新型双链表面活性剂DDOBA的合成与高单分散性憎水纳米金的制备

doi:10.3866/PKU.WHXB201210082

Abstract

Abstract:

3,4-Didodecyloxybenzylamine (DDOBA), a novel surfactant with two alkyl tail chains, was designed and synthesized. DDOBA-capped hydrophobic gold nanoparticles were successfully fabricated using formic acid as a reducing agent in a DDOBA/n-butanol/n-heptane/formic acid/HAuCl₄·4H₂O water/oil (W/O) microemulsion system under microwave irradiation. DDOBA-stabilized gold nanoparticles were characterized by ultraviolet-visible (UV-Vis) spectroscopy, transmission electron microscopy (TEM), high resolution transmission electron microscopy (HR-TEM), and X-ray diffraction (XRD). The experimental results showed that DDOBA not only participated in the formation of a stable W/O microemulsion system, but also became a good protecting agent for gold nanoparticles. Within an appropriate concentration range of components in the W/O microemulsion system, hydrophobic gold nanoparticles with high monodispersity can be obtained using this experimental method and automatically form large areas of ordered monolayer built with DDOBA-capped gold nanoparticles at the air/water interface.

Key words: 3,4-Didodecyloxybenzylamine, Surfactant, W/O microemulsion, Hydrophobic gold nanoparticle, Formic acid, Microwave irradiation

HAN Ying, ZHU Lu, SHEN Ming, LI Heng-Heng. Synthesis of a Novel Surfactant with Two Alkyl Tail-Chains (DDOBA) and Fabrication of Hydrophobic Gold Nanoparticles with High Monodispersity[J]. Acta Phys. -Chim. Sin. 2013, 29(01), 131-138. doi: 10.3866/PKU.WHXB201210082

References

(1) Cortie, M. B.; McDonagh, A. M. Chem. Rev. 2011, 111, 3713.doi: 10.1021/cr1002529
(2) Ke, S. L.; Kan, C. X.; Mo, B.; Cong, B.; Zhu, J. J. Acta Phys. -Chim. Sin. 2012, 28 (6), 1275. [柯善林, 阚彩侠,莫博, 从博, 朱杰君. 物理化学学报, 2012, 28 (6), 1275.]doi: 10.3866/PKU.WHXB201203162
(3) Zhang, Y.; Cui, X. J.; Shi, F.; Deng, Y. Q. Chem. Rev. 2012, 112,2467. doi: 10.1021/cr200260m
(4) Corma, A.; Garcia, H. Chem. Soc. Rev. 2008, 37 (9), 2096. doi: 10.1039/b707314n
(5) Yen, C.W.; El-Sayed, M. A. J. Phys. Chem. C 2009, 113, 19585.doi: 10.1021/jp905186g
(6) Herne, T. M.; Tarlov, M. J. J. Am. Chem. Soc. 1997, 119, 8916.doi: 10.1021/ja9719586
(7) Rosi, N. L.; Mirkin, C. A. Chem. Rev. 2005, 105, 1547. doi: 10.1021/cr030067f
(8) Chen, Y.; Gu, X.; Nie, C. G.; Jiang, Z. Y.; Xie, Z. X.; Lin, C. J.Chem. Commun. 2005, 4181.
(9) Grzelczak, M.; Pérez-Juste, J.; Mulvaney, P.; Liz-Marzán, L. M.Chem. Soc. Rev. 2008, 37, 1783. doi: 10.1039/b711490g
(10) Wang, C.; Daimon, H.; Onodera, T.; Koda, T.; Sun, S. H. Angew. Chem. Int. Edit. 2008, 47 (19), 3588.
(11) Kochkar, H.; Aouine, M.; Ghorbel, A.; Berhault, G. J. Phys. Chem. C 2011, 115 (23), 11364. doi: 10.1021/jp200662j
(12) Collier, C. P.; Saykally, R. J.; Shiang, J. J.; Henrichs, S. E.;Heath, J. R. Science 1997, 277, 1978. doi: 10.1126/science.277.5334.1978
(13) Pena, S. R. N.; Raina, S.; Goodrich, G. P.; Fedoroff, N. V.;Keating, C. D. J. Am. Chem. Soc. 2002, 124 (25), 7314. doi: 10.1021/ja0177915
(14) Brust, M.;Walker, M.; Bethell, D.; Schriffrin, D. J.; Whyman,R. J. Chem. Soc. Chem. Commun. 1994, 7, 801.
(15) Fan, C. Y.; Jiang, L. Langmuir 1997, 13, 3059. doi: 10.1021/la960150g
(16) Song, J.; Kim, D.; Lee, D. Langmuir 2011, 27, 13854. doi: 10.1021/la203113r
(17) Shen, M.; Du, Y. K.; Hua, N. P.; Yang, P. Powder Tech. 2006,162, 64. doi: 10.1016/j.powtec.2005.09.007
(18) Shen, M.; Du, Y. K.; Yang, P.; Jiang, L. J. Phys. Chem. Solids2005, 66, 1628. doi: 10.1016/j.jpcs.2005.05.078
(19) Han, Y.; Li, H. H.; Shen, M.; Li, L.; Xu, G. Y. Acta Chimica Sinica 2010, 68 (18), 1813. [韩莹, 李恒恒, 沈明,李亮, 徐桂英. 化学学报, 2010, 68 (18), 1813.]
(20) Yang, G. J.; Qu, X. L.; Shen, M.;Wang, C. Y.; Qu, Q. S.; Hu, X.Y. Sensors and Actuators B 2007, 128, 258. doi: 10.1016/j.snb.2007.06.005
(21) Qu, Q. S.; Shen, F.; Shen, M.; Hu, X. Y.; Yang, G. J.;Wang, C.Y.; Yan, C.; Zhang, Y. K. Analytic Chimica Acta 2008, 609, 76.doi: 10.1016/j.aca.2007.12.031
(22) Zhang, Y.W.; Zhou, H.; Liu, X. F.;Wang, J. F.; Shen, Z. X.Chinese Journal of Applied Chemistry 2003, 20 (1), 98. [张雅文, 周华, 刘小峰, 王建非, 沈宗旋. 应用化学, 2003, 20 (1),98.]
(23) Norman, T. J.; Grant, C. D.; Magana, D.; Zhang, J. Z.; Liu, J.;Cao, D. L.; Bridges, F.; Buuren, A. V. J. Phys. Chem. B 2002,106, 7005. doi: 10.1021/jp0204197
(24) Shen, M.; Yao, Y. F.; Zhang, J. G. Journal of Jiangsu University2010, 31 (4), 422. [沈明, 姚玉峰, 张金贵. 江苏大学学报,2010, 31 (4), 422.]
(25) Aslan, K.; Perez-Luna, V. H. Langmuir 2002, 18, 6059. doi: 10.1021/la025795x
(26) Nehl, C. L.; Liao, H.; Hafner, J. H. Nano Lett. 2006, 6, 683. doi: 10.1021/nl052409y
(27) Bain, C. D.; Evall, J.; Whitesides, G. M. J. Am. Chem. Soc.1989, 111, 7155. doi: 10.1021/ja00200a039
(28) Shen, M.; Du, Y. K.; Rong, H. L.; Li, J. R.; Jiang, L. Colloids and Surfaces A 2005, 257-258, 439.

[1]	Yucui Hou, Zhuosen He, Shuhang Ren, Weize Wu. Catalytic Oxidation of Biomass to Formic Acid under O₂ with Homogeneous Catalysts [J]. Acta Phys. -Chim. Sin., 2023, 39(9): 2212065-0.
[2]	Zhicong Sun, Ergui Luo, Qinglei Meng, Xian Wang, Junjie Ge, Changpeng Liu, Wei Xing. High-Performance Palladium-Based Catalyst Boosted by Thin-Layered Carbon Nitride for Hydrogen Generation from Formic Acid [J]. Acta Phys. -Chim. Sin., 2022, 38(3): 2003035-.
[3]	Jian Yang, Chen Lei, Xiang Liu, Jian Zhang, Yudie Sun, Cheng Zhang, Mingfu Ye, Kui Zhang. Versatile Performance of a Cationic Surfactant Derived from Carbon Quantum Dots [J]. Acta Phys. -Chim. Sin., 2022, 38(12): 2111030-.
[4]	Yan Yang, Bowen He, Hualong Ma, Sen Yang, Zhouhong Ren, Tian Qin, Fagui Lu, Liwen Ren, Yixiao Zhang, Tianfu Wang, Xi Liu, Liwei Chen. PtRuAgCoNi High-Entropy Alloy Nanoparticles for High-Efficiency Electrocatalytic Oxidation of 5-Hydroxymethylfurfural [J]. Acta Phys. -Chim. Sin., 2022, 38(12): 2201050-.
[5]	Chong Cao, Pei Zhang, Lidong Cao, Mingxin Liu, Yuying Song, Peng Chen, Qiliang Huang, Buxing Han. Experimental and Molecular Dynamic Simulation of Droplet Deposition on Superhydrophobic Plant Leaf Surfaces [J]. Acta Phys. -Chim. Sin., 2022, 38(12): 2207006-.
[6]	Yufei Bao, Ligang Feng. Formic Acid Electro-Oxidation Catalyzed by PdNi/Graphene Aerogel [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2008031-.
[7]	Yuan Zhou, Na Han, Yanguang Li. Recent Progress on Pd-based Nanomaterials for Electrochemical CO₂ Reduction [J]. Acta Physico-Chimica Sinica, 2020, 36(9): 2001041-.
[8]	Zhaobi Xing,Zhijun Guo,Yuwei Zhang,Junling Liu,Yujie Wang,Guangyue Bai. Regulation of SDS on the Surface Charge Density of SB3-12 Micelles and Its Effect on Drug Dissolution [J]. Acta Physico-Chimica Sinica, 2020, 36(6): 1906006-.
[9]	Yimin Hu, Jie Han, Rong Guo. Wormlike Micelle to Gel Transition Induced by Brij 30 in Ionic Liquid-Type Surfactant Aqueous Solution [J]. Acta Physico-Chimica Sinica, 2020, 36(10): 1909049-.
[10]	Yingxiong Wang, Manli Deng, Yongqiang Tang, Yuchun Han, Xu Huang, Yanbo Hou, Yilin Wang. Aggregation of Biodegradable Cationic Gemini Surfactants with Amide or Ester Groups [J]. Acta Physico-Chimica Sinica, 2020, 36(10): 1909046-.
[11]	Lingyan GONG, Guangzhi LIAO, Quansheng CHEN, Hexin LUAN, Yujun FENG. Swollen Surfactant Micelles: Properties and Applications [J]. Acta Physico-Chimica Sinica, 2019, 35(8): 816-828.
[12]	Siqi LUO,Meina WANG,Weiwei ZHAO,Yilin WANG. Interactions between Surfactants and Folic Acid and the Effects of Surfactants on the Photodegradation of Folic Acid [J]. Acta Phys. -Chim. Sin., 2019, 35(7): 766-774.
[13]	Hengchang LIU,Yujun FENG. CO₂-Induced Interaction between a Pentablock Nonionic Copolymer and an Anionic Fluorocarbon Surfactant [J]. Acta Phys. -Chim. Sin., 2019, 35(4): 408-414.
[14]	Mingming YUAN,Difan LI,Xiuge ZHAO,Wenbao MA,Kang KONG,Wenxiu NI,Qingwen GU,Zhenshan HOU. Selective Oxidation of Glycerol with Hydrogen Peroxide Using Silica-Encapsulated Heteropolyacid Catalyst [J]. Acta Phys. -Chim. Sin., 2018, 34(8): 886-895.
[15]	Chen-Hui ZHANG,Xin ZHAO,Jin-Mei LEI,Yue MA,Feng-Pei DU. Wettability of Triton X-100 on Wheat (Triticum aestivum) Leaf Surfaces with Respect to Developmental Changes [J]. Acta Phys. -Chim. Sin., 2017, 33(9): 1846-1854.

Synthesis of a Novel Surfactant with Two Alkyl Tail-Chains (DDOBA) and Fabrication of Hydrophobic Gold Nanoparticles with High Monodispersity

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0