磷酸钒钠Na3V2(PO4)3电化学储能研究进展

doi:10.3866/PKU.WHXB201608303

Abstract

Abstract:

Lithium ion batteries (LiBs) have been widely utilized, but the limited lithium resource restricts development and application of LiBs in large-scale energy storage. Sodium has similar physicochemical characteristics to that of lithium and is suitable to transfer between two electrodes as a cation in the "rocking chair" mechanism of LiBs. Na-containing compounds have been proposed as the electrodes to store sodium ions and provide channels for diffusion. Polyanion Na₃V₂(PO₄)₃ is a Na-super-ionic conductor (NASICON) with specific Na sites in its crystal structure and three-dimensional open channels. Recently, Na₃V₂(PO₄)₃ has been demonstrated as potential electrode material with promising properties for energy storage. In this review we systematically summarize the structure of Na₃V₂(PO₄)₃, the application and mechanism in a specific energy system, and the recent development of Na₃V₂(PO₄)₃ structure for use as electrodes. The potential problems and trends of Na₃V₂(PO₄)₃ are also discussed.

Key words: Na₃V₂(PO₄)₃, Na-super-ionic conductor, Electrochemistry, Energy storage, Material structure

Wei-Xin SONG,Hong-Shuai HOU,Xiao-Bo JI. Progress in the Investigation and Application of Na₃V₂(PO₄)₃ for Electrochemical Energy Storage[J].Acta Phys. -Chim. Sin., 2017, 33(1): 103-129.

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Progress in the Investigation and Application of Na₃V₂(PO₄)₃ for Electrochemical Energy Storage

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