紫外激发Sr1-x-yMgP2O7:xCe3+,yTb3+荧光粉的发光特性及能量传递

doi:10.3866/PKU.WHXB201201121

物理化学学报 >> 2012, Vol. 28 >> Issue (03): 699-705.doi: 10.3866/PKU.WHXB201201121

紫外激发Sr_1-x-yMgP₂O₇:xCe³⁺,yTb³⁺荧光粉的发光特性及能量传递

豆喜华¹, 赵韦人¹, 宋恩海¹, 闵华初²

1. 广东工业大学物理与光电工程学院, 广州 510006;
2. 东莞欣光源电子有限公司, 广东东莞 523500

收稿日期:2011-09-08 修回日期:2011-12-21 发布日期:2012-02-23
通讯作者: 赵韦人 E-mail:zwren123@126.com
基金资助:
广东省教育部产学研结合项目(2010B090400021)资助

Optical Properties and Energy Transfer of Sr_1-x-yMgP₂O₇:xCe³⁺,yTb³⁺ Phosphor under Ultraviolet Excitation

DOU Xi-Hua¹, ZHAO Wei-Ren¹, SONG En-Hai¹, MIN Hua-Chu²

1. School of Physics & Optoelectronic Engineering, Guangdong University of Technology, Guangzhou 510006, P. R. China;
2. Dongguan Xinguangyuan Electronics Co. Ltd., Dongguan 523500, Guangdong Province, P. R. China

Received:2011-09-08 Revised:2011-12-21 Published:2012-02-23
Contact: ZHAO Wei-Ren E-mail:zwren123@126.com
Supported by:
The project was supported by the Cooperation Project in Industry, Education and Research of Guangdong Province and Ministry of Education of China (2010B090400021).

摘要/Abstract

摘要： 采用高温固相法合成了Sr_1-x-yMgP₂O₇:xCe³⁺,yTb³⁺荧光粉. 研究了荧光粉的晶体结构、发光特性、荧光寿命、能量传递机理和荧光粉的热稳定性. 研究结果表明: 在SrMgP₂O₇基质中, Ce³⁺的发射峰值为398 nm, Tb³⁺的主发射峰值为545 nm, 它们分别属于5d-4f 跃迁和⁵D₄→⁷F₅跃迁. Ce³⁺和Tb³⁺共掺时, Ce³⁺和Tb³⁺通过电偶极子-电偶极子相互作用发生能量传递, 能量传递的临界距离为0.614 nm. 通过计算得到单掺杂Ce³⁺、Tb³⁺时热猝灭过程的激活能分别为0.122和0.111 eV, Tb³⁺离子的发光热稳定性比Ce³⁺离子的好.

关键词: 发光特性, 荧光寿命, 能量传递, 热稳定性

Abstract: Sr_1-x-yMgP₂O₇:xCe³⁺,yTb³⁺ phosphors were successfully synthesized by a solid-state reaction method. The crystal structure, optical properties, luminescence decay, energy transfer, and thermal stability properties were investigated. The results showed that the emission peaks of the co-doped Ce³⁺ and Tb³⁺ ions in the SrMgP₂O₇ host were located at 398 and 545 nm, respectively. The peaks were attributed to 5d-4f and ⁵D₄→⁷F₅ transitions, respectively. An efficient energy transfer from the Ce³⁺ to Tb³⁺ ions by means of dipole-dipole interactions was observed and the critical distance of the energy transfer was 0.614 nm. The thermal activation energies of 0.122 and 0.111 eV for SrMgP₂O₇:Ce³⁺ and SrMgP₂O₇:Tb³⁺, respectively, were obtained from the temperature dependent (313-453 K) luminescence intensities. The Tb³⁺ ion was found to be superior to Ce³⁺ ion in the thermal stability of light-emitting diodes.

Key words: Optical property, Luminescence decay, Energy transfer, Thermal stability

豆喜华, 赵韦人, 宋恩海, 闵华初. 紫外激发Sr_1-x-yMgP₂O₇:xCe³⁺,yTb³⁺荧光粉的发光特性及能量传递[J]. 物理化学学报, 2012, 28(03), 699-705. doi: 10.3866/PKU.WHXB201201121

DOU Xi-Hua, ZHAO Wei-Ren, SONG En-Hai, MIN Hua-Chu. Optical Properties and Energy Transfer of Sr_1-x-yMgP₂O₇:xCe³⁺,yTb³⁺ Phosphor under Ultraviolet Excitation[J]. Acta Phys. -Chim. Sin. 2012, 28(03), 699-705. doi: 10.3866/PKU.WHXB201201121

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB201201121

https://www.whxb.pku.edu.cn/CN/Y2012/V28/I03/699

参考文献

(1) Tan, Y.; Shi, C. J. Solid State Chem. 2000, 150, 178.

(2) Zhang, X. M.; Su, H. Q.; Ye, Z. R.; Jia, Z. H.; Zang, C. Y.; Shi, C. S. Chin. J. Chin. Univ. 2001, 22 (3), 358. [张献明, 苏海全, 叶泽人, 贾志宏, 臧春雨, 石春山. 高等学校化学学报, 2001, 22 (3), 358.]
(3) Zheng, T.; Li, P.; Xiao, S. C.;Wang, D.; LU, J.W.; Men, Z.W. Acta Phys. -Chim. Sin. 2011, 27 (9), 2095. [郑涛, 李攀, 肖生春, 王丹, 吕景文, 门志伟. 物理化学学报, 2011, 27 (9), 2095.]
(4) Verstegen, J.; Sommerdijk, J. L.; Verriet, J. G. J. Lumin. 1973, 6, 425.

(5) Jiao, H.; Zhang, N.; Jing, X.; Jiao, D. Opt. Mater. 2007, 29, 1023.

(6) Liu,W. R.; Chiu, Y. C.; Yeh, Y. T.; Jang, S. M.; Chen, T. M. J. Electrochem. Soc. 2009, 156, J165.
(7) Jia, D.; Jia,W.;Wang, X. J.; Yen,W. M. Solid State Commun. 2004, 129, 1.

(8) Zhu, H.; Zhu, E.; Yang, H.;Wang, L.; Jin, D.; Yao, K. J. Am. Ceram. Soc. 2008, 91, 1682.

(9) Guo, N.; Song, Y.; You, H.; Jia, G.; Yang, M.; Liu, K.; Zheng, Y.; Huang, Y.; Zhang, H. Eur. J. Inorg. Chem. 2010, 2010, 4636.

(10) Lai, H.; Bao, A.; Yang, Y.; Tao, Y.; Yang, H.; Zhang, Y.; Han, L. The Journal of Physical Chemistry C 2008, 112, 282.

(11) Wang, Z. J.; Yang, Z. P.; Guo, Q. L.; Li, P. L. Acta Phys. -Chim. Sin. 2010, 26 (12), 3317. [王志军, 杨志平, 郭庆林, 李盼来. 物理化学学报, 2010, 26 (12), 3317.]
(12) Tahiri, A. A.; Bali, B. E.; Lachkar, M.; Ouarsal, R.; Zavalij, P. Y. Acta Crystallographica Section E: Structure Reports Online 2001, 58, i9.
(13) Shannon, R. D. Acta Crystallographica Section A: Crystal Physics, Diffraction, Theoretical and General Crystallography. 1976, 32, 751.

(14) Dorenbos, P. Phys. Rev. B 2000, 62, 15650.

(15) Dorenbos, P. J. Lumin. 2000, 91, 155.

(16) Perlin, Y. E. Usp. Fiz. Nauk. 1963, 80, 553.
(17) Nazarov, M.; Tsukerblat, B.; Noh, D. Y. J. Phys. Chem. Solids. 2008, 69, 2605.

(18) Huang, Z. P.; Jing, X. P.; Yu, H. Chin. J. Chin. Univ. 1986, 7 (9), 759. [黄竹坡, 荆西平, 余红. 高等学校化学学报. 1986, 7 (9), 759.]
(19) Yu, M.; Lin, J.; Fu, J.; Zhang, H. J.; Han, Y. C. J. Mater. Chem. 2003, 13, 1413.

(20) Lü, J.; Huang, Y.; Tao, Y.; Seo, H. J. J. Alloy. Compd. 2010, 500, 134.

(21) Zhang, X.; Park, B.; Choi, N.; Kim, J.; Kim, G. C.; Yoo, J. H. Mater. Lett. 2009, 63, 700.

(22) Huang, Y.;Wang, X.; Lee, H. S.; Cho, E.; Jang, K.; Tao, Y. Journal of Physics D: Applied Physics. 2007, 40, 7821.

(23) Holloway,W.W. Jr.; Kestigian, M.; Newman, R. Phys. Rev. Lett. 1963, 11, 458.

(24) Lin, H.; Pun, E. Y. B.;Wang, X.; Liu, X. J. Alloy. Compd. 2005, 390, 197.

(25) Turos-Matysiak, R.; Gryk,W.; Grinberg, M.; Lin, Y. S.; Liu, R. S. Radiat. Meas. 2007, 42, 755.

(26) Liu, X.;Wang, X.;Wang, Z. Phys. Rev. B 1989, 39, 10633.

(27) Pang, R.; Li, C.; Shi, L.; Su, Q. J. Phys. Chem. Solids 2009, 70, 303.

(28) Paulose, P. I.; Jose, G.; Thomas, V.; Unnikrishnan, N. V.; Warrier, M. J. Phys. Chem. Solids 2003, 64, 841.

(29) Martínez-Martínez, R.; álvarez, E.; Speghini, A.; Falcony, C.; Caldiño, U. Thin Solid Films 2010, 518, 5724.

(30) Hsu, C. H.; Lu, C. H. J. Mater. Chem. 2011, 21, 2932.

(31) Li, P. L.; Liu, H. Y.;Wang, Z. J.; Yang, Z. P.; Li, X.; Yang, Y. M. Chin. J. Lumin. 2010, 31 (5), 719. [李盼来, 刘海燕, 王志军, 杨志平, 李旭, 杨艳民. 发光学报, 2010, 31 (5), 719.]
(32) Dexter, D. L. The Journal of Chemical Physics 1953, 21, 836.

(33) Reisfeld, R.; Lieblich-sofer, N. J. Solid State Chem. 1979, 28, 391.

(34) Yang,W. J.; Luo, L.; Chen, T. M.;Wang, N. S. Chem. Mater. 2005, 17, 3883.

(35) Verstegen, J.; Sommerdijk, J. L.; Verriet, J. G. J. Lumin. 1973, 6, 425.

(36) Srivastava, A. M.; Sobieraj, M. T.; Valossis, A.; Ruan, S. K.; Banks, E. J. Electrochem. Soc. 1990, 137, 2959.

(37) Xu, X. R.; Su, M. Z. Luminescence and Luminescent Materials; Chemical Industry Press: Beijing, 2004: pp 49−58. [徐叙瑢, 苏勉曾. 发光学与发光材料. 北京: 化学工业出版社, 2004: 49-58.]
(38) Holtz, P. O.; Monemar, B.; Loykowski, H. J. Phys. Rev. B 1985, 32, 986.

(39) Yu, L. X.; Song, H.; Lu, S.; Liu, Z.; Yang, L.;Wang, T.; Kong, X. Mater. Res. Bull. 2004, 39, 2083.

(40) Lin, C. C.; Liu, R. S.; Tang, Y. S.; Hu, S. F. J. Electrochem. Soc. 2008, 155, J248.
(41) Lozykowski, H. J.; Jadwisienczak,W. M. Physica Status Solidi B-Basic Solid State Phys. 2007, 244, 2109.

(42) Zhang, S.; Nakai, Y.; Tsuboi, T.; Huang, Y.; Seo, H. J. Inorg. Chem. 2011, 5, 2897.
(43) Baginskiy, I.; Liu, R. S. J. Electrochem. Soc. 2009, 156, G29.
(44) Fonger,W. H.; Struck, C.W. J. Chem. Phys. 1970, 52, 6364.

[1]	王甜, 张太阳, 陈悦天, 赵一新. ALD-Al₂O₃涂层保护的高抗湿5-氨基戊酸铰链甲胺铅溴钙钛矿薄膜[J]. 物理化学学报, 2021, 37(4): 2007021 - .
[2]	乔成芳,吕磊,许文风,夏正强,周春生,陈三平,高胜利. 三维无溶剂含能Ag-MOF的制备、热分解动力学及爆炸性能[J]. 物理化学学报, 2020, 36(6): 1905085 - .
[3]	陈文君,薛智敏,王晋芳,蒋静云,赵新辉,牟天成. 低共熔溶剂的热稳定性研究[J]. 物理化学学报, 2018, 34(8): 904 -911 .
[4]	鄢慧君,李彪,蒋宁,夏定国. 阴离子硫氧化还原与Li_1-xNiO_2-yS_y的结构稳定性:第一性原理研究[J]. 物理化学学报, 2017, 33(9): 1781 -1788 .
[5]	陈海龙,边红涛,郑俊荣. 基于超快多维振动光谱技术解析分子体系的三维空间构型[J]. 物理化学学报, 2017, 33(1): 40 -62 .
[6]	刘珊珊,徐征,赵谡玲,梁志琴,朱薇. 氟离子浓度对稀土掺杂上转换发光纳米材料形貌及荧光寿命的影响[J]. 物理化学学报, 2016, 32(8): 2108 -2112 .
[7]	李红梅,兰丽,陈山虎,刘达玉,王卫,龚茂初,陈耀强. 复合沉淀剂制备的CeO₂-ZrO₂-Al₂O₃材料及其负载的单Pd三效催化剂[J]. 物理化学学报, 2016, 32(7): 1734 -1746 .
[8]	边高峰,黄华,占玲玲,吕晓静,曹枫,张诚,张玉建. 有机荧光分子2-氰基-3-(3, 4-二甲氧基苯基)-2-丙烯酰胺的可逆压致变色和质子刺激响应性能[J]. 物理化学学报, 2016, 32(2): 589 -594 .
[9]	武娜, 骆群, 吴振武, 马昌期. 电极界面缓冲层对P3HT:PC₆₁BM太阳能电池热稳定性的影响[J]. 物理化学学报, 2015, 31(7): 1413 -1420 .
[10]	李宪华, 张雷刚, 王雪雪, 于清波. 界面聚合法制备PANI/g-C₃N₄复合催化剂及其热稳定性和可见光催化性能[J]. 物理化学学报, 2015, 31(4): 764 -770 .
[11]	孙盼盼, 刘翔宇, 孙琳, 张盛, 魏青, 尹琰, 杨奇, 陈三平. 分子间作用力构筑的具有柔性结构的醋氯芬酸多聚物: 晶体结构, 热稳定性, 溶解度和DFT计算[J]. 物理化学学报, 2015, 31(2): 211 -220 .
[12]	袁树威, 吕荣, 于安池. IR125和HDITCP在不同烷基链长阳离子离子液体中的光异构化动力学[J]. 物理化学学报, 2014, 30(5): 987 -993 .
[13]	邓陶丽, 闫世润, 胡建国. GdAlO₃：Er³⁺，Yb³⁺荧光粉的制备与上转换发光性能[J]. 物理化学学报, 2014, 30(4): 773 -780 .
[14]	于惠梅, 潘秀红, 张明辉, 刘岩, 余建定. Nd³⁺/Yb³⁺离子共掺的氧化钛基上转换发光玻璃的热学和力学性能[J]. 物理化学学报, 2014, 30(2): 227 -231 .
[15]	朱德华, 钟蓉, 曹宇, 彭志辉, 冯爱新, 向卫东, 赵家龙. CuInS₂量子点敏化太阳能电池中尺寸依赖的电子注入和光电性质[J]. 物理化学学报, 2014, 30(10): 1861 -1866 .

紫外激发Sr_1-x-yMgP₂O₇:xCe³⁺,yTb³⁺荧光粉的发光特性及能量传递

Optical Properties and Energy Transfer of Sr_1-x-yMgP₂O₇:xCe³⁺,yTb³⁺ Phosphor under Ultraviolet Excitation

PDF

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

推荐阅读 0