微观结构调控的g-C3N4在光催化NO转化中的最新进展：吸附/活化位点的关键作用

doi:10.1016/j.actphy.2024.100039

Abstract

Abstract:

Photocatalytic nitric oxide (NO) conversion technology has the characteristics of high efficiency, economy, and environment friendly to remove NO using g-C₃N₄. Introducing new adsorption sites on the surface of g-C₃N₄ through microstructure control can alter the structure-activity relationship between g-C₃N₄ and gas molecules, thereby improving photocatalytic NO conversion activity and inhibiting NO₂ generation. However, few review articles have focused on the microscopic effects of microstructural changes in g-C₃N₄ based materials on the adsorption and activation of NO and O₂. This has important guiding significance for material design work in the field of NO conversion and strategies to fundamentally improve NO conversion activity and selectivity. Therefore, our work systematically summarizes the strategy of introducing adsorption and activation sites through microstructure control, and emphasizes the role of these sites in the photocatalytic NO conversion process. The aim is to clarify the influence of adsorption and activation sites on adsorption behavior and the correlation between these sites and reaction paths. Finally, the development trend and future prospects of increasing the level of g-C₃N₄ adsorption and activation in the field of photocatalytic NO conversion are introduced, which is expected to provide an important reference for the development and practical application of g-C₃N₄-based photocatalytic materials.

Key words: Photocatalysis, g-C₃N₄, NO conversion, Microstructure control, Adsorption, Activation

Hui Wang, Abdelkader Labidi, Menghan Ren, Feroz Shaik, Chuanyi Wang. Recent Progress of Microstructure-Regulated g-C₃N₄ in Photocatalytic NO Conversion: The Pivotal Roles of Adsorption/Activation Sites[J]. Acta Phys. -Chim. Sin. 2025, 41(5), 100039. doi: 10.1016/j.actphy.2024.100039

Figures/Tables 18

Fig 1

Fig 2

Table 1

Compare the photocatalytic NO conversion efficiency reported by different g-C3N4-based materials in this work."

No.	Microstructure control method	Type	Photocatalyst amount (g)	Light source	Initial Conc.	Conv. (%)	NO₂ Conc.	Ref.
1	Vacancy engineering	N_2C vacancy	0.1	150 W commercial tungsten halogen lamp equipped with a 420 nm cut-off filter	600 ppb	41.84	77.8 ppb	[67]
2		N_3C vacancy	0.1	150 W tungsten halogen lamp	–	57.1	82.15 ppb	[68]
3		N_3C vacancy	0.2	30 W LED (Visible region)	600 ppb	66.7	26.8 ppb	[69]
4		N_3C vacancy	0.2	LED lamp	600 ppb	40.3	87.7 ppb	[70]
5		C vacancy	0.2	LED lamp (λ ≥ 448 nm)	600 ppb	47.0	30 ppb	[71]
6		non-intrinsic O vacancies	0.1	300 W xenon lamp equipped with a cut-off filter (λ＞420 nm)	500 ppb	47.7	25 ppb	[72]
7	Doping	Sulfur doping	0.2	150 W visible light LED lamp (λ > 400 nm)	600 ppb	53	58.86 ppb	[73]
8		Boron doping	0.1	500 W Xe lamp	600 ppb	54	–	[34]
9		Sulfur doping	0.025	LED array (450 nm centre wavelength)	1 ppm	50	200 ppb	[74]
10		C self doping	0.2	150 W commercial tungsten halogen lamp	550 ppb	56.77	–	[75]
11		Sulfur doping	0.2	Xe lamp	500 ppb	78.0	–	[76]
12		Na⁺, Li⁺ interlayer doping	0.2	30 W visible LED lamp	600 ppb	82	3.7 ppb	[77]
13		Zn interlayer doping	0.1	150 W metal halide lamp (λ greater than 420 nm)	600 ppb	49	5.88 ppb	[78]
14		Ca interlayer doping	0.2	150 W commercial tungsten halogen lamp	500 ppb	54.78	–	[79]
15		Sr cavity filling	0.05	xenon lamp with a 420 nm filter	600 ppb	55	66 ppb	[80]
16	Functional group modification	Oxygenated functional group	0.2	150 W commercial tungsten halogen lamp equipped with a UV light cutoff filter (420 nm)	500 ppb	45.5	–	[81]
17		Cyano and hydroxyl groups	0.05	300 W xenon lamp equipped with a cut-off filter (λ > 420 nm)	600 ppb	46.2	77.61 ppb	[82]
18		hydroxyl groups	0.2	Visible light LED lamp (λ ≥ 420 nm)	600 ppb	65.0	117 ppb	[83]
19		Oxygenated functional group	0.1	150 W commercial tungsten halogen lamp	500 ppb	50.4	–	[84]
20	Cocatalyst loading	SrSO₄ loading	0.05	30 W LED lamp	600 ppb	67.5	85.05 ppb	[85]
21		CaCO₃ loading	0.2	LED lamp (λ > 420 nm)	550 ppb	51.18	107.5 ppb	[86]
22		ZIF-67/CoOOH loading	0.2	150 W metal halide lamp with a 420 nm cutoff	500 ppb	52.5	0	[87]
23		Au loading	0.2	150 W commercial halogen tungsten lamp	500 ppb	41.0	10.25 ppb	[88]
24	Construction of and heterojunctions	(BiO)₂CO₃@ g-C₃N₄ heterojunction	–	150 W commercial tungsten halogen lamp	–	53.28	–	[89]
25		g-C₃N₄/BO_0.2N_0.8 heterojunction	0.2	Metal halide lamp (150 W) was used as the light source with a visible light filter (λ > 420 nm).	500 ppb	30.2	4.53 ppb	[90]
26		Pd1/g-C₃N₄-UiO-66-NH₂ heterojunction	10–40	300 W Xenon lamp	40–70 ppm	93.91	1.02 ppm	[91]
27		Graphene quantum dots/g-C₃N₄	0.08	300 W Xe lamp	600 ppb	90.0	140.4 ppb	[92]
28		UiO-67/g-C₃N₄ S- scheme heterojunction	0.2	Tungsten halogen lamp (150 W)	500 ppb	60.4	–	[93]
29		CeO₂/g-C₃N₄ S- scheme heterojunction	0.05	300 W Xe lamp	600 ppb	73.8	96 ppb	[94]

Table 1

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Recent Progress of Microstructure-Regulated g-C₃N₄ in Photocatalytic NO Conversion: The Pivotal Roles of Adsorption/Activation Sites

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Recent Progress of Microstructure-Regulated g-C3N4 in Photocatalytic NO Conversion: The Pivotal Roles of Adsorption/Activation Sites

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Recent Progress of Microstructure-Regulated g-C₃N₄ in Photocatalytic NO Conversion: The Pivotal Roles of Adsorption/Activation Sites