可放大电沉积的MoNi4合金/非晶NiMoOx电极用于稳定碱性海水析氢

doi:10.1016/j.actphy.2026.100381

物理化学学报 >> 2026, Vol. 42 >> Issue (11): 100381.doi: 10.1016/j.actphy.2026.100381

论文上一篇

可放大电沉积的MoNi₄合金/非晶NiMoO_x电极用于稳定碱性海水析氢

史雅然¹, 马颖², 李黎明², 张安然², 王舟舟³, 余颖¹

1 华中师范大学物理科学与技术学院纳米科学与纳米技术研究所, 湖北武汉 430079;
2 中船(邯郸)派瑞氢能科技有限公司, 河北邯郸 057551;
3 海氢科技(武汉)有限公司, 湖北武汉 430223

收稿日期:2026-06-29 修回日期:2026-07-31 录用日期:2026-08-01 发布日期:2026-09-29
通讯作者: 王舟舟, 余颖 E-mail:wzzphysics@163.com;yuying01@ccnu.edu.cn
基金资助:
我们感谢国家重点研发计划(2026YFE0199500)；国家自然科学基金(52472205)以及华中师范大学自主科研基金(教育部高校基本科研业务费，CCNU26ZH014)的资助。

Scalable electrodeposited MoNi₄ alloy/amorphous NiMoO_x electrodes for stable alkaline seawater hydrogen evolution

Yaran Shi¹, Ying Ma², Liming Li², Anran Zhang², Zhouzhou Wang³, Ying Yu¹

1 Institute of Nanoscience and Nanotechnology, College of Physical Science and Technology, Central China Normal University, Wuhan 430079, Hubei Province, China;
2 PERIC Hydrogen Technologies Co., Ltd., Handan 057551, Hebei Province, China;
3 Hyper Hydrogen (Wuhan) Technology Co., Ltd., Wuhan 430223, Hubei Province, China

Received:2026-06-29 Revised:2026-07-31 Accepted:2026-08-01 Published:2026-09-29
Contact: Zhouzhou Wang, Ying Yu E-mail:wzzphysics@163.com;yuying01@ccnu.edu.cn

1. 2026.100381-ACTPHY-D-26-00453-16p-2# SI.pdf(1276KB)

摘要/Abstract

摘要： 在碱性析氢反应(HER)中，Volmer步骤(H₂O + e^- → H* + OH^-)的缓慢动力学以及海水中的腐蚀性氯离子，对高效海水电解构成了双重挑战。本文通过一步电沉积法合成了MoNi₄合金/非晶态NiMoO_x(MoNi₄/NiMoO_x)催化剂，在10 mA cm^-2下仅需28 mV的过电位，并在碱性天然海水中于500 mA cm^-2下稳定运行800 h。该电极可放大至15 cm×15 cm，其切割片(110 cm²)在工业电解槽中于2 A cm^-2下稳定工作750 h。X射线光电子能谱(XPS)和X射线吸收精细结构(XAFS)分析表明，MoNi₄/NiMoO_x通过从MoNi₄到NiMoO_x的电子转移，生成了富含电子的低价Ni^δ+(0 < δ < 1)物种。原位拉曼光谱、Bode相分析和局部pH测量证明，MoNi₄/NiMoO_x中的这种界面电子效应通过促进界面水分解加速了Volmer决速步骤，并维持了热力学上更有利于HER的较低局部pH值。理论计算显示，MoNi₄/NiMoO_x的d带中心更接近费米能级，提供了更强的H*吸附，近乎热中性的Volmer解离步骤以及固有的Cl^-排斥作用，从而实现了在海水中的良好稳定性。该策略为直接海水电解提供了一条简单且可放大的高性能非贵金属催化剂制备途径。

关键词: MoNi₄/NiMoO_x, 碱性海水电解, 析氢反应, Volmer步骤

Abstract: The sluggish kinetics of the Volmer step (H₂O + e^- → H* + OH^-) in alkaline hydrogen evolution reaction (HER) and the corrosive chloride ions in seawater pose dual challenges for efficient seawater electrolysis. Here a MoNi₄ alloy/amorphous NiMoO_x (MoNi₄/NiMoO_x) catalyst is synthesized by one-step electrodeposition, delivering an overpotential of only 28 mV at 10 mA cm^-2 and stably running at 500 mA cm^-2 in alkaline natural seawater for 800 h. The electrode can be scaled up to 15 cm×15 cm, and a cut piece (110 cm²) works stably in an industrial electrolyzer at 2 A cm^-2 for 750 h. X-ray photoelectron spectroscopy (XPS) and X-ray absorption fine structure (XAFS) reveal that MoNi₄/NiMoO_x generates electron-rich low-valent Ni^d⁺ (0 < d < 1) species through electron transfer from MoNi₄ to NiMoO_x. In situ Raman spectroscopy, bode phase analysis, and local pH measurements demonstrate that this interfacial electronic effect in MoNi₄/NiMoO_x accelerates the Volmer rate-determining step by facilitating interfacial water dissociation, and maintains a lower local pH that is thermodynamically more favorable for HER. Theoretical calculations show that MoNi₄/NiMoO_x possesses a d-band center shifted closer to the Fermi level, which provides stronger H* adsorption, a nearly thermoneutral Volmer dissociation step, and intrinsic Cl^- repulsion, leading to the good stability in seawater. This strategy provides a simple and scalable route to high-performance non-noble metal catalysts for direct seawater electrolysis.

Key words: MoNi₄/NiMoO_x, Alkaline seawater electrolysis, Hydrogen evolution reaction, Volmer step

史雅然, 马颖, 李黎明, 张安然, 王舟舟, 余颖. 可放大电沉积的MoNi₄合金/非晶NiMoO_x电极用于稳定碱性海水析氢[J]. 物理化学学报, 2026, 42(11), 100381. doi: 10.1016/j.actphy.2026.100381

Yaran Shi, Ying Ma, Liming Li, Anran Zhang, Zhouzhou Wang, Ying Yu. Scalable electrodeposited MoNi₄ alloy/amorphous NiMoO_x electrodes for stable alkaline seawater hydrogen evolution[J]. Acta Phys. -Chim. Sin. 2026, 42(11), 100381. doi: 10.1016/j.actphy.2026.100381

链接本文: https://www.whxb.pku.edu.cn/CN/10.1016/j.actphy.2026.100381

https://www.whxb.pku.edu.cn/CN/Y2026/V42/I11/100381

参考文献

[1] Z. Wang, J. Zhou, Y. Shi, L. Luo, H. Li, Q. Zhou, C. Wang, Z. Xing, Z. Yang, Y. Yu, Chem. Soc. Rev. 55(2026) 254, https://doi.org/10.1039/D5CS00881F.
[2] Y. Shi, Z. Yang, X. Li, Z. Wang, X. Dong, W. Cao, C. Wei, Z. Huang, Z. Sun, Y. Jiang, et al., Mater. Today Phys. 61(2026) 102021, https://doi.org/10.1016/j.mtphys.2026.102021.
[3] Y. Xiao, Z. Shi, H. Yan, J. Li, S. Han, Y. Yang, X. Jing, Chem. Commun. 61(2025) 16648, https://doi.org/10.1039/D5CC03929K.
[4] Z. Wang, Q. Zhou, L. Luo, Y. Shi, H. Li, C. Wang, K. Lin, C. Wang, L. Zhu, L. Han, et al., Chin. J. Catal. 76(2025) 146, https://doi.org/10.1016/S1872-2067(25)64748-6.
[5] Z. Wang, Y. Chen, B. Sheng, J. Li, L. Yao, Y. Yu, J. Song, T. Yu, Y. Li, H. Pan, et al., Angew. Chem. Int. Ed. 63(2024) e202400011, https://doi.org/10.1002/anie.202400011.
[6] H. Ye, Y. Xin, Z. Zhang, S. Cheng, R. Zhang, M. Wang, Y. Zhu, Z. Ren, Chem. Commun. 62(2026) 255, https://doi.org/10.1039/D5CC05104E.
[7] F. Sun, Z. Li, H. Xu, Y. Fu, H. Li, Y. Yao, L. Ren, X. He, Y. Li, R. Yang, et al., Adv. Energy Mater. 14(2024) 2400875, https://doi.org/10.1002/aenm.202400875.
[8] J. Zhou, L. Yu, Q. Zhou, C. Huang, Y. Zhang, B. Yu, Y. Yu, Appl. Catal. B: Environ. 288(2021) 120002, https://doi.org/10.1016/j.apcatb.2021.120002.
[9] W. Cui, X. Ren, S. Wang, Y. Zhang, Z. Li, K. Wang, F. Gao, Z. Shen, Y. Liu, X. Wang, et al., Adv. Energy Mater. 15(2025) e03257, https://doi.org/10.1002/aenm.202503257.
[10] J. Gao, H. Zhang, X. Zhao, Y. Wang, H. Zhu, X. Kong, Y. Liang, T. Ou, R. Ren, Y. Gu, et al., Chin. J. Struct. Chem. 44(2025) 100563, https://doi.org/10.1016/j.cjsc.2025.100563.
[11] M. Li, H. Li, H. Fan, Q. Liu, Z. Yan, A. Wang, B. Yang, E. Wang, Nat. Commun. 15(2024) 6154, https://doi.org/10.1038/s41467-024-50535-2.
[12] B. Zhong, S. Wan, P. Kuang, B. Cheng, L. Yu, J. Yu, Appl. Catal. B: Environ. 340(2024) 123195, https://doi.org/10.1016/j.apcatb.2023.123195.
[13] R. Duan, X. Wang, P. Zhou, Y. Liu, C. Li, Acta Phys. Chim. Sin. 41(2025) 100111, https://doi.org/10.1016/j.actphy.2025.100111.
[14] P. Kuang, Z. Ni, B. Zhu, Y. Lin, J. Yu, Adv. Mater. 35(2023) 2303030, https://doi.org/10.1002/adma.202303030.
[15] Z. Ni, C. Luo, B. Cheng, P. Kuang, Y. Li, J. Yu, Appl. Catal. B: Environ. 321(2023) 122072, https://doi.org/10.1016/j.apcatb.2022.122072.
[16] H.Q. Fu, M. Zhou, P.F. Liu, P. Liu, H. Yin, K.Z. Sun, H.G. Yang, M. Al-Mamun, P. Hu, H.-F. Wang, et al., J. Am. Chem. Soc. 144(2022) 6028, https://doi.org/10.1021/jacs.2c01094.
[17] K. Lu, Y. Liu, F. Lin, I.A. Cordova, S. Gao, B. Li, B. Peng, H. Xu, J. Kaelin, D. Coliz, et al., J. Am. Chem. Soc. 142(2020) 12613, https://doi.org/10.1021/jacs.0c00241.
[18] L. Yu, Q. Zhu, S. Song, B. McElhenny, D. Wang, C. Wu, Z. Qin, J. Bao, Y. Yu, S. Chen, et al., Nat. Commun. 10(2019) 5106, https://doi.org/10.1038/s41467-019-13092-7.
[19] L. Wu, F. Zhang, S. Song, M. Ning, Q. Zhu, J. Zhou, G. Gao, Z. Chen, Q. Zhou, X. Xing, et al., Adv. Mater. 34(2022) 2201774, https://doi.org/10.1002/adma.202201774.
[20] M. Ning, F. Zhang, L. Wu, X. Xing, D. Wang, S. Song, Q. Zhou, L. Yu, J. Bao, S. Chen, et al., Energy Environ. Sci. 15(2022) 3945, https://doi.org/10.1039/D2EE01094A.
[21] M. Li, Y. Chen, X. Wang, J. Zheng, K. Chen, H. Xian, Y. Lv, W. Zhou, ACS Nano 19(2025) 35647, https://doi.org/10.1021/acsnano.5c11278.
[22] H. Funke, M. Chukalina, A.C. Scheinost, J. Synchrotron Radiat. 14(2007) 426, https://doi.org/10.1107/S0909049507031901.
[23] B. Ravel, M. Newville, J.Synchrotron Radiat. 12(2005) 537, https://doi.org/10.1107/S0909049505012719.
[24] K. Yamanaka, Jpn. J. Appl. Phys. 28(1989) 632, https://doi.org/10.1143/JJAP.28.632.
[25] J. Guo, Y. Zheng, Z. Hu, C. Zheng, J. Mao, K. Du, M. Jaroniec, S.-Z. Qiao, T. Ling, Nat. Energy 8(2023) 264, https://doi.org/10.1038/s41560-023-01195-x.
[26] Y. Yokoyama, K. Miyazaki, Y. Kondo, Y. Miyahara, T. Fukutsuka, T. Abe, Chem. Lett. 49(2020) 195, https://doi.org/10.1246/cl.190856.
[27] P. Steegstra; E. Ahlberg, J. Electroanal. Chem. 685(2012) 1, https://doi.org/10.1016/j.jelechem.2012.07.040.
[28] J. Hutter, M. Iannuzzi, F. Schiffmann, J. VandeVondele, WIREs Comput. Mol. Sci. 4(2014) 15, https://doi.org/10.1002/wcms.1159.
[29] J.P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 77(1996) 3865, https://doi.org/10.1103/PhysRevLett.77.3865.
[30] G. Kresse, J. Furthmüller, Comput. Mater. Sci. 6(1996) 15, https://doi.org/10.1016/0927-0256(96)00008-0.
[31] H.J. Monkhorst, J.D. Pack, Phys. Rev. B 13(1976) 5188, https://doi.org/10.1103/PhysRevB.13.5188.
[32] T. Lu, F. Chen, J. Comput. Chem. 33(2012) 580, https://doi.org/10.1002/jcc.22885.
[33] T. Lu, J. Chem. Phys. 161(2024) 082503. https://doi.org/10.1063/5.0216272.
[34] W. Yu, M.H. Richter, E. Simonoff, B.S. Brunschwig, N.S. Lewis, J. Mater. Chem. A 9(2021) 22958, https://doi.org/10.1039/D1TA04145B.
[35] Y. Guo, L. Shi, X. Shi, T. Zhao, W. Tian, S. Zhang, D. Liu, Y. Li, F. Zhong, S. Zhao, Nat. Chem. Eng. 2(2025) 474, https://doi.org/10.1038/s44286-025-00262-2.
[36] Y. Sun, Z. Xue, Q. Liu, Y. Jia, Y. Li, K. Liu, Y. Lin, M. Liu, G. Li, C.-Y. Su, Nat. Commun. 12(2021) 1369, https://doi.org/10.1038/s41467-021-21595-5.
[37] W. Yu, M.H. Richter, P. Buabthong, I.A. Moreno-Hernandez, C.G. Read, E. Simonoff, B.S. Brunschwig, N.S. Lewis, Energy Environ. Sci. 14(2021) 6007, https://doi.org/10.1039/D1EE02809J.
[38] X. Feng, K. Guo, C. Jia, B. Liu, S. Ci, J. Chen, Z. Wen, Acta Phys. Chim. Sin. 40(2024) 2303050, https://doi.org/10.3866/PKU.WHXB202303050.
[39] M. Lei, W. Hu, K. Lin, X. Sun, H. Zhang, Y. Qian, T. Kang, X. Wu, H. Liao, Y. Pan, et al., Acta Phys. Chim. Sin. 41(2025) 100083, https://doi.org/10.1016/j.actphy.2025.100083.
[40] Y. Xu, S. Li, J. Cao, Z. Ren, Y. He, Z. Cai, C. Hou, J. Zhang, Z. Chen, R. Shi, et al., Energy Environ. Sci. 18(2025) 4811, https://doi.org/10.1039/D4EE05829A.
[41] D. Zhang, H. Gong, T. Liu, J. Yu, P. Kuang, J. Colloid Interface Sci. 672(2024) 423, https://doi.org/10.1016/j.jcis.2024.06.023.
[42] Y. Li, T. Wu, J. Chi, J. Yu, J. Wang, K. Zhang, L. Wang, Y. Yang, J. Mater. Sci. Technol. 273(2026) 302, https://doi.org/10.1016/j.jmst.2026.03.023.
[43] J. Zhu, J. Qian, X. Peng, B. Xia, D. Gao, Nano-Micro Lett. 15(2023) 30, https://doi.org/10.1007/s40820-022-01011-3.
[44] R. Liu, Z. Ni, O. Ruzimuradov, K. Turayev, T. Liu, L. Yu, P. Kuang, Acta Phys. Chim. Sin. 41(2025) 100159, https://doi.org/10.1016/j.actphy.2025.100159.
[45] Z. Li, G. Lin, L. Wang, H. Lee, J. Du, T. Tang, G. Ding, R. Ren, W. Li, X. Cao, et al., Nat. Catal. 7(2024) 944, https://doi.org/10.1038/s41929-024-01209-1.
[46] A.H. Shah, Z. Zhang, Z. Huang, S. Wang, G. Zhong, C. Wan, A.N. Alexandrova, Y. Huang, X. Duan, Nat. Catal. 5(2022) 923, https://doi.org/10.1038/s41929-022-00851-x.
[47] Y. Li, B. Lan, B. Guan, C. Dai, F. Zhang, Z. Lin, Acta Phys. Chim. Sin. 40(2024) 2306031, https://doi.org/10.3866/PKU.WHXB202306031.
[48] J. Gao, J. Liu, M. Wang, N. Sun, H. Hu, X. Cui, X. Zhou, L. Jiang, Chin. J. Catal. 82(2026) 74, https://doi.org/10.1016/S1872-2067(25)64853-4.
[49] L. Luo, W. Li, Y. Kang, Z. Wang, X. Cheng, M. Ruan, Q. Wu, Appl. Surf. Sci. 606(2022) 154950. https://doi.org/10.1016/j.apsusc.2022.154950.
[50] C. Huang, Q. Zhou, D. Duan, L. Yu, W. Zhang, Z. Wang, J. Liu, B. Peng, P. An, J. Zhang, et al., Energy Environ. Sci. 15(2022) 4647, https://doi.org/10.1039/D2EE01478E.
[51] D. Tian, J. Yan, L. Yang, M. Xi, Y. Long, H. Zhang, A. Chen, Chem. Eng. J. 520(2025) 165957, https://doi.org/10.1016/j.cej.2025.165957.
[52] L. Zhou, Z. Zhao, A. Xie, R. Zhang, L. Cheng, J. Liu, H. Zhou, Y. Chen, P. Wan, Y. Tang, Chem. Commun. 61(2025) 4983, https://doi.org/10.1039/D5CC00513B.
[53] S. Liu, Z. Zhang, K. Dastafkan, Y. Shen, C. Zhao, M. Wang, Nat. Commun. 16(2025) 773, https://doi.org/10.1038/s41467-025-55856-4.
[54] Z. Ge, S. Chen, H. Zhang, C. Liu, G. Che, X. Wang, Z. Liu, Angew. Chem. Int. Ed. 65(2026) e6457530, https://doi.org/10.1002/anie.6457530.
[55] K. Liu, K. Deng, X. Zhang, L. Lei, Z. Chu, X. Chen, Y. Li, X. Han, X. Guo, D. Wang, Adv. Mater. 38(2026) e72996, https://doi.org/10.1002/adma.72996.
[56] X. He, Y. Yao, M. Zhang, Y. Zhou, L. Zhang, Y. Ren, K. Dong, H. Tang, J. Nan, X. Zhou, et al., Nat. Commun. 16(2025) 5541, https://doi.org/10.1038/s41467-025-60620-9.
[57] X. Wang, F. Liu, H. Qin, J. Li, X. Chen, K. Liu, T. Zhao, W. Yang, M. Yu, G. Fan, et al., Angew. Chem. Int. Ed. 63(2024) e202409628, https://doi.org/10.1002/anie.202409628.
[58] Y. Yu, W. Zhou, J. Yuan, X. Zhou, X. Zhang, X. Li, X. Xia, L. Zhang, Y. Chen, X. Meng, et al., Nat. Commun. 17(2026) 3014, https://doi.org/10.1038/s41467-026-69755-9.
[59] Y. Ren, D. Wang, S. Sun, Z. Li, Y. Yao, Z. Yang, H. Wang, J. Song, C. Yang, Z. Cai, et al., Nat. Commun. 17(2026) 5178, https://doi.org/10.1038/s41467-026-71910-1.
[60] W. Hao, L. Wu, Y. Wang, P. Zhao, S. Weng, J. Zhang, J. Fan, L. Zhai, Y. Guo, H. Li, et al., Nat. Commun. 17(2026) 7158, https://doi.org/10.1038/s41467-026-73894-4.
[61] Z. Li, M. Li, Y. Chen, X. Ye, M. Liu, L.Y S. Lee, Angew. Chem. Int. Ed. 63(2024) e202410396, https://doi.org/10.1002/anie.202410396.
[62] W. Xu, Z. Wang, P. Liu, X. Tang, S. Zhang, H. Chen, Q. Yang, X. Chen, Z. Tian, S. Dai, et al., Adv. Mater. 36(2024) 2306062, https://doi.org/10.1002/adma.202306062.
[63] J. Wang, Y. Liu, G. Yang, Y. Jiao, Y. Dong, C. Tian, H. Yan, H. Fu, Nat. Commun. 16(2025) 1319, https://doi.org/10.1038/s41467-025-56639-7.
[64] Q. Sha, W. Shiyuan, Y. Li, F. Yisui, Z. Zhuang, L. Shihang, G. Xinlong, L. Tianshui, L. Hui, Z. Zhongbin, et al., Nature 639(2025) 360, https://doi.org/10.1038/s41586-025-08610-1.
[65] W. Li, Z. Ni, O. Akdim, T. Liu, B. Zhu, P. Kuang, J. Yu, Adv. Mater. 37(2025) 2503742, https://doi.org/10.1002/adma.202503742.
[66] H. Wu, X. Jiang, J. Lu, Y. Li, X. Li, G. Ju, R. Li, J. Zhang, Chin. J. Catal. 79(2025) 91, https://doi.org/10.1016/S1872-2067(25)64852-2.
[67] W. Wu, S. Yang, H. Qian, L. Zhang, L. Peng, L. Li, B. Liu, Z. Wei, Chin. J. Catal. 66(2024) 1, https://doi.org/10.1016/S1872-2067(24)60130-0.
[68] W. Chen, B. Wu, Y. Wang, W. Zhou, Y. Li, T. Liu, C. Xie, L. Xu, S. Du, M. Song, et al., Energy Environ. Sci. 14(2021) 6428, https://doi.org/10.1039/D1EE01395E.
[69] Z. Chen, W. Gong, J. Wang, S. Hou, G. Yang, C. Zhu, X. Fan, Y. Li, R. Gao, Y. Cui, Nat. Commun. 14(2023) 5363, https://doi.org/10.1038/s41467-023-41097-w.
[70] S. Qian, F. Xu, Y. Fan, N. Cheng, H. Xue, Y. Yuan, R. Gautier, T. Jiang, J. Tian, Nat. Commun. 15(2024) 2774, https://doi.org/10.1038/s41467-024-47061-6.
[71] J. Zhu, N. Yao, C. Jiang, W. Luo, Angew. Chem. Int. Ed. 65(2026) e8433540, https://doi.org/10.1002/anie.8433540.
[72] Y. Liu, W. Shen, Y. Hou, L. Zhang, F.R. Wang, P. Xi, C.-H. Yan, Sci. Adv. 12(2026) eaeb8831, https://doi.org/10.1126/sciadv.aeb8831
[73] J. Zhu, X. Sun, N. Feng, B. Zhao, M. Qiu, J. Xu, W. Luo J. Am. Chem. Soc. 147(2025) 47454, https://doi.org/10.1021/jacs.5c16177.
[74] Q. Zhang, K. Lian, Q. Liu, G. Qi, S. Zhang, J. Luo, X. Liu, J. Colloid Interf. Sci. 646(2023) 844, https://doi.org/10.1016/j.jcis.2023.05.074.
[75] Q. Li, C. Chen, W. Luo, X. Yu, Z. Chang, F. Kong, L. Zhu, Y. Huang, H. Tian, X. Cui, et al., Adv. Energy Mater. 14(2024) 2304099, https://doi.org/10.1002/aenm.202304099.
[76] G. Lin, A. Dong, Z. Li, W. Li, X. Cao, Y. Zhao, L. Wang, L. Sun, Adv. Mater. 37(2025) 2507525, https://doi.org/10.1002/adma.202507525.
[77] H. Hu, Z. Zhang, Y. Zhang, T. Thomas, H. Du, K. Huang, J.P. Attfield, M. Yang, Energy Environ. Sci. 16(2023) 4584, https://doi.org/10.1039/D3EE01541F.
[78] M. Zhang, K. Zhang, X. Ai, X. Liang, Q. Zhang, H. Chen, X. Zou, Chin. J. Catal. 43(2022) 2987, https://doi.org/10.1016/S1872-2067(22)64103-2.
[79] Y. Feng, Y. Xie, Y. Yu, Y. Chen, Q. Liu, H. Bao, F. Luo, S. Pan, Z. Yang, Angew. Chem. Int. Ed. 64(2025) e202413417, https://doi.org/10.1002/anie.202413417.
[80] Y. Xing, H. Xue, J. Sun, N. Guo, T. Song, J. Sun, Y.-R. Hao, Q. Wang, Acta Phys. Chim. Sin. 40(2024) 2304046, https://doi.org/10.3866/PKU.WHXB202304046.
[81] Z. Ni, O. Ruzimuradov, K. Turayev, S. Chen, G. Tang, J. Zhang, O. Akdim, P. Kuang, G.J. Hutchings, J. Yu, Angew. Chem. Int. Ed. 65(2026) e9797893, https://doi.org/10.1002/anie.9797893.
[82] H. Gong, B. Zhu, D. Zhang, T. Liu, P. Kuang, J. Yu, Appl. Catal. B: Environ. 349(2024) 123892, https://doi.org/10.1016/j.apcatb.2024.123892.
[83] X. Luo, Y. Wang, G. Yang, L. Liu, S. Guo, Y. Cui, X. Xu, Chin. J. Catal. 61(2024) 281, https://doi.org/10.1016/S1872-2067(24)60034-3.
[84] Z. Wan, Y. Yang, Z. Wang, L. Wu, H. Zhang, Q. Shi, X. Liu, H. Yang, B. Kang, Q. Xu, et al., Chin. J. Catal. 84(2026) 130, https://doi.org/10.1016/S1872-2067(26)65000-0.
[85] L. Chen, Y. Fang, M. Pang, R. Sun, L. Xu, Q. Zhou, Y. Tang, Chin. J. Struct. Chem. 44(2025) 100461, https://doi.org/10.1016/j.cjsc.2024.100461.
[86] B.S. Salokhe, T.T. Nguyen, A. Sakthivel, S.S. Salokhe, V. Gurav, N.H. Kim, D.H. Kim, D.T. Tran, J.H. Lee, J. Mater. Sci. Technol. 276(2027) 279, https://doi.org/10.1016/j.jmst.2026.04.033.
[87] H. Gong, D. Zhang, T. Liu, P. Kuang, J. Yu, Small 21(2025) 2407790, https://doi.org/10.1002/smll.202407790.
[88] C. Huang, Q. Zhou, L. Yu, D. Duan, T. Cao, S. Qiu, Z. Wang, J. Guo, Y. Xie, L. Li, et al., Adv. Energy Mater. 13(2023) 2301475, https://doi.org/10.1002/aenm.202301475.

可放大电沉积的MoNi₄合金/非晶NiMoO_x电极用于稳定碱性海水析氢

Scalable electrodeposited MoNi₄ alloy/amorphous NiMoO_x electrodes for stable alkaline seawater hydrogen evolution

PDF

赞

补充材料

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

推荐阅读 0

[1]	伍昊, 李凤麒, 石欣伟, 卞海峰, 周庆, 贾顺顺, 马玉洁, 顾坚, 张靖梓, 何水剑, 孟祥康. 机器学习指导筛选多主元合金作为析氢反应电催化剂[J]. 物理化学学报, 2026, 42(8): 100227 - .
[2]	赵呈孝, 李昭霖, 吴东方, 杨小飞. SBA-15模板化共价三嗪框架增强光催化产氢[J]. 物理化学学报, 2026, 42(1): 100149 - .
[3]	柳如艳, 倪振瑞, RuzimuradovOlim, TurayevKhayit, 刘涛, 余罗, 邝攀勇. Ni诱导的Pt 5d-H 1s反键轨道调控以增强析氢和尿素氧化[J]. 物理化学学报, 2025, 41(12): 100159 - .
[4]	秦春玲, 陈爽, GomaaHassanien, ShenashenMohamed A., El-SaftySherif A., 刘倩, 安翠华, 刘熙俊, 邓齐波, 胡宁. 外加物理场调控二维材料的HER和OER性能[J]. 物理化学学报, 2024, 40(9): 2307059 - .
[5]	孙巍, 王永靖, 项坤, 白赛帅, 王海涛, 邹菁, Arramel, 江吉周. CoP修饰Ti₃C₂T_x MXene纳米复合材料作为高效析氢反应电催化剂[J]. 物理化学学报, 2024, 40(8): 2308015 - .
[6]	卢华森, 宋世旭, 贾萁森, 刘光波, 姜鲁华. 用于光电催化水分解的氧化亚铜基光电阴极研究进展[J]. 物理化学学报, 2024, 40(2): 2304035 - .
[7]	周正宇, 姚惠琴, 吴有林, 李腾, 椿范立, 靳治良. Cu-石墨炔/双金属钨酸盐S型异质结协同增强光催化析氢[J]. 物理化学学报, 2024, 40(10): 2312010 - .
[8]	卢尔君, 陶俊乾, 阳灿, 侯乙东, 张金水, 王心晨, 付贤智. 碳包覆Pd/TiO₂光催化产氢协同胺类选择性氧化合成亚胺[J]. 物理化学学报, 2023, 39(4): 2211029 -0 .
[9]	徐斯然, 吴奇, 卢帮安, 唐堂, 张佳楠, 胡劲松. “绿氢”工业化碱性催化剂研究现状及未来展望[J]. 物理化学学报, 2023, 39(2): 2209001 -0 .
[10]	王正慜, 洪庆玲, 王晓慧, 黄昊, 陈煜, 李淑妮. 氮掺杂石墨烯气凝胶锚定RuP纳米粒子用于水合肼氧化辅助产氢[J]. 物理化学学报, 2023, 39(12): 2303028 - .
[11]	郑书逸, 吴佳, 王可, 胡梦晨, 文欢, 尹诗斌. 钴掺杂电子调控Ni-Mo-O多孔纳米棒选择性氧化5-羟甲基糠醛耦合制氢[J]. 物理化学学报, 2023, 39(12): 2301032 - .
[12]	李孟婷, 郑星群, 李莉, 魏子栋. 碱性介质中氢氧化和析氢反应机理研究现状[J]. 物理化学学报, 2021, 37(9): 2007054 - .
[13]	闫大强, 张林, 陈祖鹏, 肖卫平, 杨小飞. 镍基金属有机框架衍生的双功能电催化剂用于析氢和析氧反应[J]. 物理化学学报, 2021, 37(7): 2009054 - .
[14]	高增强, 王聪勇, 李俊俊, 朱亚廷, 张志成, 胡文平. 导电金属有机框架材料在电催化中的成就，挑战和机遇[J]. 物理化学学报, 2021, 37(7): 2010025 - .
[15]	葛靖暄, 胡钧, 朱盈婷, 泽妮诗, 臧德进, 秦召贤, 黄毅超, 张江威, 魏永革. 多酸在电催化析氢反应中的应用研究进展[J]. 物理化学学报, 2020, 36(1): 1906063 - .