具有光热效应的多级Ti3C2/Bi12O17Br2肖特基异质结简单合成及其太阳能驱动抗生素光降解的研究

doi:10.1016/j.actphy.2025.100075

物理化学学报 >> 2025, Vol. 41 >> Issue (7): 100075.doi: 10.1016/j.actphy.2025.100075

具有光热效应的多级Ti₃C₂/Bi₁₂O₁₇Br₂肖特基异质结简单合成及其太阳能驱动抗生素光降解的研究

刘超¹^,*(), 余欢¹, 李佳明¹, 余茜¹, 郁壮志¹, 宋玉玺¹, 张峰¹, 张勤芳¹^,*(), 邹志刚²

¹ 盐城工学院材料科学与工程学院, 江苏盐城 224051
² 南京大学生态材料与可再生能源研究中心, 江苏南京 210093

收稿日期:2025-01-17 修回日期:2025-02-24 录用日期:2025-03-03 发布日期:2025-05-22
通讯作者: Email: cliu@ycit.edu.cn (刘超)qfangzhang@ycit.edu.cn (张勤芳)
基金资助:
国家自然科学基金(12474276); 国家自然科学基金(12274361); 江苏高校青蓝工程资助项目

Facile synthesis of hierarchical Ti₃C₂/Bi₁₂O₁₇Br₂ Schottky heterojunction with photothermal effect for solar-driven antibiotics photodegradation

Chao Liu¹^,*(), Huan Yu¹, Jiaming Li¹, Xi Yu¹, Zhuangzhi Yu¹, Yuxi Song¹, Feng Zhang¹, Qinfang Zhang¹^,*(), Zhigang Zou²

¹ School of Materials Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, Jiangsu Province, China
² Eco-Materials and Renewable Energy Research Centre (ERERC), Nanjing University, Nanjing 210093, Jiangsu Province, China

Received:2025-01-17 Revised:2025-02-24 Accepted:2025-03-03 Published:2025-05-22
Contact: Email: cliu@ycit.edu.cn (Chao Liu)qfangzhang@ycit.edu.cn (Qinfang Zhang)
Supported by:
the National Natural Science Foundation of Chin(12474276); the National Natural Science Foundation of Chin(12274361); Qinglan Project of Jiangsu of China

1. ACTPHY-D-25-100075-SI.pdf(3750KB)

摘要/Abstract

摘要：

在去除盐酸四环素(TC)方面，光催化技术被认为是一种高效和绿色的方法，可满足可持续发展的需求。本研究采用简单的搅拌过程来构建具有多级结构的Ti₃C₂/Bi₁₂O₁₇Br₂ (命名为TBOB)肖特基异质结，其中Bi₁₂O₁₇Br₂组分紧密地沉积在Ti₃C₂表面。通过模拟太阳光下降解TC来评价所有样品的光催化性能。与Bi₁₂O₁₇Br₂相比，所制备的TBOB复合材料表现出更好的光降解活性，活性的增强归功于Ti₃C₂和Bi₁₂O₁₇Br₂之间的协同效应，增加Ti₃C₂的负载量可提高光捕获能力，肖特基异质结的形成可促进有效的电荷载流子分离，以及光热效应可促进表面反应动力学。此外，对影响TBOB复合材料光催化性能的关键因素进行了详细的研究。自由基捕获实验和电子顺磁共振(EPR)技术证实了•O₂⁻和e⁻是TC光催化降解的主要活性物种。结合实验分析和理论计算，提出并讨论了可能的电荷载流子转移途径和光催化降解机理。本研究为合理设计高效光热辅助Ti₃C₂基光催化剂提供了理论和实验依据。

关键词: Bi₁₂O₁₇Br₂, Ti₃C₂, 肖特基异质结, 光热效应, 光降解

Abstract:

Photocatalytic technology is considered to be an efficient and green approach for removing tetracycline hydrochloride (TC) to meet the demands of sustainable development. Here, a facile stirring process was employed to construct Ti₃C₂/Bi₁₂O₁₇Br₂ (termed as TBOB) Schottky heterojunction with a hierarchical structure, in which the Bi₁₂O₁₇Br₂ component was closely deposited on the surface of Ti₃C₂. The TC photodegradation performance was estimated for all catalysts under simulated solar light. Compared with Bi₁₂O₁₇Br₂, TBOB materials exhibited the superior photodegradation activity due to the synergistic effect between Ti₃C₂ and Bi₁₂O₁₇Br₂, which could increase light harvesting capacity derived from Ti₃C₂ loading, promote the charge carrier separation due to the formed Schottky heterojunction, and facilitate surface reaction kinetics owing to the photothermal effect. Besides, some crucial influencing factors on the photocatalytic performance over TBOB composites were separately studied in detail. The free radical capture experiment and electron paramagnetic resonance (EPR) technique confirmed the predominant active species of •O₂⁻ and e⁻ for the TC photodegradation. Combined with experimental analysis and theoretical calculations, insight into the charge carrier transfer and photodegradation mechanisms were proposed. This study provides theoretical and experimental insights for the rational design of high-efficiency photothermal-assisted Ti₃C₂-based photocatalysts.

Key words: Bi₁₂O₁₇Br₂, Ti₃C₂, Schottky heterojunction, Photothermal effect, Photodegradation

刘超, 余欢, 李佳明, 余茜, 郁壮志, 宋玉玺, 张峰, 张勤芳, 邹志刚. 具有光热效应的多级Ti₃C₂/Bi₁₂O₁₇Br₂肖特基异质结简单合成及其太阳能驱动抗生素光降解的研究[J]. 物理化学学报, 2025, 41(7), 100075. doi: 10.1016/j.actphy.2025.100075

Chao Liu, Huan Yu, Jiaming Li, Xi Yu, Zhuangzhi Yu, Yuxi Song, Feng Zhang, Qinfang Zhang, Zhigang Zou. Facile synthesis of hierarchical Ti₃C₂/Bi₁₂O₁₇Br₂ Schottky heterojunction with photothermal effect for solar-driven antibiotics photodegradation[J]. Acta Phys. -Chim. Sin. 2025, 41(7), 100075. doi: 10.1016/j.actphy.2025.100075

链接本文: https://www.whxb.pku.edu.cn/CN/10.1016/j.actphy.2025.100075

https://www.whxb.pku.edu.cn/CN/Y2025/V41/I7/100075

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具有光热效应的多级Ti₃C₂/Bi₁₂O₁₇Br₂肖特基异质结简单合成及其太阳能驱动抗生素光降解的研究

Facile synthesis of hierarchical Ti₃C₂/Bi₁₂O₁₇Br₂ Schottky heterojunction with photothermal effect for solar-driven antibiotics photodegradation

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