
⁴ 南京大学物理学院, 江苏省纳米技术重点实验室, 生态材料与可再生能源研究中心, 固态微结构国家实验室, 先进微结构协同创新中心, 南京 210093
⁵ Multidisciplinary Platform of Advanced Engineering, Chemical Engineering Discipline, School of Engineering, Monash University Malaysia, Bandar Sunway 47500, Selangor, Malaysia

收稿日期:2024-07-02 修回日期:2024-08-05 录用日期:2024-08-05 发布日期:2024-10-14
通讯作者: Email: gaowa@tiangong.edu.cn (高娃)iamlshi@njupt.edu.cn (史丽)jxlow@tiangong.edu.cn (刘敬祥)zhouyong1999@nju.edu.cn (周勇)
作者简介:
^†These authors contributed equally to this work.
基金资助:
国家重点研发计划(2022YFE0126500); 国家重点研发计划(2018YFE0208500); 国家自然科学基金委员会项目(21972065); 国家自然科学基金委员会项目(22203046); 国家自然科学基金委员会项目(22202152); 江苏省科学基金会(BK20220006); 合肥微尺度物理科学国家实验室(KF2020006); 广东省创新创业团队引进项目(2019ZL08L101); 中国高校发展基金(UDF01001159); 南京邮电大学有机电子与信息显示国家重点实验室项目(GZR2023010003); 南京邮电大学自然科学研究创业人才招聘基金(NY221128)

Highly Efficient InOOH/ZnIn₂S₄ Hollow Sphere S-Scheme Heterojunction with 0D/2D Interface for Enhancing Photocatalytic CO₂ Conversion

Jiaxing Cai¹, Wendi Xu³, Haoqiang Chi⁴, Qian Liu¹, Wa Gao¹^,*(), Li Shi³^,*(), Jingxiang Low¹^,⁵^,*(), Zhigang Zou⁴, Yong Zhou²^,⁴^,*()

¹ School of Physical Science and Technology, Tiangong University, Tianjin 300387, China
² School of Chemical and Environmental Engineering, Anhui Polytechnic University, Wuhu 241000, Anhui Province, China
³ State Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Nanjing University of Posts and Telecommunications, Nanjing 210023, China
⁴ School of Physics, Jiangsu Key Laboratory of Nanotechnology, Eco-materials and Renewable Energy Research Center (ERERC), National Laboratory of Solid State Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China
⁵ Multidisciplinary Platform of Advanced Engineering, Chemical Engineering Discipline, School of Engineering, Monash University Malaysia, Bandar Sunway 47500, Selangor, Malaysia

Received:2024-07-02 Revised:2024-08-05 Accepted:2024-08-05 Published:2024-10-14
Contact: Email: gaowa@tiangong.edu.cn (Wa Gao)iamlshi@njupt.edu.cn (Li Shi)jxlow@tiangong.edu.cn (Jingxiang Low)zhouyong1999@nju.edu.cn (Yong Zhou)
Supported by:
the National Key R & D Program of China(2022YFE0126500); the National Key R & D Program of China(2018YFE0208500); the National Natural Science Foundation of China(21972065); the National Natural Science Foundation of China(22203046); the National Natural Science Foundation of China(22202152); the Natural Science Foundation of Jiangsu Province(BK20220006); the Hefei National Laboratory for Physical Sciences at the Microscale(KF2020006); the Program for Guangdong Introducing Innovative and Entrepreneurial Team(2019ZL08L101); the Chinese University Development Fund(UDF01001159); the Project of State Key Laboratory of Organic Electronics and Information Displays, Nanjing University of Posts and Telecommunications(GZR2023010003); Natural Science Research Start-up Foundation of Recruiting Talents of Nanjing University of Posts and Telecommunications(NY221128)

1. WHXB202407002-SI-6p.pdf(757KB)

摘要/Abstract

摘要：

S型异质结光催化剂因其能够同时促进光生载流子的分离，并优化光催化剂的还原和氧化能力，而被广泛应用于光催化CO₂转化中。尽管S型异质结具有巨大的潜力，但其光催化CO₂转化性能仍然有限，这主要是由于其界面光生载流子迁移缓慢和光利用效率差。本文报道了一种具有0D/2D接触界面的InOOH/ZnIn₂S₄空心球S型异质结，以提高光催化CO₂转化性能。具体来说，空心球结构可以允许入射光在光催化剂内进行多重反射，以增强光利用效率。此外，0D/2D接触界面可以促进光生载流子在InOOH/ZnIn₂S₄空心球S型异质结上的迁移速率。结合原位光照X射线光电子能谱表征和自由基捕获实验，确认了InOOH和ZnIn₂S₄上光生空穴和电子的空间分离，有利于高效利用光生载流子进行光催化CO₂转化。因此，优化后的InOOH/ZnIn₂S₄展示了比原始ZnIn₂S₄高出25.8倍的光催化CO₂转化性能。本工作展示了一种简单而有效的策略，用于提高S型异质结的界面光电荷载流子迁移和光利用效率。

关键词: 光催化CO₂转化, S型异质结, ZnIn₂S₄, 空心球, 接触界面

Abstract:

S-scheme heterojunction system represents a highly efficient strategy for photocatalytic applications as it can simultaneously facilitate photogenerated charge carrier separation and enhance the reduction-oxidation potentials of the photocatalyst. Despite its gigantic potential, the photocatalytic CO₂ conversion efficiency of the S-scheme heterojunction remains limited mainly attributed to the sluggish interfacial charge carrier migration and poor light utilization efficiency. Herein, we prepare an InOOH/ZnIn₂S₄ hollow sphere S-scheme heterojunction with 0D/2D contact interface for enhancing photocatalytic CO₂ conversion performance. Specifically, the hollow sphere morphology can cause the multireflection of incident light within the photocatalyst leading to enhanced light absorption of the photocatalyst. In addition, the 0D/2D contact interface can facilitate the photogenerated charge carrier migration transfer over the InOOH/ZnIn₂S₄ S-scheme heterojunction. Furthermore, combining in situ irradiated X-ray photoelectron spectroscopy (ISI-XPS) characterization and radicals trapping test, it is affirmed the accumulation of photogenerated holes and electrons respectively on InOOH and ZnIn₂S₄, which is beneficial for the effective utilization of photogenerated charge carriers. As a result, the photocatalytic CO₂ conversion performance of the optimized InOOH/ZnIn₂S₄ is ca. 25.8 times higher than that of pristine ZnIn₂S₄. Our reported results demonstrate a facile yet effective strategy for enhancing the interfacial photogenerated charge carrier migration and light utilization efficiency of S-scheme heterojunction.

Key words: Photocatalytic CO₂ conversion, S-scheme heterojunction, ZnIn₂S₄, Hollow sphere, Contact interface

蔡佳星, 徐文迪, 迟浩强, 刘倩, 高娃, 史丽, 刘敬祥, 邹志刚, 周勇. 具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能[J]. 物理化学学报, 2024, 40(11), 2407002. doi: 10.3866/PKU.WHXB202407002

Jiaxing Cai, Wendi Xu, Haoqiang Chi, Qian Liu, Wa Gao, Li Shi, Jingxiang Low, Zhigang Zou, Yong Zhou. Highly Efficient InOOH/ZnIn₂S₄ Hollow Sphere S-Scheme Heterojunction with 0D/2D Interface for Enhancing Photocatalytic CO₂ Conversion[J]. Acta Phys. -Chim. Sin. 2024, 40(11), 2407002. doi: 10.3866/PKU.WHXB202407002

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB202407002

https://www.whxb.pku.edu.cn/CN/Y2024/V40/I11/2407002

图/表 6

参考文献 59

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具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能

Highly Efficient InOOH/ZnIn₂S₄ Hollow Sphere S-Scheme Heterojunction with 0D/2D Interface for Enhancing Photocatalytic CO₂ Conversion

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