物理化学学报 >> 1993, Vol. 9 >> Issue (02): 277-280.doi: 10.3866/PKU.WHXB19930226

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导电聚合物单体的光电聚合

陈衍珍; 辜志俊; 田中群   

  1. 厦门大学化学系，厦门 361005
  • 收稿日期:1992-02-10 修回日期:1992-08-19 发布日期:1993-04-15
  • 通讯作者:

Photoelectrochemical Polymerization of Conducting Polymer Monomers

Chen Yan-Zhen; Gu Zhi-Jun; Tian Zhong-Qun   

  1. Department of Chemistry, Xiamen University, Xiamen 361005
  • Received:1992-02-10 Revised:1992-08-19 Published:1993-04-15
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关键词: 光电聚合, 导电聚合物, 聚苯胺, 聚吡咯, 聚噻吩

Abstract: The photoelectrochemical polymerization process: monomer first polymerizes into low polymer and then the low polymer may be oxidized into polymerfilm.
monomer→low polymer→polymerfilm
Irradiation can accelerate the formation of low polymer. The rate of the first step for pyrrole and thiophene is slow, and the second step for aniline is slow. When the film is formed, it can speed up the rate of film formation.

Key words: Photoelectrochemical polymerization, Conducting polymer, Polyaniline, Polypurrole, Polythiophene