三维配位聚合物[Sr(BDC)(H2O)]的合成、结构与热稳定性

doi:10.3866/PKU.WHXB20110908

Abstract

Abstract: The solvothermal reactions of Sr(NO₃)₂ with 1,4-benzenedicarboxylic acid (BDC) in a mixture of H₂O/N,N'-dimethylformamide (DMF) resulted in a novel coordination polymer, [Sr(BDC) (H₂O)] (1), which was characterized by single crystal and variable temperature powder X-ray diffraction (VTPXRD), elemental analysis, infra-red (IR) spectroscopy, and thermogravimetric-mass spectrometric (TG-MS) analysis. Compound 1 crystallizes in the orthorhombic space group Pbca with a=1.1854(2) nm, b=0.7122 (1) nm, and c=2.0031(4) nm. It is a three-dimensional (3D) framework consisting of zigzag chains that are formed by face-shared SrO₈ square antiprisms and bridging BDC ligands. TG-MS and VTPXRD studies revealed that the framework of compound 1 exhibited a high thermal stability.

Key words: 1,4-Benzenedicarboxylic acid, Strontium, Solvothermal synthesis, Structure, Thermal property

FU Ying, LI Guo-Bao, LIAO Fu-Hui, LIN Jian-Hua. Synthesis, Structure and Thermal Property of a 3D Coordination Polymer [Sr(BDC)(H₂O)][J].Acta Phys. -Chim. Sin., 2011, 27(10): 2269-2274.

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Synthesis, Structure and Thermal Property of a 3D Coordination Polymer [Sr(BDC)(H₂O)]

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Synthesis, Structure and Thermal Property of a 3D Coordination Polymer [Sr(BDC)(H₂O)]