D-π-A-π-A结构有机光敏染料的合成及其在太阳能光电转化和光解水制氢中的应用

doi:10.3866/PKU.WHXB201609194

Abstract

Abstract:

A novel metal-free D-π-A-π-A-based organic sensitizer OD2 featuring a N,N'-dimethylaniline unit as the donor residue, acetylene and benzene groups as π-spacer units, and benzothiadiazole and cyanoacrylic acid residues as acceptor units, was designed and synthesized. After the spectra and electrochemistry of the organic dye were investigated, it was applied in the development of solar energy conversion, including dyesensitized solar cell (DSSC) and dye-sensitized photocatalytic H₂ production. For a typical device based on OD2, a maximum power conversion efficiency (η) of 4.40% was obtained under simulated AM 1.5 irradiation (100 mW·cm^-2) with J_sc=10.58 mA·cm^-2, V_oc=630 mV and FF=0.65. In comparison, the efficiency of photocatalytic H₂ production by OD2 sensitized Pt/TiO₂ is low with a TON (turnover number)=140 and quantum efficiency for H₂ conversion of water (Φ_H₂)=0.42% under visible light irradiation for 10 h with a 300 W Xe-lamp light source and 10% (volume fraction) aqueous triethanolamine (TEOA) at pH 7.0. The above results showed that OD2 has greater potential in the light-to-electricity conversion than light-to-fuel conversion.

Key words: Photoelectric property, Hydrogen production, Organic sensitizer, D-π-A-π-A configuration

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An XIAO,Hui LU,Yang ZHAO,Geng-Geng LUO. Synthesis of a Novel D-π-A-π-A Organic Sensitizer and Its Application in a Dye-Sensitized Solar Cell and Dye-Sensitized Photocatalytic H₂ Production[J]. Acta Phys. -Chim. Sin. 2016, 32(12), 2968-2975. doi: 10.3866/PKU.WHXB201609194

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Synthesis of a Novel D-π-A-π-A Organic Sensitizer and Its Application in a Dye-Sensitized Solar Cell and Dye-Sensitized Photocatalytic H₂ Production

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Synthesis of a Novel D-π-A-π-A Organic Sensitizer and Its Application in a Dye-Sensitized Solar Cell and Dye-Sensitized Photocatalytic H₂ Production