银基陶瓷复合电极的电性能及其在固体氧化物燃料电池中的应用

doi:10.3866/PKU.WHXB201512032

Abstract

Abstract:

Silver-based ceramic composite electrodes are expected to be widely applied in medium-or lowtemperature solid oxide fuel cells (SOFCs), SOFCs operated on carbon-containing fuels, and solid oxide electrolysis cells (SOECs). To optimize the composition of a silver-based ceramic composite electrode, the performances of Ag-YSZ (yttrium-stabilized zirconia) and Ag-GDC (gadolinium doped ceria) are investigated. First, they are used as electrode materials to make symmetric electrodes on a YSZ electrolyte, to which impedance spectra are measured in an ambient atmosphere to evaluate their feasibility as cathode materials. It was found that that Ag-YSZ reaches the lowest polarization resistance when the content of Ag is 65%(w, mass fraction), while for Ag-GDC, the value is 70% (w). The Ag-YSZ and Ag-GDC with the lowest polarization resistance are used as electrode materials to make SOFC single cells whose electrochemical performances are tested. The polarization resistance of an anode of the SOFCs can be obtained by subtracting the cathode polarization resistance from the overall SOFC polarization resistance. Both the polarization resistance result and the output performance show that the performance of Ag-GDC is superior to Ag-YSZ as an anode. In the present work, Ag-YSZ is more suitable as the cathode and the Ag-GDC as the anode. The present work provides not only useful data for Ag-based composite electrodes but also a method for measuring the polarization resistance of SOFC anodes.

Key words: Solid oxide fuel cell, Electrode, Silver, Yttrium stabilized zirconia, Gadolinium doped ceria

Liang YU,Fang-Yong YU,Li-Li YUAN,Wei-Zi CAI,Jiang LIU,Cheng-Hao YANG,Mei-Lin LIU. Electrical Performance of Ag-Based Ceramic Composite Electrodes and Their Application in Solid Oxide Fuel Cells[J]. Acta Phys. -Chim. Sin. 2016, 32(2), 503-509. doi: 10.3866/PKU.WHXB201512032

References

1	Minh N. Q. J Am. Ceram. Soc 1993, 76 (3), 563.
2	Winter M. ; Brodd R. J Chem. Rev 2004, 104, 4245.
3	McIntosh S. ; Gorte R. J Chem. Rev 2004, 104 (10), 4845.
4	Singhal S. C Solid State Ionics 2000, 135, 305.
5	Zhu W. ; Ding D. ; Xia C. R Electrochemical and Solid-State Letters 2008, 11 (6), B83.
6	Jin C. ; Liu J. ; Zhang Y. H. ; Sui J. ; Guo W. M. J Power Sources 2008, 182, 482.
7	Bai Y. H. ; Liu J. ; Gao H. B. ; Jin C. J Alloy. Compd 2009, 480, 554.
8	Ding J. ; Liu J. ; Yuan W. S. ; Zhang Y. H. J Eur. Ceram. Soc 2008, 28, 3113.
9	Kim J.W. ; Virkar A. V. ; Fung K. Z. ; Mehta K. ; Singhal S.C. J Electrochem. Soc 1999, 146 (1), 69.
10	Liu D. D. ; Xie Y. M. ; Liu J. ; Wang J. X Acta Phys. -Chim. Sin 2014, 30 (2), 331.
10	刘丹丹; 谢永敏; 刘江; 王金霞. 物理化学学报, 2014, 30 (2), 331.
11	Steele B. C. H Solid State Ionics 2000, 129, 95.
12	Feng M. ; Goodenough J. B. ; Huang K. Q. ; Milliken C J. Power Sources 1996, 63, 47.
13	Zhang J. D. ; Ji Y. ; Gao H. B. ; He T. M. ; Liu J. J Alloy. Compd 2005, 395, 322.
14	Panuh D. ; Muchtar A. ; Muhamad N. ; Majlan E. H. ; Daud W. R W. Composites: Part B 2014, 58, 193.
15	Shao Z. P. ; Haile1 S. M. ; Ahn J. ; Ronney P. D. ; Zhan Z. L. ; Barnett S. A Nature 2005, 435 (7043), 795.
16	Murray E. P. ; Tsai T. ; Barnett S. A Nature 1999, 400, 649.
17	Tang Y. B. ; Liu J. ; Sui J. J Electrochem. Soc 2009, 25 (2), 1109.
18	Tang Y. B. ; Liu J. J Acta Phys. -Chim. Sin 2010, 26 (5), 1191.
18	唐玉宝; 刘江. 物理化学学报, 2010, 26 (5), 1191.
19	Tang Y. B. ; Liu J. Int. J. Hydrog. Energy 2010, 35, 11188.
20	Xie Y. M. ; Tang Y. B. ; Liu J. J Solid State Electr 2013, 17 (1), 121.
21	Zhang L. ; Xiao J. ; Xie Y. M. ; Tang Y. B. ; Liu J. ; Liu M. L J. Alloy. Compd 2014, 608, 272.
22	Cai W. Z. ; Zhou Q. ; Xie Y. M. ; Liu J Fuel 2015, 159, 887.
23	Xie Y. M. ; Xiao J. ; Liu D. D. ; Liu J. ; Yang C. H J. Electrochem. Soc 2015, 162 (4), F397.
24	Larminie, J.; Dicks, A. Fuel Cell Systems Explained; JohnWiley & Sons Ltd.: Chichester, 2000; pp 40-45.
25	Nielsen J. ; Jacobsen T Solid State Ionics 2008, 179, 1314.
26	Murray E. P. ; Barnett S. A Solid State Ionics 2001, 143, 265.

[1]	Youwen Rong, Jiaqi Sang, Li Che, Dunfeng Gao, Guoxiong Wang. Designing Electrolytes for Aqueous Electrocatalytic CO₂ Reduction [J]. Acta Phys. -Chim. Sin., 2023, 39(5): 2212027-0.
[2]	Yanpeng Fu, Changbao Zhu. Design Strategies for Sodium Electrode Materials: Solid-State Ionics Perspective [J]. Acta Phys. -Chim. Sin., 2023, 39(3): 2209002-0.
[3]	Jingwen Zhang, Hualong Ma, Jun Ma, Meixue Hu, Qihao Li, Sheng Chen, Tianshu Ning, Chuangxin Ge, Xi Liu, Li Xiao, Lin Zhuang, Yixiao Zhang, Liwei Chen. Cone Shaped Surface Array Structure on an Alkaline Polymer Electrolyte Membrane Improves Fuel Cell Performance [J]. Acta Phys. -Chim. Sin., 2023, 39(2): 2111037-0.
[4]	Siran Xu, Qi Wu, Bang-An Lu, Tang Tang, Jia-Nan Zhang, Jin-Song Hu. Recent Advances and Future Prospects on Industrial Catalysts for Green Hydrogen Production in Alkaline Media [J]. Acta Phys. -Chim. Sin., 2023, 39(2): 2209001-0.
[5]	Yingying Zhu, Yong Wang, Miao Xu, Yongmin Wu, Weiping Tang, Di Zhu, Yu-Shi He, Zi-Feng Ma, Linsen Li. Tracking Pressure Changes and Morphology Evolution of Lithium Metal Anodes [J]. Acta Phys. -Chim. Sin., 2023, 39(1): 2110040-0.
[6]	Tonghui Cui, Hangyue Li, Zewei Lyu, Yige Wang, Minfang Han, Zaihong Sun, Kaihua Sun. Identification of Electrode Process in Large-Size Solid Oxide Fuel Cell [J]. Acta Phys. -Chim. Sin., 2022, 38(8): 2011009-.
[7]	Yuke Song, Wenfu Xie, Mingfei Shao. Recent Advances in Integrated Electrode for Electrocatalytic Carbon Dioxide Reduction [J]. Acta Phys. -Chim. Sin., 2022, 38(6): 2101028-.
[8]	Jian Wang, Bo Yin, Tian Gao, Xingyi Wang, Wang Li, Xingxing Hong, Zhuqing Wang, Haiyong He. Reduced Graphene Oxide Modified Few-Layer Exfoliated Graphite to Enhance the Stability of the Negative Electrode of a Graphite-Based Potassium Ion Battery [J]. Acta Phys. -Chim. Sin., 2022, 38(2): 2012088-.
[9]	Liliang Tian, Weiqi Zhang, Zheng Xie, Kai Peng, Qiang Ma, Qian Xu, Sivakumar Pasupathi, Huaneng Su. Enhanced Performance and Durability of High-Temperature Polymer Electrolyte Membrane Fuel Cell by Incorporating Covalent Organic Framework into Catalyst Layer [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2009049-.
[10]	Jujia Zhang, Jin Zhang, Haining Wang, Yan Xiang, Shanfu Lu. Advancement in Distribution and Control Strategy of Phosphoric Acid in Membrane Electrode Assembly of High-Temperature Polymer Electrolyte Membrane Fuel Cells [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2010071-.
[11]	Dunfeng Gao, Pengfei Wei, Hefei Li, Long Lin, Guoxiong Wang, Xinhe Bao. Designing Electrolyzers for Electrocatalytic CO₂ Reduction [J]. Acta Phys. -Chim. Sin., 2021, 37(5): 2009021-.
[12]	Yitao He, Fei Ding, Li Lin, Zhihong Wang, Zhe Lü, Yaohui Zhang. Influence of Interfacial Concentration Polarization on Lithium Metal Electrodeposition [J]. Acta Phys. -Chim. Sin., 2021, 37(2): 2009001-.
[13]	Yao Chen, Haoyang Dong, Yuanyuan Li, Jinping Liu. Recent Advances in 3D Array Anode Materials for Sodium-Ion Batteries [J]. Acta Phys. -Chim. Sin., 2021, 37(12): 2007075-.
[14]	Hantao Sun, Jianhui Liao, Shimin Hou. Single-Molecule Field-Effect Transistors with Graphene Electrodes and Covalent Pyrazine Linkers [J]. Acta Phys. -Chim. Sin., 2021, 37(10): 1906027-.
[15]	Hongyi Pan, Quan Li, Xiqian Yu, Hong Li. Characterization Techniques for Lithium Metal Anodes at Multiple Spatial Scales [J]. Acta Phys. -Chim. Sin., 2021, 37(1): 2008091-.

Electrical Performance of Ag-Based Ceramic Composite Electrodes and Their Application in Solid Oxide Fuel Cells

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0