离子液体中磺化无定形炭催化菊糖制备5-羟甲基糠醛

doi:10.3866/PKU.WHXB201112292

Abstract

Abstract: The production of 5-hydroxylmethylfurfural (HMF) from inulin over sulfonated amorphous carbon was studied in an ionic liquid, 1-butyl-3-methylimidazolium chloride ([Bmim]Cl). The effects of reaction solvent, water content, reaction temperature, reaction time, and catalyst dosage on the yield of HMF were investigated. Experimental results indicated that optimum reaction conditions required a reaction temperature of 100 °C, a reaction time of 60 min, an R value of 5 (R represents the molar ratio of added water to fructose units in inulin), and a mass ratio of catalyst to inulin of 1:3, affording HMF in yields of up to 50%.

Key words: Inulin, 5-Hydroxymethylfurfural, Sulfonated amorphous carbon, Ionic liquid, Fructose

GONG Yan-Yan, LIU Min, JIA Song-Yan, FENG Jian-Ping, SONG Chun-Shan, GUO Xin-Wen. Production of 5-Hydroxymethylfurfural from Inulin Catalyzed by Sulfonated Amorphous Carbon in an Ionic Liquid[J]. Acta Phys. -Chim. Sin. 2012, 28(03), 686-692. doi: 10.3866/PKU.WHXB201112292

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Production of 5-Hydroxymethylfurfural from Inulin Catalyzed by Sulfonated Amorphous Carbon in an Ionic Liquid

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