稀土离子及其配合物对二棕榈酰磷脂酰乙醇胺酯双层结构的影响

doi:10.3866/PKU.WHXB19950509

物理化学学报 >> 1995, Vol. 11 >> Issue (05): 429-432.doi: 10.3866/PKU.WHXB19950509

稀土离子及其配合物对二棕榈酰磷脂酰乙醇胺酯双层结构的影响

赵冰, 袁春波, 赵大庆, 倪嘉缵

中国科学院应用化学研究所稀土化学与物理开放实验室|长春 130022|吉林大学分子光谱与分子结构开放实验室|长春 130023

收稿日期:1994-01-22 修回日期:1994-05-31 发布日期:1995-05-15
通讯作者: 赵冰

Study of FT-Raman Spectroscopy on the Effects of Lanthanide Ions and Their Complexes on the Fluidity of Dipalmitoylphosphatidylethanolamine Bilayer

Zhao Bing, YUAN Chun-Bei, Zhao Da-Qing, Ni Jia-Zuang

Laboratory of Rare Earth Chemistry and Physics,Changchun Institute of Applied Chemsitry,Academia Sinica,Changchun 130022|Institute of Theoretical Chemistry,Jilin University,Changchun 130023

Received:1994-01-22 Revised:1994-05-31 Published:1995-05-15
Contact: Zhao Bing

摘要/Abstract

关键词: 稀土离子及配合物, 拉曼光谱, 二棕榈酰磷脂酰乙醇胺

Abstract:

The effects of lanthanide ions and their complexes of citrate and DTPA ligands on the fluldity of dipalmitoylphosphatidylethanolamine (DPPE) bilayers have been studied by FT-Raman spectroscopy. The results show that lanthanide ions of lower concentration decrease the fluidity of acyl chains of DPPE bilayers and change the conformation of C-C-C backbone from gauche to the trans lanthanide ions of higher concentration, however, increase the fluidity of acyl chains and increase the gauche population of C-C-C backbone. Lanthanide complex of citrate have no effect on the fluidity of acyl chains of DPPE bilayers in the region of experimental concentration, but La-DTPA complex increase slightly the fluidity of acyl chains. The results also indicated that lanthanide ion of lower concentration changed the lattice packing of hydrocarbon chains from hexagonal form to orthorhombic form, but it is still in hexagonal or distorted hexagonal lattice cell in the gel state in the presence of metal ions and lanthanide complexes of higher concentration.

Key words: Lanthanide ion, Lanthanide complex, FT-Raman spectroscopy Dipalmitoylphosphatidylethanolamine

赵冰, 袁春波, 赵大庆, 倪嘉缵. 稀土离子及其配合物对二棕榈酰磷脂酰乙醇胺酯双层结构的影响[J]. 物理化学学报, 1995, 11(05): 429-432.

Zhao Bing, YUAN Chun-Bei, Zhao Da-Qing, Ni Jia-Zuang. Study of FT-Raman Spectroscopy on the Effects of Lanthanide Ions and Their Complexes on the Fluidity of Dipalmitoylphosphatidylethanolamine Bilayer[J]. Acta Phys. -Chim. Sin., 1995, 11(05): 429-432.

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB19950509

https://www.whxb.pku.edu.cn/CN/Y1995/V11/I05/429

[1]	张月皎, 朱越洲, 李剑锋. 拉曼光谱在燃料电池领域的应用[J]. 物理化学学报, 2021, 37(9): 2004052 - .
[2]	张宗辉, 任进军, 胡丽丽. 利用固态核磁共振研究100LiO_1/2-(100-x)PO_5/2-xTeO₂快离子导电玻璃的结构[J]. 物理化学学报, 2020, 36(11): 2001048 - .
[3]	刘芳,张鲁凤,董倩,陈卓. 小尺寸金石墨纳米颗粒的合成与表征[J]. 物理化学学报, 2019, 35(6): 651 -656 .
[4]	韩磊,彭丽,蔡凌云,郑旭明,张富山. 液态聚乙二醇CH₂剪切振动和扭转振动——拉曼光谱和密度泛函理论计算[J]. 物理化学学报, 2017, 33(5): 1043 -1050 .
[5]	吴元菲,李明雪,周剑章,吴德印,田中群. 密度泛函理论研究银上吸附对巯基吡啶的SERS化学增强效应[J]. 物理化学学报, 2017, 33(3): 530 -538 .
[6]	金璐頔,徐晶晶,张勇,余跃洲,刘畅,赵东平,叶安培. 软骨细胞体外增殖去分化的拉曼光谱分析[J]. 物理化学学报, 2017, 33(12): 2446 -2453 .
[7]	金颖淳,郑旭明. 2, 4-二硫代尿嘧啶的紫外吸收光谱和共振拉曼光谱[J]. 物理化学学报, 2017, 33(10): 1989 -1997 .
[8]	马红星,葛婷婕,蔡倩倩,徐颖华,马淳安. 水溶液中银阴极对3,4,5,6-四氯吡啶甲酸脱氯反应的催化作用[J]. 物理化学学报, 2016, 32(7): 1715 -1721 .
[9]	袁俊生,刘子禹,李非,李申予. 利用X射线衍射和拉曼光谱法对KCl和NaCl混合溶液微观结构的研究[J]. 物理化学学报, 2016, 32(5): 1143 -1150 .
[10]	阎波,周桓,李文轩. 拉曼光谱法研究Na⁺, Mg²⁺//SO₄^2-, Cl^-, H₂O四元体系中SO₄^2-离子缔合结构特征及其变化规律[J]. 物理化学学报, 2016, 32(2): 405 -414 .
[11]	仲敬荣, 邵浪, 余春荣, 任一鸣. UF₄在空气、氧或湿氧中热化学反应研究[J]. 物理化学学报, 2015, 31(Suppl): 25 -31 .
[12]	陈晨,逯丹凤,程进,祁志美. 银膜表面等离子体耦合辐射特性的仿真分析[J]. 物理化学学报, 2015, 31(11): 2023 -2028 .
[13]	邓淑芬,黄溦,张继芳,林玲,何嘉伟,卞勋涛,陈文凯,孙建军. 双氰胺在金团簇上吸附的密度泛函理论和表面增强拉曼光谱研究[J]. 物理化学学报, 2015, 31(10): 1872 -1879 .
[14]	曹潇潇, 苏艳, 赵纪军, 刘昌岭, 周潘旺. 烷烃客体分子(C_nH_m, n≤6, m≤14)在5¹²6²和5¹²6⁴水笼中的稳定性与拉曼光谱的密度泛函理论计算[J]. 物理化学学报, 2014, 30(8): 1437 -1446 .
[15]	周杰, 李柏霖, 朱沛志, 卢晓林. 表面增强拉曼光谱研究自组装单分子层在化学接触和纳米隔绝下的分子振动活性变化[J]. 物理化学学报, 2014, 30(4): 623 -627 .

稀土离子及其配合物对二棕榈酰磷脂酰乙醇胺酯双层结构的影响

Study of FT-Raman Spectroscopy on the Effects of Lanthanide Ions and Their Complexes on the Fluidity of Dipalmitoylphosphatidylethanolamine Bilayer

PDF

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

推荐阅读 0