中温固体氧化物燃料电池La1.6Sr0.4Ni1-xCuxO4阴极材料的制备及电化学性能

doi:10.3866/PKU.WHXB201206272

Abstract

Abstract:

Cathodic materials La_1.6Sr_0.4Ni_1-xCu_xO₄ (x=0.2, 0.4, 0.6, 0.8), for an intermediate temperature solid oxide fuel cell (IT-SOFC), were prepared by a glycine-nitrate process and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM). Results showed that no reaction occurred between the La_1.6Sr_0.4Ni_1-xCu_xO₄ electrode and the Ce_0.9Gd_0.1O_1.95 (CGO) electrolyte at 1000 °C, and that the electrode formed good contact with the electrolyte after sintering at 1000 °C for 4 h. Electrochemical AC impedance spectroscopy measurements were used to study cathodic performance. The La_1.6Sr_0.4Ni_0.4Cu_0.6O₄ cathode gave the lowest polarization resistance (R_p) of 0.35 Ω·cm² at 750 ° C in air. Electrode properties of La_1.6Sr_0.4Ni_1-xCu_xO₄ were studied under various temperatures and oxygen partial pressures. The two main oxygen reduction processes at the cathode are the oxygen ion transfer from the triple phase boundary to CGO electrolyte, and the charge transfer process. Charge transfer is the major rate limiting step for La_1.6Sr_0.4Ni_1-xCu_xO₄ cathode. The La_1.6Sr_0.4Ni_0.4Cu_0.6O₄ cathode exhibited the lowest overpotential, about 45 mV for a current density of 45 mA·cm^-2 at 700 °C in air. This preliminary work showed that the present La_1.6Sr_0.4Ni_1-xCu_xO₄ materials may be potential cathodes for use in IT-SOFCs.

Key words: Intermediate temperature solid oxide fuel cell, La_1.6Sr_0.4Ni_1-xCu_xO₄ cathode material, Glycine-nitrate process, Electrochemical property, Oxygen reduction reaction

LI Qiang, ZHAO Hui, JIANG Rui, GUO Li-Fan. Synthesis and Electrochemical Properties of La_1.6Sr_0.4Ni_1-xCu_xO₄ as Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells[J]. Acta Phys. -Chim. Sin. 2012, 28(09), 2065-2070. doi: 10.3866/PKU.WHXB201206272

References

(1) Skinner, S. J.; Kilner, J. A. Solid State Ionics 2000, 135, 709.doi: 10.1016/S0167-2738(00)00388-X
(2) Ding, X. F.; Kong, X.; Jiang, J. G.; Cui, C. Int. J. Hydrog. Energy 2009, 34, 6869. doi: 10.1016/j.ijhydene.2009.06.041
(3) Peng, B.; Chen, G.;Wang, T.; Zhou, J.; Guo, J. J.; Cheng, Y. H.;Wu, K. J. Power Sources 2012, 201, 174.
(4) Taguchi, H. Mater. Res. Bull. 2001, 36, 1361. doi: 10.1016/S0025-5408(01)00631-6
(5) Vashook, V.; Girdauskaite, E.; Zosel, J.;Wen, T. L.; Ullmann,H.; Guth, U. Solid State Ionics 2006, 177, 1163. doi: 10.1016/j.ssi. 2006.05.018
(6) Minervini, L.; Grimes, R.W.; Kilner, J. A.; Sickafus, K. E.J. Mater. Chem. 2000, 10, 2349. doi: 10.1039/b004212i
(7) Yang, X. M.; Luo, L. T.; Zhong, H. Appl. Catal. A 2001, 207,69. doi: 10.1016/S0926-860X(00)00658-X
(8) Bochkov, D. M.; Kharton, V. V.; Kovalevsky, A. V.; Viskup, A.P.; Naumovich, E. N. Solid State Ionics 1999, 120, 281. doi: 10.1016/S0167-2738(99)00019-3
(9) Vashooka, V. V.; Trofimenko, N. E.; Ullmann, H.; Makhnach, L.V. Solid State Ionics 2000, 131, 329. doi: 10.1016/S0167-2738(00)00571-3
(10) Yang, J. F.; Cheng, J. G.; Fan, Y. M.;Wang, R.; Gao, J. F. Acta Phys. -Chim. Sin. 2012, 28, 1230. [杨俊芳, 程继贵, 樊玉萌,王睿, 高建峰. 物理化学学报, 2012, 28, 1230.] doi: 10.3866/PKU.WHXB201202232
(11) Khandale, A. P.; Bhoga, S. S. J. Power Sources 2010, 195, 7974.doi: 10.1016/j.jpowsour.2010.06.044
(12) Al Daroukh, M.; Vashook, V. V.; Ullmann, H.; Tietz, F.; ArualRaj, I. Solid State Ionics 2003, 158, 141. doi: 10.1016/S0167-2738(02)00773-7
(13) Jorgensen, J.; Dabrowski, B.; Pei, S.; Richards, D. R.; Hinks, D.G. Phys. Rev. B 1989, 40, 2187. doi: 10.1103/PhysRevB.40.2187
(14) Li, Q.; Fan, Y.; Zhao, H.; Huo, L. H. Chin. J. Inorg. Chem.2006, 22, 2025. [李强, 范勇, 赵辉, 霍丽华. 无机化学学报, 2006, 22, 2025.]
(15) Inprasit, T.; Limthongkul, P.;Wongkasemjit, S. ECS Transactions 2009, 25, 2581.
(16) Ling, Y. H.; Zhao, L.; Lin, B.; Dong, Y. C.; Zhang, X. Z.; Meng,G. Y.; Liu, X. Q. Int. J. Hydrog. Energy 2010, 35, 6905. doi: 10.1016/j.ijhydene.2010.04.021
(17) Zhang, H.;Wang, T.; Dong, X.; Lin,W. J. Nat. Gas Chem.2009, 18, 45. doi: 10.1016/S1003-9953(08)60084-5
(18) Zha, S.W.; Moore, A.; Abernathy, H.; Liu, M. L.J. Electrochem. Soc. 2004, 151, A1128.
(19) Zhao, H.; Li, Q.; Sun, L. P. Sci. China Ser. B-Chem. 2011, 54,898. doi: 10.1007/s11426-011-4290-2
(20) Aguadero, A.; Alonso, J. A.; Escudero, M. J.; Daza, L. Solid State Ionics 2008, 151, 393.
(21) Li, Q.; Zhao, H.; Huo, L. H.; Sun, L. P.; Cheng, X. L.; Grenier,J. C. Electrochem. Commun. 2007, 9, 1508. doi: 10.1016/j.elecom.2007.02.013
(22) Li, Q.; Fan, Y.; Zhao, H.; Sun, L. P.; Huo, L. H. J. Power Sources 2007, 167, 64. doi: 10.1016/j.jpowsour.2007.02.018
(23) Efimov, K.; Halfer, T.; Kuhn, A.; Heitjans, P.; Caro, J.; Feldhoff,A. Chem. Mater. 2010, 22, 1540. doi: 10.1021/cm902882s
(24) Irvine, J. T. S.; Sinclair, D. C.;West, A. R. Adv. Mater. 1990, 2,132. doi: 10.1002/adma.19900020304
(25) Takeda, Y.; Kanno, R.; Noda, M.; Yamamoto, O.J. Electrochem. Soc. 1987, 134, A2656.
(26) Sicbeit, E.; Hammouche, A.; Kleitz, M. Electrochim. Acta 1995,40, 1741. doi: 10.1016/0013-4686(94)00361-4
(27) Li, Q.; Zeng, X.; Sun, L. P.; Zhao, H.; Huo, L. H.; Grenier, J. C.Int. J. Hydrog. Energy 2012, 37, 2552. doi: 10.1016/j.ijhydene.2011.11.014
(28) Mauvy, F.; Lalanne, C.; Bassat, J. M.; Grenier, J. C.; Zhao, H.;Dordor, P.; Stevens, P. J. Eur. Ceram. Soc. 2005, 25, 2669.doi: 10.1016/j.jeurceramsoc.2005.03.120

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Synthesis and Electrochemical Properties of La_1.6Sr_0.4Ni_1-xCu_xO₄ as Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells

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Synthesis and Electrochemical Properties of La1.6Sr0.4Ni1-xCuxO4 as Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells

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Synthesis and Electrochemical Properties of La_1.6Sr_0.4Ni_1-xCu_xO₄ as Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells