可用作便携式电源的高性能直接碳固体氧化物燃料电池组

doi:10.3866/PKU.WHXB201704181

Acta Phys. -Chim. Sin. ›› 2017, Vol. 33 ›› Issue (8): 1614-1620.doi: 10.3866/PKU.WHXB201704181

• ARTICLE • Previous Articles Next Articles

A High Performance Direct Carbon Solid Oxide Fuel Cell Stack for Portable Applications

Xiao-Qiang. WANG¹,Jiang. LIU^1,*(),Yong-Min. XIE^1,²,Wei-Zi. CAI^1,³,Ya-Peng. ZHANG¹,Qian. ZHOU¹,Fang-Yong. YU^1,⁴,Mei-Lin. LIU^1,⁵

¹ New Energy Research Institute, School of Environment and Energy, South China University of Technology, Guangzhou 510006, P. R. China
² Institute of Metallurgy and Chemical Industry, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi Province, P. R. China
³ Department of Building and Real Estate, Hong Kong Polytechnic University, Hong Kong 999077, P. R. China
⁴ Institute of Chemical Engineering, Shandong University of Technology, Zibo 255000, Shandong Province, P. R. China
⁵ School of Materials Science and Engineering, Georgia Institute of Technology, 771 Ferst Drive, Atlanta, GA 30332-0245, USA

Received:2017-02-17 Published:2017-06-14
Contact: Jiang. LIU E-mail:jiangliu@scut.edu.cn
Supported by:
The project was supported by the National Natural Science Foundation of China(21276097);The project was supported by the National Natural Science Foundation of China(21567008);The project was supported by the National Natural Science Foundation of China(21263005);Special Funds of Guangdong Province Public Research and Ability Construction, China(2014A010106008);Guangdong Innovative and Entrepreneurial Research Team Program, China(2014ZT05N200);and Program of Excellent Ph.D Thesis Authors of Guangdong Province, China

Abstract

Abstract:

A direct carbon solid oxide fuel cell (DC-SOFC) stack was prepared with 3 tubular cells electrically connected in series. To increase carbon storage in the stack, the anode was fabricated outside the tubular cells so that carbon fuel can be loaded at the exterior of the stack, which is more spacious than the interior. The 3-cell-stack is operated directly with carbon as the fuel and oxygen in ambient air as the oxidant. With a total effective area of 10.2 cm² and a 5% (w) Fe-loaded activated carbon fuel of 17 g, the stack reveals a peak power of 4.1 W at 800℃. The stack discharged at a constant current of 1.0 A for 19 h, giving a charge capacity of 19 A·h and an energy capacity of 31.6 W·h, which are much higher than those of a similar stack with anode on the inside and carbon loaded at the interior. The high capacity of our DC-SOFC opens up potential applications in portable devices.

Key words: Solid oxide fuel cell, Carbon fuel, Segmented-in-series stack, Carbon-air battery, Portable application

Xiao-Qiang. WANG,Jiang. LIU,Yong-Min. XIE,Wei-Zi. CAI,Ya-Peng. ZHANG,Qian. ZHOU,Fang-Yong. YU,Mei-Lin. LIU. A High Performance Direct Carbon Solid Oxide Fuel Cell Stack for Portable Applications[J]. Acta Phys. -Chim. Sin. 2017, 33(8), 1614-1620. doi: 10.3866/PKU.WHXB201704181

References

1	Cao D. ; Sun Y. ; Wang G. J. Power Sources 2007, 167, 250.
2	Nakagawa N. ; Ishida M. Ind. Eng. Chem. Res. 1988, 27, 1181.
3	Tang Y. B. ; Liu J. Int. J. Hydrog. Energy 2010, 35, 11188.
4	Bai Y. H. ; Liu Y. ; Tang Y. B. ; Xie Y. M. ; Liu J. Int. J. Hydrog. Energy 2011, 36, 9189.
5	Liu, J. ; Liu, Y. ; Tang, Y. B. ; Bai, Y. H. A Direct Carbon Solid OxideFuel Cell Power System. CN Patent: ZL201110008698. 8, 2013.
6	Yang B. B. ; Ran R. ; Zhong Y. J. ; Su C. ; Moses O. T% Shao Z. P. Angew. Chem. Int. Edit. 2015, 54, 1.
7	Zhou W. ; Jiao Y. ; Li S. D. ; Shao Z. P. ChemElectroChem 2016, 3 (2), 193.
8	Lee A. C. ; Mitchell R. E. ; Gür T. M. J. Power Sources 2009, 194, 774.
9	Li C. ; Shi Y. X. ; Cai N. S. J. Power Sources 2010, 195, 4660.
10	Xu X. Y. ; Zhou W. ; Liang F. C. ; Zhu Z. H. Appl. Energy 2013, 108, 402.
11	Jayakumar A. ; Küngas R.S. R. ; Javadekar A. ; Buttrey D. J. ; Vohs J. M. Energy Environ. Sci. 2011, 4, 4133.
12	Xu X. Y. ; Zhou W. ; Zhu Z. H. Ind. Eng. Chem. Res. 2013, 52 (50), 17927.
13	Zecevic S. ; Patton E. M. ; Parhami P. Carbon 2004, 42, 1983.
14	Cooper J. F. ; Selman R. ECS Trans. 2009, 19, 15.
15	Xie Y. M. ; Tang Y. B. Liu J. J. Solid State Electr. 2013, 17, 121.
16	Rady A.C. ; Giddey S. ; Badwal S. P. ; Ladewig B. P. ; Bhattacharya S. Energy Fuels 2012, 26, 1471.
17	Gür T. M. Chem. Rev. 2013, 113, 6179.
18	Tang Y. B. ; Liu J. ; Sui J. ECS Trans. 2009, 25, 1109.
19	Tang Y. B. ; Liu J. Acta Phys. -Chim. Sin. 2010, 26 (5), 1191.
19	唐玉宝.; 刘江.. 物理化学学报, 2010, 26 (5), 1191.
20	Liu R. Z. ; Zhao C. H. ; Li J. L. ; Zeng F. R. ; Wang S. R. J. Power Sources 2010, 195, 480.
21	Zhang L. ; Xiao J. ; Xie Y. M. ; Tang Y. B. ; Liu J. ; Liu M. L. J. Alloy. Compd. 2014, 608, 272.
22	Cai W. Z. ; Zhou Q. ; Xie Y. M. ; Liu J. Fuel 2015, 159, 887.
23	Yu F. Y. ; Zhang Y. P. ; Yu L. ; Cai W. Z. ; Yuan L. L. ; Liu J. ; Liu M. L. Int. J. Hydrog. Energy 2016, 41, 9048.
24	Xie Y. M. ; Cai W. Z. ; Xiao J. ; Tang Y. B. ; Liu J. ; Liu M. L. J. Power Sources 2015, 277, 1.
25	Rady A. C. ; Giddey S. ; Kulkarni A. ; Badwal S. P. S. ; Bhattacharya S. ; Ladewig B. P. Appl. Energy 2014, 120, 56.
26	Dudek M. ; Tomczyk P. ; Socha R. ; Hamaguchi M. Int. J. Hydrog. Energy 2014, 39, 12386.
27	Zhu X. B. ; Li Y. Q. ; Lü Z. Int. J. Hydrog. Energy 2016, 41, 5057.
28	Zhou Q. ; Cai W. Z. ; Zhang Y. P. ; Liu J. ; Yuan L. L. ; Yu F. Y. ; Wang X. Q. ; Liu M. L. Biomass Bioenergy 2016, 91, 250.
29	Cai W. Z. ; Zhou Q. ; Xie Y. M. ; Liu J. ; Long G. H. ; Cheng S. ; Liu M. L. Appl. Energy 2016, 179, 1232.
30	Xu H. R. ; Chen B. ; Liu J. ; Ni M. Appl. Energy 2016, 178, 353.
31	Bai Y. H. ; Liu J. ; Gao H. B. J. Alloy. Compd. 2009, 480, 554.
32	Liu, J. ; Su, W. H. ; Lü, Z. ; Ji, Y. ; Pei, L. ; Liu, W. ; He, T. M. A RapidSealing Method for Solid Oxide Fuel Cell Using Metal Conductive Adhesive. CN Patent: ZL 02133049. 2. 2004.

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[13]	TANG Yu-Bao, LIU Jiang. Fueling Solid Oxide Fuel Cells with Activated Carbon [J]. Acta Phys. -Chim. Sin., 2010, 26(05): 1191-1194.
[14]	ZONG Wei-Zheng, ZHU Yong-Fa. Preparation of Single-Chamber Solid Oxide Fuel Cell by Co-Pressing and Direct Forming Process [J]. Acta Phys. -Chim. Sin., 2010, 26(04): 827-832.
[15]	LEI Ze, ZHU Qing-Shan, HAN Min-Fang. Fabrication and Performance of Direct Methane SOFC with a Cu-CeO₂-Based Anode [J]. Acta Phys. -Chim. Sin., 2010, 26(03): 583-588.

A High Performance Direct Carbon Solid Oxide Fuel Cell Stack for Portable Applications

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