二氧化碳和胺催化合成甲酰胺反应研究

doi:10.3866/PKU.WHXB201701081

Abstract

Abstract:

Carbon dioxide is a green C₁ resource that can be efficiently recycled by catalytic transformation into value-added chemicals. Formamides are important intermediates and solvents that are used extensively in pharmaceutical, daily-chemical, and petrochemical industry. Therefore, it is worthwhile to synthesize formamides with CO₂ and amines. In this review, the main advancements in the synthesis of formamides by using CO₂ as the C₁ feedstock with noble metal catalysts (Ir, Pd, Pt, Ru, Rh, etc.), non-noble metal catalysts (Ni, Mo, Cu, Fe, Co, Zn, Al, etc.), organocatalysts, and catalyst-free systems have been summarized. In addition, the role of the reducing agents such as H₂, silanes, and boranes involved in these transformations has also been reviewed. In addition, the reaction mechanisms with the different catalyst systems have been discussed.

Key words: Carbon dioxide, Amines, Formamides, Carbonylation

Yujing ZHANG,Xingchao DAI,Hongli WANG,Feng SHI. Catalytic Synthesis of Formamides with Carbon Dioxide and Amines[J]. Acta Phys. -Chim. Sin. 2018, 34(8), 845-857. doi: 10.3866/PKU.WHXB201701081

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Catalytic Synthesis of Formamides with Carbon Dioxide and Amines

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