S型异质结H2O2光催化剂的研究进展

doi:10.3866/PKU.WHXB202212010

摘要/Abstract

摘要：

随着现代经济和工业的快速发展，传统化石能源的过度开发和消耗造成了日益严重的环境污染和能源危机，极大地威胁着我们的健康和生活。我们需要开发新的可持续技术来解决日益恶化的环境和能源问题。太阳能作为一种绿色、可持续的清洁能源，在过去几十年中受到了广泛的关注。因此，开发和利用太阳能对解决当前面临的问题具有重要意义。半导体光催化技术是一种太阳能驱动的半导体材料表面催化反应过程，可利用太阳能并将其转化为其他能源，用于进一步的能量存储和应用。目前，制备高效稳定的光催化剂仍然是一个巨大的挑战。最近，为了解决传统异质结光催化剂电荷转移过程中的缺点和不足，一种新型梯形(S型)异质结概念被首次提出。S型异质结不仅有效地解决了电荷转移问题，实现了载流子的快速分离，而且保留了光催化体系最强的氧化还原能力，提高其光催化性能。到目前为止，各种S型异质结已被开发并应用于太阳能转化可用化学燃料领域以减少化石燃料的使用。此外，S型异质结也可用于降解污染物，以减少化石燃料的消耗所造成对环境恶化的影响。过氧化氢(H₂O₂)作为一种有效、多用途、绿色的氧化剂，已应用于诸多领域，包括污染物净化、医疗消毒和化学合成。它还可以用作燃料电池的高密度能量载体，仅以水和氧作为副产物。光催化技术提供了一种低成本、环保且安全的方法来生产H₂O₂，并只需要太阳能、H₂O和气态氧作为原料。本文综述了用于光催化生成H₂O₂的新型S型异质结，包括g-C₃N₄基S型异质结、硫化物基S型异质结、TiO₂基S型异质结和ZnO基S型异质结等，并讨论了光催化生成H₂O₂的主要原理和S型异质结的形成机理。此外，本文总结了S型异质结的一些有效的先进表征方法。最后，根据目前的研究进展，确定了未来研究所面临的挑战和可能的发展方向，为设计开发用于制备H₂O₂的高性能光催化剂提供了新的途径。

关键词: 光催化, S型异质结, H₂O₂制备, 电荷转移

Abstract:

Rapid industrialization throughout the 20th and 21st centuries has led to the excessive consumption of fossil fuels to satisfy global energy demands. The dominant use of these fuel sources is the main cause of the ever-increasing environmental issues that greatly threaten humanity. Therefore, the development of renewable energy sources is fundamental to solving environmental issues. Solar energy has received widespread attention over the past decades as a green and sustainable energy source. Solar radiation-induced photocatalytic processes on the surface of semiconductor materials are able to convert solar energy into other energy sources for storage and further applications. However, the preparation of highly efficient and stable photocatalysts remains challenging. Recently, a new step-scheme (S-scheme) carrier migration mechanism was reported that solves the drawbacks of carrier migration in conventional heterojunction photocatalysts. The S-scheme heterojunction not only effectively solves the carrier migration problem and achieves fast separation but also preserves the powerful redox abilities and improves the catalytic performance of the photocatalytic system. To date, various S-scheme heterojunctions have been developed and employed to convert solar energy into useful chemical fuels to decrease the reliance on fossil fuels. Furthermore, these systems can also be used to degrade pollutants and reduce the harmful impact on the environment associated with the consumption of fossil fuels, including H₂ evolution, pollutant degradation, and the reduction of CO₂. H₂O₂ has been used as an effective, multipurpose, and green oxidizing agent in many applications including pollutant purification, medical disinfection, and chemical synthesis. It has also been used as a high-density energy carrier for fuel cells, with only water and oxygen produced as by-products. Photocatalytic technology provides a low-cost, environmentally friendly, and safe way to produce H₂O₂, requiring only solar energy, H₂O, and O₂ gas as raw materials. This paper reviews new S-scheme heterojunction designs for photocatalytic H₂O₂ production, including g-C₃N₄-, sulfide-, TiO₂-, and ZnO-based S-scheme heterojunctions. The main principles of photocatalytic H₂O₂ production and the formation mechanism of the S-scheme heterojunction are also discussed. In addition, effective advanced characterization methods for S-scheme heterojunctions have been analyzed. Finally, the challenges that need to be addressed and the direction of future research are identified to provide new methods for the development of high-performance photocatalysts for H₂O₂ production.

Key words: Photocatalysis, S-scheme heterojunction, H₂O₂ generation, Charge transfer

张珂瑜, 李云锋, 袁仕丹, 张洛红, 王倩. S型异质结H₂O₂光催化剂的研究进展[J]. 物理化学学报, 2023, 39(6), 2212010. doi: 10.3866/PKU.WHXB202212010

Keyu Zhang, Yunfeng Li, Shidan Yuan, Luohong Zhang, Qian Wang. Review of S-Scheme Heterojunction Photocatalyst for H₂O₂ Production[J]. Acta Phys. -Chim. Sin. 2023, 39(6), 2212010. doi: 10.3866/PKU.WHXB202212010

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB202212010

https://www.whxb.pku.edu.cn/CN/Y2023/V39/I6/2212010

图/表 18

Fig 1

Fig 2

Fig 3

Fig 4

Fig 5

Fig 6

Fig 7

Fig 8

Fig 9

Fig 10

Fig 11

Fig 12

Fig 13

Fig 14

Fig 15

Fig 16

Fig 17

Fig 18

参考文献 100

1	Sayed, M.; Yu, J.; Liu, G.; Jaroniec, M. Chem. Rev. 2022, 122, 10484. doi: 10.1021/acs.chemrev.1c00473
2	Hasija, V.; Kumar, A.; Sudhaik, A.; Raizada, P.; Singh, P.; Le, Q.; Le, T.; Nguyen, V. Chem. Lett. 2021, 19, 2941. doi: 10.1007/s10311-021-01231-w
3	Kumar, A.; Khosla, A.; Sharma, S.; Dhiman, P.; Sharma, G.; Gnanasekaran, L.; Naushad, M.; Stadler, F. Fuel 2023, 333, 126267. doi: 10.1016/j.fuel.2022.126267
4	Cheng, L.; Yue, X.; Wang, L.; Zhang, D.; Zhang, P.; Fan, J.; Xiang, Q. Adv. Mater. 2021, 33, 2105135. doi: 10.1002/adma.202105135
5	Bie, C.; Cheng, B.; Ho, W.; Li, Y.; Macyk, W.; Ghasemi, J.; Yu, J. Green Chem. 2022, 24, 5739. doi: 10.1039/D2GC01684B
6	Yu, W.; Zhang, S.; Richter, M.; Chen, L.; Xu, W.; Jin, J.; Chen, S.; Peng, T. J. Mater. Chem. A 2018, 6, 15668. doi: 10.1039/c8ta02922a
7	Wang, Y.; Zhu, B.; Cheng, B.; Macyk, W.; Kuang, P.; Yu, J. Appl. Catal. B 2022, 314, 121503. doi: 10.1016/j.apcatb.2022.121503
8	Sun, B.; Dong, X.; Li, H.; Shang, Y.; Zhang, Y.; Hu, F.; Gu, S.; Wu, Y.; Gao, T.; Zhou, G. Sep. Purif. Technol. 2021, 272, 118964. doi: 10.1016/j.seppur.2021.118964
9	Huo, W.; Cao, T.; Xu, W.; Guo, Z.; Liu, X.; Yao, H.; Zhang, Y.; Dong, F. Chin. J. Catal. 2020, 41, 268. doi: 10.1016/S1872-2067(19)63460-1
10	Wang, J.; Li, H.; Gao, P.; Peng, Y.; Cao, S.; Antonietti, M. Chem. Eng. J. 2022, 443, 136447. doi: 10.1016/j.cej.2022.136447
11	Bie, C.; Yu, H.; Cheng, B.; Ho, W.; Fan, J.; Yu, J. Adv. Mater. 2021, 33, 2003521. doi: 10.1002/adma.202003521
12	Li, Y.; Zhang, M.; Zhou, L.; Yang, S.; Wu, Z.; Ma, Y. Acta Phys. -Chim. Sin. 2021, 37, 2009030.
	李云锋, 张敏, 周亮, 杨思佳, 武占省, 马玉花物理化学学报, 2021, 37, 2009030. doi: 10.3866/PKU.WHXB202009030
13	Yu, W.; Xu, D.; Peng, T. J. Mater. Chem. A 2015, 3, 19936. doi: 10.1039/c5ta05503b
14	Tang, R.; Dong, X.; Sheng, J.; Xi, S.; Zhang, L.; Dong, F. Appl. Catal. B 2022, 316, 121661. doi: 10.1016/j.apcatb.2022.121661
15	Zhao, W.; Luo, C.; Lin, Y.; Wang, G.; Chen, H.; Kuang, P.; Yu, J. ACS Catal. 2022, 12, 5540. doi: 10.1021/acscatal.2c00851
16	Meng, X.; Wang, S.; Zhang, C.; Dong, C.; Li, R.; Li, B.; Wang, Q.; Ding, Y. ACS Catal. 2022, 12, 10115. doi: 10.1021/acscatal.2c01877
17	Collado, L.; Naranjo, T.; Gomez-Mendoza, M.; Lopez-Calixto, C.; Oropeza, F.; Liras, M.; Marugan, J.; O'Shea, V. Adv. Funct. Mater. 2021, 31, 2105384. doi: 10.1002/adfm.202105384
18	Lin, J.; Tian, W.; Guan, Z.; Zhang, H.; Duan, X.; Wang, H.; Sun, H.; Fang, Y.; Huang, Y.; Wang, S. Adv. Funct. Mater. 2022, 32, 2201743. doi: 10.1002/adfm.202201743
19	Li, S.; Cai, M.; Liu, Y.; Wang, C.; Lv, K.; Chen, X. Chin. J. Catal. 2022, 43, 2652. doi: 10.1016/S1872-2067(22)64106-8
20	Li, S.; Wang, C.; Cai, M.; Liu, Y.; Dong, K.; Zhang, J. J. Colloid Interface Sci. 2022, 624, 219. doi: 10.1016/j.jcis.2022.05.151
21	Qin, D.; Xia, Y.; Li, Q.; Yang, C.; Qin, Y.; Lv, K. J. Mater. Sci. Technol. 2020, 56, 206. doi: 10.1016/j.jmst.2020.03.034
22	Wang, L.; Bie, C.; Yu, J. Trends Chem. 2022, 4, 973. doi: 10.1016/j.trechm.2022.08.008
23	Lu, M.; Li, Q.; Zhang, C.; Fan, X.; Li, L.; Dong, Y.; Chen, G.; Shi, H. Carbon 2020, 160, 342. doi: 10.1016/j.carbon.2020.01.038
24	Wang, C.; Li, S.; Cai, M.; Yan, R.; Dong, K.; Zhang, J.; Liu, Y. J. Colloid Interface Sci. 2022, 619, 307. doi: 10.1016/j.jcis.2022.03.075
25	Li, S.; Cai, M.; Wang, C.; Liu, Y.; Li, N.; Zhang, P.; Li, X. J. Mater. Sci. Technol. 2022, 123, 177. doi: 10.1016/j.jmst.2022.02.012
26	Das, K.; Mansingh, S.; Sahoo, D.; Mohanty, R.; Parida, K. New J. Chem. 2022, 46, 5785. doi: 10.1039/d2nj00067a
27	Wang, W.; Zhang, H.; Chen, Y.; Shi, H. Acta Phys. -Chim. Sin. 2022, 38, 2201008.
	王文亮, 张灏纯, 陈义钢, 史海峰物理化学学报, 2022, 38, 2201008. doi: 10.3866/PKU.WHXB202201008
28	Zhang, J.; Wang, L.; Mousavi, M.; Ghasemi, J.; Yu, J. Chin. J. Struct. Chem. 2022, 41, 2206003. doi: 10.14102/j.cnki.0254-5861.2022-0150
29	Xia, P.; Cao, S.; Zhu, B.; Liu, M.; Shi, M.; Yu, J.; Zhang, Y. Angew. Chem. Int. Ed. 2020, 59, 5218. doi: 10.1002/anie.201916012
30	Wang, L.; Fei, X.; Zhang, L.; Yu, J.; Cheng, B.; Ma, Y. J. Mater. Sci. Technol. 2022, 112, 1. doi: 10.1016/j.jmst.2021.10.016
31	Huang, Y.; Mei, F.; Zhang, J.; Dai, K.; Dawson, G. Acta Phys. -Chim. Sin. 2022, 28, 2108028.
	黄悦, 梅飞飞, 张金锋, 代凯, Dawson, G. 物理化学学报, 2022, 28, 2108028. doi: 10.3866/PKU.WHXB202108028
32	Mei, F.; Li, Z.; Dai, K.; Zhang, J.; Liang, C. Chin. J. Catal. 2020, 41, 41. doi: 10.1016/S1872-2067(19)63389-9
33	Li, X.; Zhang, J.; Huo, Y.; Dai, K.; Li, S.; Chen, S. Appl. Catal. B 2021, 280, 119452. doi: 10.1016/j.apcatb.2020.119452
34	He, R.; Ou, S.; Liu, Y.; Liu, Y.; Xu, D. Chin. J. Catal. 2022, 43, 370. doi: 10.1016/S1872-2067(21)63911-6
35	Shi, L.; Yin, J.; Liu, Y.; Liu, H.; Zhang, H.; Tang, H. Chemosphere 2022, 309, 136607. doi: 10.1016/j.chemosphere.2022.136607
36	Ren, Y.; Li, Y.; Wu, X.; Wang, J.; Zhang, G. Chin. J. Catal. 2021, 42, 69. doi: 10.1016/S1872-2067(20)63631-2
37	Yue, X.; Cheng, L.; Fan, J.; Xiang, Q. Appl. Catal. B 2022, 304, 120979. doi: 10.1016/j.apcatb.2021.120979
38	Wang, Z.; Cheng, B.; Zhang, L.; Yu, J.; Li, Y.; Wageh, S.; Al‐Ghamdi, A. Chin. J. Catal. 2022, 43, 1657. doi: 10.1016/S1872-2067(21)64010-X
39	Fei, X.; Tan, H.; Cheng, B.; Zhu, B.; Zhang, L. Acta Phys. -Chim. Sin. 2021, 37, 2010027.
	费新刚, 谭海燕, 程蓓, 朱必成, 张留洋物理化学学报, 2021, 37, 2010027. doi: 10.3866/PKU.WHXB202010027
40	Wang, X.; Sayed, M.; Ruzimuradov, O.; Zhang, J.; Fan, Y.; Li, X.; Bai, X.; Low, J. Appl. Mater. Today 2022, 29, 101609. doi: 10.1016/j.apmt.2022.101609
41	He, R.; Xu, D.; Li, X. J. Mater. Sci. Technol. 2023, 138, 256. doi: 10.1016/j.jmst.2022.09.002
42	Zhang, Y.; Xia, Y.; Wang, L.; Cheng, B.; Yu, J. Nanotechnology 2021, 32, 415402. doi: 10.1088/1361-6528/ac1221
43	Khamesan, A.; Esfahani, M.; Ghasemi, J.; Farzin, F.; Parsaei-Khomami, A.; Mousavi, M. Adv. Powder. Technol. 2022, 33, 103777. doi: 10.1016/j.apt.2022.103777
44	Li, X.; Kang, B.; Dong, F.; Zhang, Z.; Luo, X.; Han, L.; Huang, J.; Feng, Z.; Chen, Z.; Xu, J.; et al Nano Energy 2021, 81, 105671. doi: 10.1016/j.nanoen.2020.105671
45	Jiang, Z.; Zhang, Y.; Zhang, L.; Cheng, B.; Wang, L. Chin. J. Catal. 2022, 43, 226. doi: 10.1016/S1872‐2067(21)63832‐9
46	Liu, B.; Du, J.; Ke, G.; Jia, B.; Huang, Y.; He, H.; Zhou, Y.; Zou, Z. Adv. Funct. Mater. 2022, 32, 2111125. doi: 10.1002/adfm.202111125
47	Yang, Y.; Zhu, B.; Wang, L.; Cheng, B.; Zhang, L.; Yu, J. Appl. Catal. B 2022, 317, 121788. doi: 10.1016/j.apcatb.2022.121788
48	He, R.; Lou, Z.; Gui, J.; Tang, B.; Xu, D. Appl. Surf. Sci. 2020, 504, 144370. doi: 10.1016/j.apsusc.2019.144370
49	Sun, B.; Tao, F.; Huang, Z.; Yan, W.; Zhang, Y.; Dong, X.; Wu, Y.; Zhou, G. Appl. Surf. Sci. 2021, 535, 147354. doi: 10.1016/j.apsusc.2020.147354
50	Thi, L.; Phan, T.; Ngoc, T.; Viswanath, N.; Le, H.; Thi, L.; Tien-Trung, N.; Nguyen, L.; Nhiem, D.; Huu, H.; et al J. Alloy. Compd. 2022, 916, 165331. doi: 10.1016/j.jallcom.2022.165331
51	Hou, H.; Zeng, X.; Zhang, X. Angew. Chem. Int. Ed. 2020, 59, 17356. doi: 10.1002/anie.201911609
52	Cheng, H.; Lv, H.; Cheng, J.; Wang, L.; Wu, X.; Xu, H. Adv. Mater. 2022, 34, 2107480. doi: 10.1002/adma.202107480
53	Yang, C.; Wan, S.; Zhu, B.; Yu, J.; Cao, S. Angew. Chem. Int. Ed. 2022, 61, e202208438. doi: 10.1002/anie.202208438
54	Wang, D.; Yin, F.; Cheng, B.; Xia, Y.; Yu, J.; Ho, W. Rare Met. 2021, 40, 2369. doi: 10.1007/s12598-021-01731-2
55	Wang, L.; Zhang, J.; Zhang, Y.; Yu, H.; Qu, Y.; Yu, J. Small 2022, 18, 2104561. doi: 10.1002/smll.202104561
56	Zhang, L.; Zhang, J.; Yu, H.; Yu, J. Adv. Mater. 2022, 34, 2107668. doi: 10.1002/adma.202107668
57	Xu, Q.; Wageh, S.; Al-Ghamdi, A.; Li, X. J. Mater. Sci. Technol. 2022, 124, 171. doi: 10.1016/j.jmst.2022.02.016
58	Ye, J.; Zhang, Y.; Wang, J.; Liu, S.; Chang, Y.; Xu, X.; Feng, C.; Xu, J.; Guo, L.; Xu, J.; et al Catal. Sci. Technol. 2022, 12, 4228. doi: 10.1039/d2cy00610c
59	Li, Y.; Xia, Z.; Yang, Q.; Wang, L.; Xing, Y. J. Mater. Sci. Technol. 2022, 125, 128. doi: 10.1016/j.jmst.2022.02.035
60	Zhang, J.; Zhang, L.; Wang, W.; Yu, J. J. Phys. Chem. Lett. 2022, 13, 8462. doi: 10.1021/acs.jpclett.2c02125
61	He, X.; Liu, Q.; Xu, D.; Wang, L.; Tang, H. J. Mater. Sci. Technol. 2022, 116, 1. doi: 10.1016/j.jmst.2021.10.033
62	Mei, Z.; Wang, G.; Yan, S.; Wang, J. Acta Phys. -Chim. Sin. 2021, 37, 2009097.
	梅子慧, 王国宏, 严素定, 王娟物理化学学报, 2021, 37, 2009097. doi: 10.3866/PKU.WHXB202009097
63	Wang, L.; Cheng, B.; Zhang, L.; Yu, J. Small 2021, 17, 2103447. doi: 10.1002/smll.202103447
64	Yu, W.; Fu, H.; Mueller, T.; Brunschwig, B.; Lewis, N. J. Chem. Phys. 2020, 153, 020902. doi: 10.1063/5.0009858
65	Wageh, S.; Al-Ghamdi, A.; Al-Hartomy, O.; Alotaibi, M.; Wang, L. Chin. J. Catal. 2022, 43, 586. doi: 10.1016/S1872-2067(21)63925-6
66	Bai, J.; Shen, R.; Jiang, Z.; Zhang, P.; Li, Y.; Li, X. Chin. J. Catal. 2022, 43, 359. doi: 10.1016/s1872-2067(21)63883-4
67	Jiang, J.; Xiong, Z.; Wang, H.; Liao, G.; Bai, S.; Zou, J.; Wu, P.; Zhang, P.; Li, X. J. Mater. Sci. Technol. 2022, 118, 15. doi: 10.1016/j.jmst.2021.12.018
68	Jiang, Z.; Chen, Q.; Zheng, Q.; Shen, R.; Zhang, P.; Li, X. Acta Phys. -Chim. Sin. 2021, 37, 2010059.
	姜志民, 陈晴, 郑巧清, 沈荣晨, 张鹏, 李鑫物理化学学报, 2021, 37, 2010059. doi: 10.3866/PKU.WHXB202010059
69	Zhou, L.; Li, Y.; Zhang, Y.; Qiu, L.; Xing, Y. Acta Phys. -Chim. Sin. 2022, 38, 2112027.
	周亮, 李云锋, 张永康, 秋列维, 邢艳物理化学学报, 2022, 38, 2112027. doi: 10.3866/PKU.WHXB202112027
70	Fu, J.; Xu, Q.; Low, J.; Jiang, C.; Yu, J. Appl. Catal. B 2019, 243, 556. doi: 10.1016/j.apcatb.2018.11.011
71	Xia, Z.; Li, Y.; Yang, Q.; Zhu, W.; Jin, R.; Zhang, L.; Xing, Y. Catal. Sci. Technol. 2022, 12, 6599. doi: 10.1039/d2cy01435a
72	Zhao, X.; Li, J.; Kong, X.; Li, C.; Lin, B.; Dong, F.; Yang, G.; Shao, G.; Xue, C. Small 2022, 18, 2204154. doi: 10.1002/smll.202204154
73	Zhang, M.; Li, Y.; Chang, W.; Zhu, W.; Zhang, L.; Jin, R.; Xing, Y. Chin. J. Catal. 2022, 43, 526. doi: 10.1016/S1872-2067(21)63872-X
74	Wang, K.; Jiang, L.; Xin, T.; Li, Y.; Wu, X.; Zhang G. Chem. Eng. J. 2021, 429, 132229. doi: 10.1016/j.cej.2021.132229
75	Zhang, X.; Yu, J.; Macyk, W.; Wageh, S.; Al-Ghamdi, A.; Wang, L. Adv. Sustain. Syst. 2022, 2200113. doi: 10.1002/adsu.202200113
76	Li, X.; Liu, J.; Huang, J.; He, C.; Feng, Z.; Chen, Z.; Wan, L.; Deng, F. Acta Phys. -Chim. Sin. 2021, 37, 2010030.
	李喜宝, 刘积有, 黄军同, 何朝政, 冯志军, 陈智, 万里鹰, 邓芳物理化学学报, 2021, 37, 2010030. doi: 10.3866/PKU.WHXB202010030
77	Liu, B.; Bie, C.; Zhang, Y.; Wang, L.; Li, Y.; Yu, J. Langmuir 2021, 37, 14114. doi: 10.1021/acs.langmuir.1c02360
78	Li, Z.; Huang, W.; Liu, J.; Lv, K.; Li, Q. ACS Catal. 2021, 11, 8510. doi: 10.1021/acscatal.1c02018
79	Huang, W.; Li, Z.; Wu, C.; Zhang, H.; Sun, J.; Li, Q. J. Mater. Sci. Technol. 2022, 120, 89. doi: 10.1016/j.jmst.2021.12.028
80	Gao, D.; Xu, J.; Wang, L.; Zhu, B.; Yu, H.; Yu, J. Adv. Mater. 2021, 34, 2108475. doi: 10.1002/adma.202108475
81	Yang, Y.; Wu, J.; Cheng, B.; Zhang, L.; Al-Ghamdi, A.; Wageh, S.; Li, Y. Chin. J. Struct. Chem. 2022, 41, 2206006. doi: 10.14102/j.cnki.0254-5861.2022-0124
82	Ghoreishian, S.; Ranjith, K.; Park, B.; Hwang, S.; Hosseini, R.; Behjatmanesh-Ardakani, R.; Pourmortazavi, S.; Lee, H.; Son, B.; Mirsadeghi, S.; et al Chem. Eng. J. 2021, 419, 129530. doi: 10.1016/j.cej.2021.129530
83	Bariki, R.; Das, K.; Pradhan, S.; Prusti, B.; Mishra, B. ACS Appl. Energy Mater. 2022, 5, 11002. doi: 10.1021/acsaem.2c01670
84	Wageh, S.; Al-Ghamdi, A.; Xu, Q. Acta Phys. -Chim. Sin. 2022, 38, 2202001.
	Wageh, S., Al-Ghamdi, A., 徐全龙物理化学学报, 2022, 38, 2202001. doi: 10.3866/PKU.WHXB202202001
85	Zhang, S.; Liu, N.; Wang, H.; Lu, Q.; Shi, W.; Wang, X. Adv. Mater. 2021, 33, 2100576. doi: 10.1002/adma.202100576
86	Xu, F.; Meng, K.; Cao, S.; Jiang, C.; Chen, T.; Xu, J.; Yu, J. ACS Catal. 2022, 12, 164. doi: 10.1021/acscatal.1c04903
87	Zhang, X.; Zeng, Y.; Shi, W.; Tao, Z.; Liao, J.; Ai, C.; Si, H.; Wang, Z.; Fisher, A.; Lin, S. Chem. Eng. J. 2022, 429, 131312. doi: 10.1016/j.cej.2021.131312
88	He, B.; Wang, Z.; Xiao, P.; Chen, T.; Yu, J.; Zhang, L. Adv. Mater. 2022, 34, 2203225. doi: 10.1002/adma.202203225
89	Yang, Y.; Cheng, B.; Yu, J.; Wang, L.; Ho, W. Nano Res. 2022, doi: 10.1007/s12274-021-3733-0
90	Chen, Z.; Fang, Y.; Wang, L.; Chen, X.; Lin, W.; Wang, X. Appl. Catal. B 2021, 296, 120369. doi: 10.1016/j.apcatb.2021.120369
91	Fu, Y.; Ren, Z.; Wu, J.; Li, Y.; Liu, W.; Li, P.; Xing, L.; Ma, J.; Wang, H.; Xue, X. Appl. Catal. B 2021, 285, 119785. doi: 10.1016/j.apcatb.2020.119785
92	Kim, D.; Yong, K. Appl. Catal. B 2021, 282, 119538. doi: 10.1016/j.apcatb.2020.119538
93	Zhang, Y.; Qiu, J.; Zhu, B.; Fedin, M.; Cheng, B.; Yu, J.; Zhang, L. Chem. Eng. J. 2022, 434, 136584. doi: 10.1016/j.cej.2022.136584
94	Han, G.; Xu, F.; Cheng, B.; Li, Y.; Yu, J.; Zhang, L. Acta Phys. -Chim. Sin. 2022, 38, 2112037.
	韩高伟, 徐飞燕, 程蓓, 李佑稷, 余家国, 张留洋物理化学学报, 2022, 38, 2112037. doi: 10.3866/PKU.WHXB202112037
95	Jiang, Z.; Cheng, B.; Zhang, Y.; Wageh, S.; Al-Ghamdi, A.; Yu, J.; Wang, L. J. Mater. Sci. Technol. 2022, 124, 193. doi: 10.1016/j.jmst.2022.01.029
96	Huang, Y.; Zhu, Y.; Chen, S.; Xie, X.; Wu, Z.; Zhang, N. Adv. Sci. 2021, 8, 2003626. doi: 10.1002/advs.202003626
97	Niu, X.; Shi, A.; Sun, D.; Xiao, S.; Zhang, T.; Zhou, Z.; Li, X.; Wang, J. ACS Catal. 2021, 11, 14058. doi: 10.1021/acscatal.1c03407
98	Wang, Q.; Miao, Z.; Zhang, Y.; Yan, T.; Meng, L.; Wang, X. ACS Catal. 2022, 12, 4016. doi: 10.1021/acscatal.1c05553
99	Wang, W.; Li, X.; Deng, F.; Liu, J.; Gao, X.; Huang, J.; Xu, J.; Feng, Z.; Chen, Z.; Han, L. Chin. Chem. Lett. 2022, 33, 5200. doi: 10.1016/j.cclet.2022.01.058
100	Lai, C.; Xu, M.; Xu, F.; Li, B.; Ma, D.; Li, Y.; Li, L.; Zhang, M.; Huang, D.; Tang, L.; et al Chem. Eng. J. 2023, 452, 139070. doi: 10.1016/j.cej.2022.1390

[1]	陈轼逸, 付家龙, 裘建平, 常国菊, 郝仕油. 废弃医用口罩衍生的碳量子点增强BiOBr/g-C₃N₄ S型异质结光催化降解聚对苯二甲酸乙二醇酯(PET)[J]. 物理化学学报, 2026, 42(1): 100135 - .
[2]	赵呈孝, 李昭霖, 吴东方, 杨小飞. SBA-15模板化共价三嗪框架增强光催化产氢[J]. 物理化学学报, 2026, 42(1): 100149 - .
[3]	葛成艳, 胡佳伟, 刘星雨, 宋玉玺, 刘超, 邹志刚. 自集成黑色NiO团簇与ZnIn₂S₄微球实现S型电子转移机制下光热辅助制氢[J]. 物理化学学报, 2026, 42(1): 100154 - .
[4]	黄火帅, 韦之栋, 严嘉玮, 池家晟, 苏千翔, 陈铭夏, 江治, 孙洋洲, 上官文峰. 揭示Zn_xCd_1−xS固溶体光催化析氢中的直接-间接带隙跃迁机制[J]. 物理化学学报, 2026, 42(1): 100141 - .
[5]	陈芸, 邓代洁, 徐丽, 朱兴旺, 李赫楠, 孙成明. 共价键调控电荷转移以实现自供能电化学传感平台对重金属离子的灵敏分析[J]. 物理化学学报, 2026, 42(1): 100144 - .
[6]	韦梦兰, 欧晓霞, 王艺濛, 张梦圆, 滕飞, 王凯旋. S型异质结g-C₃N₄/Bi₂WO₆高效降解左氧氟沙星：性能、机理及降解路径[J]. 物理化学学报, 2025, 41(9): 100105 - .
[7]	李静萍, 严素定, 吴佳曦, 程强, 王楷. LiFePO₄改善无机/有机S型光催化剂的过氧化氢光合作用[J]. 物理化学学报, 2025, 41(9): 100104 - .
[8]	吴琦, 王长华, 李莹莹, 张昕彤. 增强g-C₃N₄@BN范德华异质结界面上的三重态电子转移增强光催化合成H₂O₂[J]. 物理化学学报, 2025, 41(9): 100107 - .
[9]	张凤英, 梅杨林, 蒋毓蔓, 郑申申, 郑凯波, 周莹. 瞬态吸收光谱在太阳能转化利用中的研究进展[J]. 物理化学学报, 2025, 41(9): 100118 - .
[10]	王文龙, 郝文韬, 何浪, 乔佳, 李宁, 陈朝秋, 覃勇. 碳量子点/TiO₂ S型异质结的能带和吸附工程促进光催化CO₂甲烷化[J]. 物理化学学报, 2025, 41(9): 100116 - .
[11]	蔡家杰, 程畅, 刘博文, 张建军, 姜传佳, 程蓓. CdS/DBTSO-BDTO S型异质结光催化制氢及其电荷转移动力学[J]. 物理化学学报, 2025, 41(8): 100084 - .
[12]	袁乐汪, 彭垚垚, 管宗杰, 方煜. 二维共价有机框架作为光催化剂在有机合成中的研究进展[J]. 物理化学学报, 2025, 41(8): 100086 - .
[13]	孟凡鹏, 赵飞, 林靖恺, 赵金生, 张华阳, 王少彬. 优化氮化碳纳米片/球形共轭聚合物S型异质结界面电场以促进析氢反应[J]. 物理化学学报, 2025, 41(8): 100095 - .
[14]	王伟康, 吴亚栋, 张建军, 孟凯, 李金河, 王乐乐, 刘芹芹. 三聚氰胺泡沫支撑的S型硫铟锌镉/硫掺杂氮化碳异质结的绿色H₂O₂合成：协同界面电荷转移调控与局域光热效应[J]. 物理化学学报, 2025, 41(8): 100093 - .
[15]	王玉, 石海洋, 陈子涵, 陈峰, 王苹, 王雪飞. 具有富电子Pt^δ−壳层的空心AgPt@Pt核壳催化剂：提升光催化H₂O₂生成选择性与活性[J]. 物理化学学报, 2025, 41(7): 100081 - .

S型异质结H₂O₂光催化剂的研究进展

Review of S-Scheme Heterojunction Photocatalyst for H₂O₂ Production

RichHTML

PDF

赞

可视化

摘要/Abstract

引用本文

使用本文

图/表 18

参考文献 100

相关文章 15

Metrics

推荐阅读 0