ALD-Al2O3涂层保护的高抗湿5-氨基戊酸铰链甲胺铅溴钙钛矿薄膜

doi:10.3866/PKU.WHXB202007021

摘要/Abstract

摘要：

近年来，混合铅卤钙钛矿材料在光电领域引发的研究热潮引人注目。然而，钙钛矿材料对水和氧气的敏感性严重的阻碍了其实用化进程。在众多的稳定钙钛矿的方法中，利用简单的原子层沉积方法(Atomic layer deposition，ALD)在钙钛矿表面沉积一层保护层的技术具有极大的潜力。而ALD应用的困难在于，在常规的ALD过程中，做为氧源的H₂O和O₃对铅卤钙钛矿有着腐蚀作用。在本文，我们提出将双官能团的5-氨基戊酸(5-Aminovaleric acid，AVA)引入到CH₃NH₂PbBr₃ (MAPbBr₃)钙钛矿晶格层中，形成稳定的铰链结构的2D/3D钙钛矿AVA(MAPbBr₃)₂。AVA的引入可以钝化并防止ALD过程中水对钙钛矿的侵蚀，从而成功地直接在钙钛矿表面沉积了Al₂O₃保护层。覆盖了保护层的AVA(MAPbBr₃)₂钙钛矿薄膜获得了优异的热稳定性和抗水性。

关键词: 铅卤钙钛矿, 原子层沉积, 铰链2D/3D结构, 热稳定性, 抗水性

Abstract:

In recent years, hybrid lead halide perovskites have attracted significant research interest in the optoelectronic fields owing to their exceptional physical and chemical properties. However, their commercialization process is limited largely because of the sensitive nature of perovskite materials towards external stresses, such as heat, UV irradiance, oxygen, and moisture. Among various perovskite-stabilization methods, deposition of a protective layer over the vulnerable perovskite film via simple atomic layer deposition (ALD) technology is of great potential. However, the corrosive effect of H₂O or O₃ on perovskites, which is used as the oxygen source during ALD process, is one of the main obstacles in the application of regular ALD technology for coating compact and highly conformal layer directly onto the perovskite film. In this study, by introducing bifunctional 5-aminovaleric acid (AVA) crosslinking into the layers of CH₃NH₃PbBr₃ (MAPbBr₃) units, we propose a simple yet effective strategy to prevent the degradation of sensitive perovskite structure during the ALD process when H₂O is used as the oxygen source. The formed crosslinked 2D/3D structure of AVA(MAPbBr₃)₂ perovskite film was extremely dense and ultra-smooth compared to the coarse MAPbBr₃ film. With the passivation and protection of AVA, the AVA(MAPbBr₃)₂ perovskite film exhibited high moisture resistance, thereby leading to the successful deposition of dense and conformal Al₂O₃ protective layer onto the perovskite surface. The deposition of Al₂O₃ layer with different thicknesses had a negligible effect on the crystalline phase and morphology of AVA(MAPbBr₃)₂ film, as confirmed by X-ray diffraction, UV-Vis absorption spectroscopy, and scanning electron microscopy characterizations. The steady-state photoluminescence (PL) intensity and time-resolved PL lifetime of AVA(MAPbBr₃)₂ film was kept almost unchanged before and after the coating of Al₂O₃ layer, suggesting that the thin Al₂O₃ layer did not significantly alter the optical properties of the perovskite material, thereby enabling the potential usages in optical and optoelectronic devices. The thermal stability and water resistance ability of Al₂O₃-coated AVA(MAPbBr₃)₂ film was proven to have greatly improved in accelerated circumstances. No impurities or decomposition were detected for Al₂O₃-coated AVA(MAPbBr₃)₂ film after the long-time annealing at high temperature (150 ℃ for 2 h), whereas the crosslinked 2D/3D structure of bare MAPbBr₃ film quickly broke down at the elevated temperature. Intriguingly, the AVA(MAPbBr₃)₂ film with 15-nm-thick Al₂O₃ coating layer could endure strong water corrosion for at least 10 min when immersed in water. Overall, the proposed strategy could not only give a good reference for successfully depositing metal oxides onto the perovskite films with preservation of the materials' intrinsic properties, but also provide a method of introducing amino acid to passivate and protect the perovskite materials from H₂O corrosion during the ALD process. Therefore, the proposed work has practical potential in improving the device stability against various external stresses under different operating conditions, thereby paving way for various applicational advances.

Key words: Lead halide perovskite, Atomic layer deposition, Crosslinked 2D/3D structure, Thermal stability, Water resistance

王甜, 张太阳, 陈悦天, 赵一新. ALD-Al₂O₃涂层保护的高抗湿5-氨基戊酸铰链甲胺铅溴钙钛矿薄膜[J]. 物理化学学报, 2021, 37(4), 2007021. doi: 10.3866/PKU.WHXB202007021

Tian Wang, Taiyang Zhang, Yuetian Chen, Yixin Zhao. Highly Moisture Resistant 5-Aminovaleric Acid Crosslinked CH₃NH₃PbBr₃ Perovskite Film with ALD-Al₂O₃ Protection[J]. Acta Phys. -Chim. Sin. 2021, 37(4), 2007021. doi: 10.3866/PKU.WHXB202007021

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB202007021

https://www.whxb.pku.edu.cn/CN/Y2021/V37/I4/2007021

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参考文献 66

1	Jena A. K. ; Kulkarni A. ; Miyasaka T. Chem. Rev. 2019, 119, 3036. doi: 10.1021/acs.chemrev.8b00539
2	Quan L. N. ; Rand B. P. ; Friend R. H. ; Mhaisalkar S. G. ; Lee T. W. ; Sargent E. H. Chem. Rev. 2019, 119, 7444. doi: 10.1021/acs.chemrev.9b00107
3	Sutherland B. R. ; Sargent E. H. Nat. Photonics 2016, 10, 295. doi: 10.1038/Nphoton.2016.62
4	Fu Y. ; Zhu H. ; Chen J. ; Hautzinger M. P. ; Zhu X. Y. ; Jin S. Nat. Rev. Mater. 2019, 4, 169. doi: 10.1038/s41578-019-0080-9
5	Huang Y. ; Sun Q. D. ; Xu W. ; He Y. ; Yin W. J. Acta Phys. -Chim. Sin. 2017, 33, 1730.
	黄杨; 孙庆德; 徐文; 何垚; 尹万健. 物理化学学报, 2017, 33, 1730. doi: 10.3866/PKU.WHXB201705042
6	Xiao J. ; Zhang H. L. Acta Phys. -Chim. Sin. 2016, 32, 1894.
	肖娟; 张浩力. 物理化学学报, 2016, 32, 1894. doi: 10.3866/PKU.WHXB201605034
7	Jeon N. J. ; Noh J. H. ; Kim Y. C. ; Yang W. S. ; Ryu S. ; Seok S. I. Nat. Mater. 2014, 13, 897. doi: 10.1038/nmat4014
8	Malinkiewicz O. ; Yella A. ; Lee Y. H. ; Espallargas G. M. ; Grätzel M. ; Nazeeruddin M. K. ; Bolink H. J. Nat. Photonics 2014, 8, 128. doi: 10.1038/nphoton.2013.341
9	Xing G. ; Mathews N. ; Sun S. ; Lim S. S. ; Lam Y. M. ; Grätzel M. ; Mhaisalkar S. ; Sum T. C. Science 2013, 342, 344. doi: 10.1126/science.1243167
10	Tan Z. K. ; Moghaddam R. S. ; Lai M. L. ; Docampo P. ; Higler R. ; Deschler F. ; Price M. ; Sadhanala A. ; Pazos L. M. ; Credgington D. Nat. Nanotech. 2014, 9, 687. doi: 10.1038/nnano.2014.149
11	Hoye R. L. ; Chua M. R. ; Musselman K. P. ; Li G. ; Lai M. L. ; Tan Z. K. ; Greenham N. C. ; MacManus-Driscoll J. L. ; Friend R. H. ; Credgington D. Adv. Mater. 2015, 27, 1414. doi: 10.1002/adma.201405044
12	Yang W. S. ; Noh J. H. ; Jeon N. J. ; Kim Y. C. ; Ryu S. ; Seo J. ; Seok S. I. Science 2015, 348, 1234. doi: 10.1126/science.aaa9272
13	Wang X. ; Wang Y. ; Zhang T. ; Liu X. ; Zhao Y. Angew. Chem. Int. Ed. 2019, 132, 1485. doi: 10.1002/anie.201911518
14	Wang Y. ; Dar M. I. ; Ono L. K. ; Zhang T. ; Kan M. ; Li Y. ; Zhang L. ; Wang X. ; Yang Y. ; Gao X. ; et al Science 2019, 365, 591. doi: 10.1126/science.aav8680
15	Zhao Y. ; Zhu K. Chem. Soc. Rev. 2016, 45, 655. doi: 10.1039/c4cs00458b
16	Niu G. ; Guo X. ; Wang L. J. Mater. Chem. A 2015, 3, 8970. doi: 10.1039/c4ta04994b
17	Leijtens T. ; Eperon G. E. ; Pathak S. ; Abate A. ; Lee M. M. ; Snaith H. J. Nat. Commun. 2013, 4, 2885. doi: 10.1038/ncomms3885
18	Ge Y. ; Mu X. L. ; Lu Y. ; Sui M. L. Acta Phys. -Chim. Sin. 2020, 36, 1905039.
	葛杨; 牟许霖; 卢岳; 隋曼龄. 物理化学学报, 2020, 36, 1905039. doi: 10.3866/PKU.WHXB201905039
19	Yang J. ; Siempelkamp B. D. ; Liu D. ; Kelly T. L. ACS Nano 2015, 9, 1955. doi: 10.1021/nn506864k
20	Dualeh A. ; Tétreault N. ; Moehl T. ; Gao P. ; Nazeeruddin M. K. ; Grätzel M. Adv. Funct. Mater. 2014, 24, 3250. doi: 10.1002/adfm.201304022
21	Christians J. A. ; Miranda Herrera P. A. ; Kamat P. V. J. Am. Chem. Soc. 2015, 137, 1530. doi: 10.1021/ja511132a
22	Niu G. ; Li W. ; Meng F. ; Wang L. ; Dong H. ; Qiu Y. J. Mater. Chem. A 2014, 2, 705. doi: 10.1039/C3TA13606J
23	Kim I. S. ; Martinson A. B. F. J. Mater. Chem. A 2015, 3, 20092. doi: 10.1039/c5ta07186k
24	Tiep N. H. ; Ku Z. ; Fan H. J. Adv. Energy Mater. 2016, 6, 1501420. doi: 10.1002/aenm.201501420
25	Frost J. M. ; Butler K. T. ; Brivio F. ; Hendon C. H. ; van Schilfgaarde M. ; Walsh A. Nano Lett. 2014, 14, 2584. doi: 10.1021/nl500390f
26	Kato Y. ; Ono L. K. ; Lee M. V. ; Wang S. ; Raga S. R. ; Qi Y. Adv. Mater. Interfaces 2015, 2, 1500195. doi: 10.1002/admi.201500195
27	Kim A. ; Lee H. ; Kwon H. C. ; Jung H. S. ; Park N. G. ; Jeong S. ; Moon J. Nanoscale 2016, 8, 6308. doi: 10.1039/C5NR04585A
28	Clever H. L. ; Johnston F. J. J. Phys. Chem.Ref. Data 1980, 9, 751. doi: 10.1063/1.555628
29	Leijtens T. ; Eperon G. E. ; Noel N. K. ; Habisreutinger S. N. ; Petrozza A. ; Snaith H. J. Adv. Energy Mater. 2015, 5, 1500963. doi: 10.1002/aenm.201500963
30	Si H. ; Liao Q. ; Zhang Z. ; Li Y. ; Yang X. ; Zhang G. ; Kang Z. ; Zhang Y. Nano Energy 2016, 22, 223. doi: 10.1016/j.nanoen.2016.02.025
31	Choudhury D. ; Rajaraman G. ; Sarkar S. K. Nanoscale 2016, 8, 7459. doi: 10.1039/C5NR06974B
32	George S. M. Chem. Rev. 2010, 110, 111. doi: 10.1021/cr900056b
33	Dong X. ; Hu H. ; Lin B. ; Ding J. ; Yuan N. Chem. Commun 2014, 50, 14405. doi: 10.1039/c4cc04685d
34	Wang L. ; Travis J. J. ; Cavanagh A. S. ; Liu X. ; Koenig S. P. ; Huang P. Y. ; George S. M. ; Bunch J. S. Nano Lett. 2012, 12, 3706. doi: 10.1021/nl3014956
35	Prasittichai C. ; Hupp J. T. J. Phys. Chem. Lett. 2010, 1, 1611. doi: 10.1021/jz100361f
36	Antila L. J. ; Heikkilä M. J. ; Aumanen V. ; Kemell M. ; Myllyperkiö P. ; Leskelä M. ; Korppi-Tommola J. E. J. Phys. Chem. Lett. 2009, 1, 536. doi: 10.1021/jz9003075
37	Dong X. ; Fang X. ; Lv M. ; Lin B. ; Zhang S. ; Ding J. ; Yuan N. J. Mater. Chem. A 2015, 3, 5360. doi: 10.1039/c4ta06128d
38	Koushik D. ; Verhees W. J. H. ; Kuang Y. ; Veenstra S. ; Zhang D. ; Verheijen M. A. ; Creatore M. ; Schropp R. E. I. Energy Environ. Sci. 2017, 10, 91. doi: 10.1039/c6ee02687g
39	Kot M. ; Das C. ; Wang Z. ; Henkel K. ; Rouissi Z. ; Wojciechowski K. ; Snaith H. J. ; Schmeisser D. ChemSusChem 2016, 9, 3401. doi: 10.1002/cssc.201601186
40	Miikkulainen V. ; Leskelä M. ; Ritala M. ; Puurunen R. L. J. Appl. Phys. 2013, 113, 2. doi: 10.1063/1.4757907
41	Kim J. ; Kwon D. ; Chakrabarti K. ; Lee C. ; Oh K. ; Lee J. J. Appl. Phys. 2002, 92, 6739. doi: 10.1063/1.1515951
42	Higashi G. ; Fleming C. Appl. Phys. Lett. 1989, 55, 1963. doi: 10.1063/1.102337
43	Raiford J. A. ; Oyakhire S. T. ; Bent S. F. Energy Environ. Sci. 2020, 13, 1997. doi: 10.1039/d0ee00385a
44	Koushik D. ; Hazendonk L. ; Zardetto V. ; Vandalon V. ; Verheijen M. A. ; Kessels W. M. M. ; Creatore M. ACS Appl. Mater. Interfaces 2019, 11, 5526. doi: 10.1021/acsami.8b18307
45	Saliba M. ; Matsui T. ; Seo J. Y. ; Domanski K. ; Correa-Baena J. P. ; Nazeeruddin M. K. ; Zakeeruddin S. M. ; Tress W. ; Abate A. ; Hagfeldt A. Energy Environ. Sci. 2016, 9, 1989. doi: 10.1039/C5EE03874J
46	Smith I. C. ; Hoke E. T. ; Solis-Ibarra D. ; McGehee M. D. ; Karunadasa H. I. Angew. Chem. Int. Ed. 2014, 126, 11414. doi: 10.1002/anie.201406466
47	Li X. ; Dar M. I. ; Yi C. ; Luo J. ; Tschumi M. ; Zakeeruddin S. M. ; Nazeeruddin M. K. ; Han H. ; Grätzel M. Nat. Chem. 2015, 7, 703. doi: 10.1038/nchem.2324
48	Noh J. H. ; Im S. H. ; Heo J. H. ; Mandal T. N. ; Seok S. I. Nano Lett. 2013, 13, 1764. doi: 10.1021/nl400349b
49	Ball J. M. ; Lee M. M. ; Hey A. ; Snaith H. J. Energy Environ. Sci. 2013, 6, 1739. doi: 10.1039/C3EE40810H
50	Kulbak M. ; Cahen D. ; Hodes G. J. Phys. Chem. Lett. 2015, 6, 2452. doi: 10.1021/acs.jpclett.5b00968
51	Kulbak M. ; Gupta S. ; Kedem N. ; Levine I. ; Bendikov T. ; Hodes G. ; Cahen D. J. Phys. Chem. Lett. 2015, 7, 167. doi: 10.1021/acs.jpclett.5b02597
52	Koh T. M. ; Shanmugam V. ; Schlipf J. ; Oesinghaus L. ; Müller-Buschbaum P. ; Ramakrishnan N. ; Swamy V. ; Mathews N. ; Boix P. P. ; Mhaisalkar S. G. Adv. Mater. 2016, 28, 3653. doi: 10.1002/adma.201506141
53	Tsai H. ; Nie W. ; Blancon J. C. ; Stoumpos C. C. ; Asadpour R. ; Harutyunyan B. ; Neukirch A. J. ; Verduzco R. ; Crochet J. J. ; Tretiak S. Nature 2016, 536, 312. doi: 10.1038/nature18306
54	Dou L. W. ; A. B. ; Yu Y. ; Lai M. ; Kornienko N. ; Eaton S. W. ; Fu A. ; Bischak C. G. ; Ma J. ; Ding T. ; Ginsberg N. S. ; et al Science 2015, 349, 1518. doi: 10.1126/science.aac7660
55	Yao K. ; Wang X. ; Xu Y. X. ; Li F. Nano Energy 2015, 18, 165. doi: 10.1016/j.nanoen.2015.10.010
56	Zhao Y. ; Wei J. ; Li H. ; Yan Y. ; Zhou W. ; Yu D. ; Zhao Q. Nat. Commun. 2016, 7, 10228. doi: 10.1038/ncomms10228
57	Zhang T. ; Xie L. ; Chen L. ; Guo N. ; Li G. ; Tian Z. ; Mao B. ; Zhao Y. Adv. Funct. Mater. 2017, 27, 1603568. doi: 10.1002/adfm.201603568
58	Mei A. ; Li X. ; Liu L. F. ; Ku Z. L. ; Liu T. F. ; Rong Y. G. ; Xu M. ; Hu M. ; Chen J. Z. ; Yang Y. ; et al Science 2014, 345, 295. doi: 10.1126/science.1254763
59	Zhao Y. ; Zhu K. J. Am. Chem. Soc. 2014, 136, 12241. doi: 10.1021/ja5071398
60	Zhang T. ; Li G. ; Xu F. ; Wang Y. ; Guo N. ; Qian X. ; Zhao Y. Chem. Commun 2016, 52, 11080. doi: 10.1039/c6cc05794b
61	Yan J. ; Ke X. ; Chen Y. ; Zhang A. ; Zhang B. Appl. Surf. Sci. 2015, 351, 1191. doi: 10.1016/j.apsusc.2015.06.025
62	Murali B. ; Saidaminov M. I. ; Abdelhady A. L. ; Peng W. ; Liu J. ; Pan J. ; Bakr O. M. ; Mohammed O. F. J. Mater. Chem. C 2016, 4, 2545. doi: 10.1039/c6tc00610h
63	Heo J. H. ; Song D. H. ; Im S. H. Adv. Mater. 2014, 26, 8179. doi: 10.1002/adma.201403140
64	Li X. ; Dar M. I. ; Yi C. ; Luo J. ; Tschumi M. ; Zakeeruddin S. M. ; Nazeeruddin M. K. ; Han H. ; Grätzel M. Nat. Chem. 2015, 7, 703. doi: 10.1038/nchem.2324
65	Bi C. ; Shao Y. ; Yuan Y. ; Xiao Z. ; Wang C. ; Gao Y. ; Huang J. J. Mater. Chem. A 2014, 2, 18508. doi: 10.1039/c4ta04007d
66	Yu J. C. ; Kim D. W. ; Kim da B. ; Jung E. D. ; Park J. H. ; Lee A. Y. ; Lee B. R. ; Di Nuzzo D. ; Friend R. H. ; Song M. H. Adv Mater 2016, 28, 6906. doi: 10.1002/adma.201601105

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ALD-Al₂O₃涂层保护的高抗湿5-氨基戊酸铰链甲胺铅溴钙钛矿薄膜

Highly Moisture Resistant 5-Aminovaleric Acid Crosslinked CH₃NH₃PbBr₃ Perovskite Film with ALD-Al₂O₃ Protection

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