醋酸铅作为铅源合成CH3NH3PbBr3-xClx纳米晶体颗粒

doi:10.3866/PKU.WHXB201705115

Abstract

Abstract:

Lead acetate, which is highly soluble in dimethylformamide, was used to synthesize mixed halide perovskite CH₃NH₃PbBr₃_-_xCl_x (MA = CH₃NH₃, 0 ≤ x ≤ 3) nanocrystals (NCs). This method provides an approach to address the low solubility of lead halides, especially lead chloride. Different Br/Cl ratios in MAPbBr₃_-_xCl_x lead to various optical properties. The photoluminescence emission peak can be tuned from 399 to 527 nm. Their full-widths at half-maxima (FWHM) are about 20 nm. MAPbBr₃_-_xCl_x NCs have an average diameter of ~(11 ± 3) nm and have uniform dispersion in toluene. The MAPbBr₃ NCs have a long average recombination lifetime (τ_ave = 97.4 ns) and a photoluminescence quantum yield (PLQY) of up to 73%.

Key words: Perovskite, CH₃NH₃PbBr₃_-_xCl_x, Nanocrystal, Lead acetate

Ya-Nan WANG,Pin MA,Lu-Mei PENG,Di ZHANG,Yan-Yan FANG,Xiao-Wen ZHOU,Yuan LIN. Synthesis of Colloidal Perovskite CH₃NH₃PbBr₃_-_xCl_x Nanocrystals with Lead Acetate[J]. Acta Phys. -Chim. Sin. 2017, 33(10), 2099-2105. doi: 10.3866/PKU.WHXB201705115

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Synthesis of Colloidal Perovskite CH₃NH₃PbBr₃_-_xCl_x Nanocrystals with Lead Acetate

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