物理化学学报 >> 2001, Vol. 17 >> Issue (03): 252-256.doi: 10.3866/PKU.WHXB20010314

研究简报 上一篇    下一篇

制备导电聚合物-半导体纳米颗粒自组装膜

李东升;吕功煊   

  1. 中国科学院兰州化学物理研究所 羰基合成与选择氧化国家重点实验室,兰州 730000
  • 收稿日期:2000-06-06 修回日期:2000-11-21 发布日期:2001-03-15
  • 通讯作者: 吕功煊 E-mail:gxlu@ns.lzb.ac.cn

Synthesis of Conductive Polymer/Semiconductor Nanocomposite Films by Layerbylayer Assembly Techniques

Li Dong-Sheng;Lu Gong-Xuan   

  1. State Key Laboratory for Oxo Synthesis & Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese Academy of Science, Lanzhou 730000
  • Received:2000-06-06 Revised:2000-11-21 Published:2001-03-15
  • Contact: Lu Gong-Xuan E-mail:gxlu@ns.lzb.ac.cn

关键词: 逐层自组装, 纳米结构复合膜, 制备

Abstract: Using layerbylayer selfassembly technique,we have successfully c onstructed nanostructured composite films of conjugated polymer (sulfonic acid r ing substituted polyaniline, SPAn)/ semiconductor nanoparticles(QCdS).The proc esses synthesis have been studied by UVVis, contact angle measurement, XPS and AFM techniques.The results indicated that the selfassembly processes were dep endent on the pH of the solution of each component and the doping time.It has be en found that the roughness of the assembled nanocomposite films increases as the layer number increases.The main reason can be attributed to the generation o f adsorption defects from partially adsorbed film surface in film fabrication pr ocesses.

Key words: Layer-by-layer self-assembly, Nanocomposite films, Preparation