TiO2纳米晶复合纳米棒染料敏化太阳能电池

doi:10.3866/PKU.WHXB20110734

Abstract

Abstract:

TiO₂ anatase nanorods (ANR) were synthesized by a two-step hydrothermal method. The materials were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and transmission electron microscopy (TEM). To increase the light harvesting efficiency and electron transfer rate, N719 dye-sensitized solar cells (DSSCs) were constructed and compared by adjusting the doping ratio of the anatase nanoparticles (ANP) and ANR in the TiO₂ nanocrystalline film that was used as a photoanode in the DSSCs. The best light-to-electricity conversion efficiency (7.3%) was obtained for a double-layered photoanode (ANP/(ANR+ANP)) cell, which is 20% higher than the traditional single-layered ANP cell (6.1%) when tested under the same conditions and at AM 1.5, 100 mW·cm^-2.

Key words: Dye-sensitized solar cell, Nanorod, Nanoparticle, Electron transfer rate, Light capture efficiency, Photoelectric conversion efficiency

LIU Run-Hua, ZHANG Sen, XIA Xin-Yuan, YUN Da-Qin, BIAN Zu-Qiang, ZHAO Yong-Liang. DSSCs Using a Nanoparticle/Nanorod Composite TiO₂ Film as a Photoanode[J]. Acta Phys. -Chim. Sin. 2011, 27(07), 1701-1706. doi: 10.3866/PKU.WHXB20110734

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DSSCs Using a Nanoparticle/Nanorod Composite TiO₂ Film as a Photoanode

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