用CdSe/ZnS量子点提高体异质结有机太阳电池的效率

doi:10.3866/PKU.WHXB201312274

Abstract

Abstract:

The efficiency of bulk heterojunction solar cells was enhanced by incorporating CdSe/ZnS core-shell colloidal quantum dots (CQDs) into copolymers of poly(3-hexylthiophene (P3HT) and [6,6]-phenyl-C₆₁-butyric acid methyl ester (PCBM) as the active layer, as result of the increased absorption in the visible region. The doping of CdSe/ZnS CQDs in the active layer and the influence of CQD surface ligands on device performance were investigated. A maximum power conversion efficiency (PCE) of 3.99% was obtained from the optimized solar cell ITO/PEDOT:PSS/P3HT:PCBM:(CdSe/ZnS)/Al (ITO: indium-tin oxide; PEDOT: poly(3,4-ethylendioxythiophene; PSS: poly(styrenesulfonate)) under AM1.5 illumination. This was 45.1% improvement on the PCE of the control device ITO/PEDOT:PSS/P3HT:PCBM/Al.

Key words: Bulk heterojunction solar cell, CdSe/ZnS core-shell colloidal quantum dot, Polymer, Ligand exchange, Power conversion efficiency

NI Ting, ZOU Fan, JIANG Yu-Rong, YANG Sheng-Yi. To Improve the Efficiency of Bulk Heterojunction Organic Solar Cells by Incorporating CdSe/ZnS Quantum Dots[J]. Acta Phys. -Chim. Sin. 2014, 30(3), 453-459. doi: 10.3866/PKU.WHXB201312274

References

(1) Landi, B. J.; Castro, S. L.; Ruf, H. J.; Evans, C. M.; Bailey, S. G.; Raffaelle, R. P. Sol. Energy Mater. Sol. Cells 2005, 87, 733. doi: 10.1016/j.solmat.2004.07.047
(2) Chang, L. L.; Lademann, H.W. A.; Bonekamp, J. B.; Meerholz, K.; Moulé, A. J. Adv. Funct. Mater. 2011, 21, 1779. doi: 10.1002/adfm.201002372
(3) Ip, A. H.; Thon, S. M.; Hoogland, S.; Voznyy, O.; Zhitomirsky, D.; Debnath, R.; Levina, L.; Rollny, L. R.; Carey, G. H.; Fischer, A.; Kemp, K.W.; Kramer, I. J.; Ning, Z. J.; Labelle, A. J.; Chou, K.W.; Amassian, A.; Sargent, E. H. Nanotechnology 2012, 7, 577.
(4) Greenham, N. C.; Peng, X.; Alivisatos, A. P. Phys. Rev. B 1996, 54, 17628. doi: 10.1103/PhysRevB.54.17628
(5) Han, L. L.; Qin, D. H.; Jiang, X.; Liu, Y. S.;Wang, L.; Chen, J. W.; Cao, Y. Nanotechnology 2006, 17, 4736. doi: 10.1088/0957-4484/17/18/035
(6) Olson, J. D.; Gray, G. P.; Carter, S. A. Sol . Energy Mater. Sol. Cells 2009, 93, 519. doi: 10.1016/j.solmat.2008.11.022
(7) Zhou, Y. F.; Riehle, F. S.; Yuan, Y.; Schleiermacher, H. F.; Niggemann, M.; Urban, G. A.; Kruger, M. Appl. Phys. Lett. 2010, 96, 013304. doi: 10.1063/1.3280370
(8) Noone, K. M.; Strein, E.; Anderson, N. C.;Wu, P. T.; Jenekhe, S. A.; Ginger, D. S. Nano Lett. 2010, 10, 2635. doi: 10.1021/nl1013663
(9) Cui, D.; Xu, J.; Zhu, T.; Paradee, G.; Ashok, S.; Gerhold, M. Appl. Phys. Lett. 2006, 88, 183111. doi: 10.1063/1.2201047
(10) Khan, M. T.; Bhargav, R.; Kaur, A.; Dhawan, S. K.; Chand, S. Thin Solid Films 2010, 519, 1007. doi: 10.1016/j.tsf.2010.08.032
(11) Yue,W.; Hart, S.; Peng, R.; Shen,W.; Geng, H.;Wu, F.; Tao, S.; Wang, M. J. Mater. Chem. 2010, 20, 7570. doi: 10.1039/c0jm00611d
(12) Fu,W. F.; Shi, Y.; Qiu,W. M.;Wang, L.; Nan, Y. X.; Shi, M. M.; Li, H. Y.; Chen, H. Z. Phys. Chem. Chem. Phys. 2012, 14, 12094. doi: 10.1039/c2cp42487h
(13) Dixit, S. K.; Madan, S.; Madhwal, D.; Kumar, J.; Singh, I.; Bhatia, C. S.; Bhatnagar, P. K.; Mathur, P. C. Org. Electron. 2012, 13, 710. doi: 10.1016/j.orgel.2012.01.014
(14) Jeong, S.; Shim, H. C.; Kim, S.; Han, C. S. ACS Nano 2009, 4, 324.
(15) Meng, Q. L.; Li, F. X.; Xi, X.; Qian,W. Y.; Que, L. Z.; Ji, J. J.; Ding, Y. Q.; Li, G. H. J. Synth. Cryst. 2010, 39, 670. [孟庆蕾, 李方馨, 席曦, 钱维莹, 阙立志, 季静佳, 丁玉强, 李果华. 人工晶体学报, 2010, 39, 670.]
(16) Zhuo, Z. L.; Zhang, F. J.; Xu, X.W.;Wang, J.; Lu, L. F.; Xu, Z. Acta Phys. -Chim. Sin. 2011, 27, 875. [卓祖亮, 张福俊, 许晓伟, 王健, 卢丽芳, 徐征. 物理化学学报, 2011, 27, 875.] doi: 10.3866/PKU.WHXB20110414
(17) Olek, M.; Bulsgen, T.; Hilgendorff, M.; Giersig, M. J. Phys. Chem. B 2006, 110, 12901. doi: 10.1021/jp061453e
(18) Dabbousi, B. O.; Rodriguez-Viejo, J.; Mikulec, F. V.; Heine, J. R.; Mattoussi, H.; Ober, R.; Jensen, K. F.; Bawendi, M. G. J. Phys. Chem. B 1997, 101, 9463. doi: 10.1021/jp971091y
(19) Efros, A. L.; Rosen, M. Annu. Rev. Mater. Sci. 2000, 30, 475. doi: 10.1146/annurev.matsci.30.1.475
(20) Kucur, E.; Qu, L.; Riegler, G. A.; Urban, G. A.; Nann, T. J. Chem. Phys. 2003, 119, 2333. doi: 10.1063/1.1582834
(21) Moule, A. J.; Meerholz, K. Adv. Funct. Mater. 2009, 19, 3028. doi: 10.1002/adfm.v19:19
(22) Wang, L.; Zhao, D.; Su, Z.; Li, B.; Zhang, Z.; Shen, D. J. Electrochem. Soc. 2011, 158, H804.
(23) Landsberg, P. T.; Nussbaumer, H.;Willeke, G. J. Appl. Phys. 1993, 74, 1451. doi: 10.1063/1.354886
(24) Kolodinski, S.;Werner, J. H.;Wittchen, T.; Queisser, H. J. Appl. Phys. Lett. 1993, 63, 2405. doi: 10.1063/1.110489
(25) Li, G.; Shrotriya, V.; Huang, J. S.; Yao, Y.; Moriarty, T.; Emery, K.; Yang, Y. Nat. Mater. 2005, 4, 864. doi: 10.1038/nmat1500

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To Improve the Efficiency of Bulk Heterojunction Organic Solar Cells by Incorporating CdSe/ZnS Quantum Dots

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