Cu-石墨炔/双金属钨酸盐S型异质结协同增强光催化析氢

doi:10.3866/PKU.WHXB202312010

物理化学学报 >> 2024, Vol. 40 >> Issue (10): 2312010.doi: 10.3866/PKU.WHXB202312010

所属专题：太阳燃料光催化剂

Cu-石墨炔/双金属钨酸盐S型异质结协同增强光催化析氢

周正宇¹, 姚惠琴²^,*(), 吴有林¹, 李腾¹^,³, 椿范立³^,*(), 靳治良¹^,*()

¹ 北方民族大学化学与化学工程学院, 银川 750021
² 宁夏医科大学基础医学院化学系, 银川 750004
³ Department of Applied Chemistry, Graduate School of Engineering, University of Toyama, Gofuku 3190, Toyama 930-8555, Japan

收稿日期:2023-12-08 修回日期:2024-01-08 录用日期:2024-01-08 发布日期:2024-03-13
通讯作者: Email: yaohq@nxmu.edu.cn (姚惠琴)tsubaki@eng.u-toyama.ac.jp (椿范立)zl-jin@nun.edu.cn (靳治良)
基金资助:
宁夏回族自治区自然科学基金(2023AAC02046)

Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution

Zhengyu Zhou¹, Huiqin Yao²^,*(), Youlin Wu¹, Teng Li¹^,³, Noritatsu Tsubaki³^,*(), Zhiliang Jin¹^,*()

¹ School of Chemistry and Chemical Engineering, North Minzu University, Yinchuan 750021, China
² Department of Chemistry, College of Basic Medicine, Ningxia Medical University, Yinchuan 750004, China
³ Department of Applied Chemistry, Graduate School of Engineering, University of Toyama, Gofuku 3190, Toyama 930-8555, Japan

Received:2023-12-08 Revised:2024-01-08 Accepted:2024-01-08 Published:2024-03-13
Contact: Email: yaohq@nxmu.edu.cn (Huiqin Yao)tsubaki@eng.u-toyama.ac.jp (Noritatsu Tsubaki)zl-jin@nun.edu.cn (Zhiliang Jin)
Supported by:
the Ningxia Hui Autonomous Region Natural Science Foundation Project(2023AAC02046)

摘要/Abstract

摘要：

采用有机法和水热法合成了Cu-石墨炔和CoNiWO₄并构建了Cu-石墨炔/CoNiWO₄ S型异质结。在保留催化剂强氧化还原能力的同时，通过内建电场和能带弯曲的协同作用促进了光生载流子的高效分离和转移。Cu-石墨炔的引入有效提高了复合催化剂的光吸收能力和导电性，抑制了光生载流子的复合。同时，Cu-石墨炔独特的二维平面网络结构提供了丰富的活性位点，从而促进了光催化反应的进行。密度泛函理论(DFT)计算表明，Cu的表面等离子体共振效应产生的热电子会转移到石墨炔上从而促进氢气的析出。本研究为Cu -石墨炔和镍钴基催化剂在光催化析氢中的潜在应用提供了新的见解。

关键词: Cu-石墨炔, S-型异质结, 界面工程设计, 析氢反应, DFT

Abstract:

Cu-Graphdiyne and CoNiWO₄ were synthesized by organic and hydrothermal methods, respectively. The establishment of an S-scheme heterojunction between Cu-Graphdiyne and CoNiWO₄ was achieved by interface engineering design. The efficient separation and transfer of photogenerated carriers are facilitated by the synergistic effect of the built-in electric field and band bending, while maintaining the strong redox capacity of the catalysts. The introduction of Cu-Graphdiyne effectively enhances the photo absorption capacity and conductivity of the composite catalyst, and significantly suppresses the recombination of photogenerated carriers. The unique two-dimensional planar network structure of Cu-Graphdiyne provides abundant active sites for photocatalytic processes, thereby facilitating the photocatalytic reaction. Density functional theory (DFT) calculations demonstrate that hot electrons generated by surface plasmon resonance effects of Cu will transfer to Graphdiyne to promote hydrogen evolution reaction. This study offers insights into potential applications of Cu-Graphdiyne and nickel-cobalt based catalysts in photocatalytic hydrogen evolution.

Key words: Cu-graphdiyne, S-scheme heterojunction, Interface engineering design, Hydrogen evolution reaction, DFT

周正宇, 姚惠琴, 吴有林, 李腾, 椿范立, 靳治良. Cu-石墨炔/双金属钨酸盐S型异质结协同增强光催化析氢[J]. 物理化学学报, 2024, 40(10), 2312010. doi: 10.3866/PKU.WHXB202312010

Zhengyu Zhou, Huiqin Yao, Youlin Wu, Teng Li, Noritatsu Tsubaki, Zhiliang Jin. Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution[J]. Acta Phys. -Chim. Sin. 2024, 40(10), 2312010. doi: 10.3866/PKU.WHXB202312010

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB202312010

https://www.whxb.pku.edu.cn/CN/Y2024/V40/I10/2312010

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Photocatalyst	Optical source	Sacrificial reagent	Hydrogen production in 5 h	Reference
GCNW20	LED 5 W	TEOA (15%)	4266 μmol∙g⁻¹	This work
NiS/GDY	LED 5 W	TEOA (15%)	4105 μmol∙g⁻¹	61
Co₃O₄/GDY	LED 5 W	TEOA (15%)	3070 μmol∙g⁻¹	62
GDY@g-C₃N₄/Pt	Solar 100 W	TEOA (15%)	3990 μmol∙g⁻¹	63
CdS/GD	LED	TEOA (0.3 mol∙L⁻¹)	2050 μmol∙g⁻¹	64
GD-CuI-NiTiO₃	LED 5 W	TEOA (15%)	2545 μmol∙g⁻¹	65

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Cu-石墨炔/双金属钨酸盐S型异质结协同增强光催化析氢

Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution

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