基于微生物作为智能模板的电催化剂制备与应用研究进展

doi:10.3866/PKU.WHXB202106003

物理化学学报 >> 2022, Vol. 38 >> Issue (6): 2106003.doi: 10.3866/PKU.WHXB202106003

所属专题：面向电化学储能与转化的表界面工程

基于微生物作为智能模板的电催化剂制备与应用研究进展

马明军¹, 冯志超¹, 张小委¹, 孙超越¹, 王海青¹^,*(), 周伟家¹, 刘宏¹^,²^,*()

¹ 济南大学前沿交叉科学研究院，山东省生物诊疗技术与装备协同创新中心，济南 250022
² 山东大学晶体材料国家重点实验室，济南 250100

收稿日期:2021-06-02 录用日期:2021-07-15 发布日期:2021-07-23
通讯作者: 王海青,刘宏 E-mail:ifc_wanghq@ujn.edu.cn;ifc_liuh@ujn.edu.cn
作者简介:王海青,1986年生。南京工业大学博士,清华大学化学系博士后。现工作于济南大学前沿交叉科学研究院,硕士生导师。研究方向为电催化剂微纳结构的可控制备以及催化析氢、二氧化碳还原等的性能研究。
刘宏,1964年1月生,2001年毕业于山东大学,获得博士学位。山东大学晶体材料国家重点实验室任教授,国家杰出青年基金获得者(2009)。研究方向为干细胞分化以及能源催化。
基金资助:
国家重点研究发展计划(2017YFB0405400);山东省自然科学基金(ZR2019BB025);济南市“高校20条”项目(2018GXRC031)

Progress in the Preparation and Application of Electrocatalysts Based on Microorganisms as Intelligent Templates

Mingjun Ma¹, Zhichao Feng¹, Xiaowei Zhang¹, Chaoyue Sun¹, Haiqing Wang¹^,*(), Weijia Zhou¹, Hong Liu¹^,²^,*()

¹ Collaborative Innovation Center of Technology and Equipment for Biological Diagnosis and Therapy in Universities of Shandong, Institute for Advanced Interdisciplinary Research (iAIR), University of Jinan, Ji'nan 250022, China
² State Key Laboratory of Crystal Materials, Shandong University, Ji'nan 250100, China

Received:2021-06-02 Accepted:2021-07-15 Published:2021-07-23
Contact: Haiqing Wang,Hong Liu E-mail:ifc_wanghq@ujn.edu.cn;ifc_liuh@ujn.edu.cn
About author:Hong Liu, Email: ifc_liuh@ujn.edu.cn (H.L.)
Haiqing Wang, Email: ifc_wanghq@ujn.edu.cn (H.W.)
Supported by:
the National Key Research and Development Program of China(2017YFB0405400);the Shandong Provincial Natural Science Foundation, China(ZR2019BB025);the Project of "20 items of University" of Jinan, China(2018GXRC031)

摘要/Abstract

摘要：

通过电催化实现可再生能源的存储与转化对于改善能源结构、保护生态环境、实现碳达峰和碳中和的国家战略具有重大意义。而开发低成本、高效的电催化剂成为全世界科学家共同面对的挑战。微生物在自然界中广泛存在，具有结构、组成和代谢丰富的特点，可以成为电催化剂的模板以及碳、磷、硫等非金属元素以及金属元素的来源，而且具有无毒、生产可重复性好、易于规模化等优点，已成为电催化剂制备的新趋势。对此，本文综述了微生物“智能”引导制备电催化剂的发展及在电催化析氢(HER)、电催化析氧(OER)、氧还原反应(ORR)、二氧化碳还原(CO₂RR)、锂电池(LBs)等领域的应用现状。希望有助于推动微生物代谢与催化剂微纳结构关系以及与催化反应的构效关系的深入理解，最后针对这类材料的问题挑战及其未来发展方向进行了探讨与展望。

关键词: 微生物, 电催化, 构效关系, 能量转换, 能量存储

Abstract:

The storage and conversion of renewable energy through electrocatalysis is of considerable significance for improving the energy structure, protecting the ecological environment, and achieving the national strategy of carbon peaking and carbon neutrality. The development of low-cost and high-efficiency electrocatalysts has become a major scientific challenge worldwide. Microorganisms are widely found in nature and are characterized by their rich structure, composition and metabolism. These properties facilitate their use as intelligent templates for electrocatalyst structures and as sources of non-metallic elements such as carbon, phosphorus, sulfur, as well as metallic elements. The use of microorganisms in electrocatalyst production has become a new trend owing to the advantages of non-toxicity, reproducible production, and ease of scaling up. Thus, this paper reviews the development of microbial "intelligence" guided preparation of electrocatalysts and their current applications in the fields of hydrogen evolution reactions, oxygen evolution reactions, oxygen reduction reactions, carbon dioxide reductions and lithium batteries. In order to achieve the function of "intelligent" guidance of microorganisms, four aspects need to be addressed: (1) the selection of suitable microbial species and the culture and activation conditions, which significantly helps in tailoring the microbial properties for specific applications; (2) the exploration of microbial species that can accumulate metal species from their living environment and thus produce metal nanoparticles, which will help obtain nanocomposites with desired properties; (3) the selection of compounds with good catalytic properties, high stability, and compatibility with microbial substrates; and (4) the development of highly controllable nanocatalysts through modern molecular biology and genetic engineering to regulate microbial life processes such as metabolic proliferation and apoptosis. With the resolution of these issues, we believe that the application of microbial intelligent templates guided electrocatalysts can be further extended to other electrocatalytic reactions such as ethanol oxidation reactions (EOR), nitrogen reduction reactions (NRR), and to other applications in fields such as electronics, sensing, imaging, and biomedicine. The goal of this review is to promote a deeper understanding of the correlations among microbial metabolism, catalyst micro-nano structures and structure-activity relationships. Furthermore, the challenges associated with such materials and the prospects for future development are discussed herein.

Key words: Microorganism, Electrocatalysis, Structure-activity relationship, Energy conversion, Energy storage

马明军, 冯志超, 张小委, 孙超越, 王海青, 周伟家, 刘宏. 基于微生物作为智能模板的电催化剂制备与应用研究进展[J]. 物理化学学报, 2022, 38(6), 2106003. doi: 10.3866/PKU.WHXB202106003

Mingjun Ma, Zhichao Feng, Xiaowei Zhang, Chaoyue Sun, Haiqing Wang, Weijia Zhou, Hong Liu. Progress in the Preparation and Application of Electrocatalysts Based on Microorganisms as Intelligent Templates[J]. Acta Phys. -Chim. Sin. 2022, 38(6), 2106003. doi: 10.3866/PKU.WHXB202106003

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB202106003

https://www.whxb.pku.edu.cn/CN/Y2022/V38/I6/2106003

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参考文献 104

1	Peng P. ; Zhou Z. ; Guo J. ; Xiang Z. ACS Energy Lett. 2017, 2 (6), 1308. doi: 10.1021/acsenergylett.7b00267
2	Xiao W. ; Lei W. ; Gong M. ; Xin H. L. ; Wang D. ACS Catal. 2018, 8 (4), 3237. doi: 10.1021/acscatal.7b04420
3	Grigoriev S. A. ; Mamat M. S. ; Dzhus K. A. ; Walker G. S. ; Millet P. Int. J. Hydrogen Energ. 2011, 36 (6), 4143. doi: 10.1016/j.ijhydene.2010.07.013
4	Bard A. J. J. Am. Chem. Soc. 2010, 132 (22), 7559. doi: 10.1021/ja101578m
5	Zhao S. ; Wang D. W. ; Amal R. ; Dai L. Adv. Mater. 2019, 31 (9), 1801526. doi: 10.1002/adma.201801526
6	Ma Y. ; Guan G. ; Hao X. ; Cao J. Renew. Sust. Energ. Rev. 2017, 75, 1101. doi: 10.1016/j.rser.2016.11.092
7	Li Y. ; Dong Z. ; Jiao L. Adv. Energy Mater. 2020, 10 (11), 1902104. doi: 10.1002/aenm.201902104
8	Logan S. R. ; Moss R. L. ; Kemball C. Trans. Faraday Soc. 1958, 54, 922. doi: 10.1039/TF9585400922
9	Alexander A. M. ; Hargreaves J. S. J. Chem. Soc. Rev. 2010, 39 (11), 4388. doi: 10.1039/B916787K
10	Min H. Microbiology Hangzhou: Zhejiang University Press, 2005.
	闵航. 微生物学, 杭州: 浙江大学, 2005.
11	Alberts B. ; Bray D. ; Hopkins K. ; Johnson A. ; Lewis J. ; Raff M. ; Roberts K. ; Walter P. Essential Cell Biology Shrewsbury: Garland Press, 1998.
12	Zhai Z. H. ; Wang X. Z. ; Ding M. X. Cell Biology Beijing: Higher Education Press, 2011.
	翟中和; 王喜忠; 丁明孝.细胞生物学. 细胞生物学, 北京: 高等教育出版社, 2011.
13	Anam M. B. ; Istiaq A. ; Kariya R. ; Kudo M. ; Ishtiyaq Ahmad S. A. ; Ito N. ; Okada S. ; Ohta K. Biochem. Biophys. Rep. 2021, 26, 100946. doi: 10.1016/j.bbrep.2021.100946
14	Wang Q. ; Yang J. ; Zhou X. ; Tang J. ; Zhong H. ; Jia M. ; Cui M. ; Jiang M. ; Wang H. J. Electrochem. Soc. 2019, 166 (4), A704. doi: 10.1149/2.0901904jes
15	Guo Z. ; Ren G. ; Jiang C. ; Lu X. ; Zhu Y. ; Jiang L. ; Dai L. Sci. Rep. 2015, 5 (1), 17064. doi: 10.1038/srep17064
16	Varman A. M. ; He L. ; You L. ; Hollinshead W. ; Tang Y. J. Microb. Cell Fact. 2014, 13 (1), 42. doi: 10.1186/1475-2859-13-42
17	Zhou W. J. ; Xiong T. L. ; Shi C. H. ; Zhou J. ; Zhou K. ; Zhu N. W. ; Li L. G. ; Tang Z. H. ; Chen S. W. Angew. Chem. Int. Edit. 2016, 55 (29), 8416. doi: 10.1002/anie.201602627
18	Markou G. ; Mitrogiannis D. ; Çelekli A. ; Bozkurt H. ; Georgakakis D. ; Chrysikopoulos C. V. Chem. Eng. J. 2015, 259, 806. doi: 10.1016/j.cej.2014.08.037
19	Zhang X. R. Acta Microbiol. Sin. 2011, (03), 12. doi: 10.3969/j.issn.1003-1634.2008.04.011
20	Heuer-Jungemann A. ; Feliu N. ; Bakaimi I. ; Hamaly M. ; Alkilany A. ; Chakraborty I. ; Masood A. ; Casula M. F. ; Kostopoulou A. ; Oh E. ; et al Chem. Rev. 2019, 119 (8), 4819. doi: 10.1021/acs.chemrev.8b00733
21	Gahlawat G. ; Choudhury A. R. RSC Adv. 2019, 9 (23), 12944. doi: 10.1039/C8RA10483B
22	Lee L. A. ; Nguyen H. G. ; Wang Q. Org. Biomol. Chem. 2011, 9 (18), 6189. doi: 10.1039/C1OB05700F
23	Heldal M. ; Norland S. ; Tumyr O. Appl. Environ. Microb. 1985, 50 (5), 1251. doi: 10.1128/aem.50.5.1251-1257.1985
24	Klaus-Joerger T. ; Joerger R. ; Olsson E. ; Granqvist C. G. Trends Biotechnol. 2001, 19 (1), 15. doi: 10.1016/S0167-7799(00)01514-6
25	Russo E. Nature 2003, 421 (6921), 456. doi: 10.1038/nj6921-456a
26	Faramarzi, M. A.; Sadighi, A. Adv. Colloid Interfaces 2013, 189–190, 1. doi: 10.1016/j.cis.2012.12.001
27	Trevors J. T. Ation. Leeuw. Int. J. G. 1997, 71 (3), 257. doi: 10.1023/A:1000175217677
28	Beveridge T. J. ; Murray R. G. J. Bacteriol. 1980, 141 (2), 876. doi: 10.1128/jb.141.2.876-887.1980
29	Srivastava S. K. ; Constanti M. J. Nanopart. Res. 2012, 14 (4), 831. doi: 10.1007/s11051-012-0831-7
30	Wang T. ; Zhu J. ; Wei Z. ; Yang H. ; Ma Z. ; Ma R. ; Zhou J. ; Yang Y. ; Peng L. ; Fei H. ; Lu B. ; Duan X. Nano Lett. 2019, 19 (7), 4384. doi: 10.1021/acs.nanolett.9b00996
31	Liu J. ; Zheng Y. ; Hong Z. ; Cai K. ; Zhao F. ; Han H. Sci. Adv. 2016, 2 (9), e1600858. doi: 10.1126/sciadv.1600858
32	Guo X. ; Qian C. ; Wan X. ; Zhang W. ; Zhu H. ; Zhang J. Nanoscale 2020, 12 (7), 4374. doi: 10.1039/c9nr10785a
33	Kalathil S. ; Katuri K. P. ; Alazmi A. S. ; Pedireddy S. ; Kornienko N. ; Costa P. M. F. J. ; Saikaly P. E. Chem. Mater. 2019, 31 (10), 3686. doi: 10.1021/acs.chemmater.9b00394
34	Singh P. ; Kim Y. J. ; Zhang D. ; Yang D. C. Trends Biotechnol. 2016, 34 (7), 588. doi: 10.1016/j.tibtech.2016.02.006
35	Li Q. ; Lin B. ; Zhang S. ; Deng C. J. Mater. Chem. A 2016, 4 (15), 5719. doi: 10.1039/C6TA01465H
36	Li J. ; Wang L. ; Li L. ; Lv C. ; Zatovsky I. V. ; Han W. ACS Appl. Mater. Inter. 2019, 11 (8), 8072. doi: 10.1021/acsami.8b21976
37	Li G. X. ; Yu J. Y. ; Jia J. ; Yang L. J. ; Zhao L. L ; Zhou W. J. ; Liu H. Adv. Funct. Mater. 2018, 28, 1801332. doi: 10.1002/adfm.201801332
38	Yu J. Y. ; Li G. X. ; Liu H. ; Zhao L. L ; Wang A.Z. ; Liu Z. ; Li H. D. ; Liu H. ; Hu Y. Y. ; Zhou W. J. Adv. Funct. Mater. 2019, 29, 1901154. doi: 10.1002/adfm.201901154
39	Li G. ; Wang J. ; Yu J. ; Liu H. ; Cao Q. ; Du J. ; Zhao L. ; Jia J. ; Liu H. ; Zhou W. Appl. Catal. B-Environ. 2020, 261, 118147. doi: 10.1016/j.apcatb.2019.118147
40	Li G. ; Yu J. ; Yu W. ; Yang L. ; Zhang X. ; Liu X. ; Liu H. ; Zhou W. Small 2020, 16, 2001980. doi: 10.1002/smll.202001980
41	Sharma A. ; Sharma S. ; Sharma K. ; Chetri S. P. K. ; Vashishtha A. ; Singh P. ; Kumar R. ; Rathi B. ; Agrawal V. J. Appl. Phycol. 2016, 28 (3), 1759. doi: 10.1007/s10811-015-0715-1
42	MubarakAli D. ; Gopinath V. Mater. Lett. 2012, 74, 8. doi: 10.1016/j.matlet.2012.01.026
43	Abboud Y. ; Saffaj T. ; Chagraoui A. ; El Bouari A. ; Brouzi K. ; Tanane O. ; Ihssane B. Appl. Nanosci. 2014, 4 (5), 571. doi: 10.1007/s13204-013-0233-x
44	Li D. ; Chang G. ; Zong L. ; Xue P. ; Wang Y. ; Xia Y. ; Lai C. ; Yang D. Energy Storage Mater. 2019, 17, 22. doi: 10.1016/j.ensm.2018.08.004
45	Chandrasekaran S. ; Sweetman M. J. ; Kant K. ; Skinner W. ; Losic D. ; Nann T. ; Voelcker N. H. Chem. Commun. 2014, 50 (72), 10441. doi: 10.1039/C4CC04470C
46	Cui J. ; Xi Y. ; Chen S. ; Li D. ; She X. ; Sun J. ; Han W. ; Yang D. ; Guo S. Adv. Funct. Mater. 2016, 26 (46), 8487. doi: 10.1002/adfm.201603933
47	Li Y. ; Liu X. ; Wang J. ; Li Y ; Chen X. ; Zhang P. Catalysts 2019, 9, 730. doi: 10.3390/catal9090730
48	Wen A. M. ; Steinmetz N. F. Chem. Soc. Rev. 2016, 45 (15), 4074. doi: 10.1039/C5CS00287G
49	Oh D. ; Qi J. ; Lu Y. C. ; Zhang Y. ; Shao-Horn Y. ; Belcher A. M. Nat. Commun. 2013, 4 (1), 2756. doi: 10.1038/ncomms3756
50	Oh D. ; Qi J. ; Han B. ; Zhang G. ; Carney T. J. ; Ohmura J. ; Zhang Y. ; Shao-Horn Y. ; Belcher A. M. Nano Lett. 2014, 14 (8), 4837. doi: 10.1021/nl502078m
51	Records W. C. ; Yoon Y. ; Ohmura J. F. ; Chanut N. ; Belcher A. M. Nano Energy 2019, 58, 167. doi: 10.1016/j.nanoen.2018.12.083
52	Yang C. ; Choi C. H. ; Lee C. S. ; Yi H. ACS Nano 2013, 7 (6), 5032. doi: 10.1021/nn4005582
53	Aljabali A. A. A. ; Sainsbury F. ; Lomonossoff G. P. ; Evans D. J. Small 2010, 6 (7), 818. doi: 10.1002/smll.200902135
54	Sicard C. ; Brayner R. ; Margueritat J. ; Hémadi M. ; Couté A. ; Yéprémian C. ; Djediat C. ; Aubard J. ; Fiévet F. ; Livage J. ; et al J. Mater. Chem 2010, 20 (42), 9342. doi: 10.1039/C0JM01735C
55	Niu S. ; Cai J. ; Wang G. Nano Res. 2021, 14 (6), 1985. doi: 10.1007/s12274-020-3249-z
56	Hua W. ; Sun H. H. ; Xu F. ; Wang J. G. Rare Met. 2020, 39 (4), 335. doi: 10.1007/s12598-020-01384-7
57	Wang J. ; Gao Y. ; Kong H. ; Kim J. ; Choi S. ; Ciucci F. ; Hao Y. ; Yang S. ; Shao Z. ; Lim J. Chem. Soc. Rev. 2020, 49 (24), 9154. doi: 10.1039/D0CS00575D
58	Shinozaki K. ; Zack J. W. ; Richards R. M. ; Pivovar B. S. J. Electrochem. Soc. 2015, 162 (10), F1144. doi: 10.1149/2.1071509jes
59	Wei L. ; Karahan H. E. ; Goh K. ; Jiang W. ; Yu D. ; Birer Ö. ; Jiang R. ; Chen Y. J. Mater. Chem. A 2015, 3 (14), 7210. doi: 10.1039/C5TA00966A
60	Zhang T. Q. ; Liu J. ; Huang L. B. ; Zhang X. D. ; Sun Y. G. ; Liu X. C. ; Bin D. S. ; Chen X. ; Cao A. M. ; Hu J. S. ; et al J. Am. Chem. Soc. 2017, 139 (32), 11248. doi: 10.1021/jacs.7b06123
61	Pan Y. ; Mauzeroll J. Joule 2020, 4 (4), 712. doi: 10.1016/j.joule.2020.03.015
62	Dau H. ; Limberg C. ; Reier T. ; Risch M. ; Roggan S. ; Strasser P. ChemCatChem 2010, 2 (7), 724. doi: 10.1002/cctc.201000126
63	Ma X. ; Zhang X. Y. ; Yang M. ; Xie J. Y. ; Lv R. Q. ; Chai Y. M. ; Dong B. Rare Met. 2021, 40 (5), 1048. doi: 10.1007/s12598-020-01704-x
64	Yang H. ; Gong L. ; Wang H. ; Dong C. ; Wang J. ; Qi K. ; Liu H. ; Guo X. ; Xia B. Y. Nat. Commun. 2020, 11 (1), 5075. doi: 10.1038/s41467-020-18891-x
65	Rho J. ; Lim S. Y. ; Hwang I. ; Yun J. ; Chung T. D. ChemCatChem 2018, 10 (1), 165. doi: 10.1002/cctc.201701111
66	Suh W. k. ; Ganesan P. ; Son B. ; Kim H. ; Shanmugam S. Int. J. Hydrogen Energ. 2016, 41 (30), 12983. doi: 10.1016/j.ijhydene.2016.04.090
67	Gómez-Marín A. ; Feliu J. ; Edson T. ACS Catal. 2018, 8 (9), 7931. doi: 10.1021/acscatal.8b01291
68	Ding R. ; Liu Y. ; Rui Z. ; Li J. ; Liu J. ; Zou Z. Nano Res. 2020, 13 (6), 1519. doi: 10.1007/s12274-020-2768-y
69	Wang Y. ; Wang D. ; Li Y. SmartMat 2021, 2 (1), 56. doi: 10.1002/smm2.1023
70	Liu X. ; Liu H. ; Chen C. ; Zou L. ; Li Y. ; Zhang Q. ; Yang B. ; Zou Z. ; Yang H. Nano Res. 2019, 12 (7), 1651. doi: 10.1007/s12274-019-2415-7
71	Chen H. ; Liang X. ; Liu Y. ; Ai X. ; Asefa T. ; Zou X. Adv. Mater. 2020, 32 (44), 2002435. doi: 10.1002/adma.202002435
72	Ma X. ; Lei Z. ; Feng W. ; Ye Y. ; Feng C. Carbon 2017, 123, 481. doi: 10.1016/j.carbon.2017.07.091
73	Ferrero G. A. ; Preuss K. ; Marinovic A. ; Jorge A. B. ; Mansor N. ; Brett D. J. L. ; Fuertes A. B. ; Sevilla M. ; Titirici M. M. ACS Nano 2016, 10 (6), 5922. doi: 10.1021/acsnano.6b01247
74	Ye Y. ; Duan W. ; Yi X. ; Lei Z. ; Li G. ; Feng C. J. Power Sources 2019, 435, 226770. doi: 10.1016/j.jpowsour.2019.226770
75	Stolarczyk J. K. ; Bhattacharyya S. ; Polavarapu L. ; Feldmann J. ACS Catal. 2018, 8 (4), 3602. doi: 10.1021/acscatal.8b00791
76	Corbin N. ; Zeng J. ; Williams K. ; Manthiram K. Nano Res. 2019, 12 (9), 2093. doi: 10.1007/s12274-019-2403-y
77	Yang C. H. ; Nosheen F. ; Zhang Z. C. Rare Met. 2021, 40 (6), 1412. doi: 10.1007/s12598-020-01600-4
78	Kuang M. ; Guan A. ; Gu Z. ; Han P. ; Qian L. ; Zheng G. Nano Res. 2019, 12 (9), 2324. doi: 10.1007/s12274-019-2396-6
79	Chen G. Z. ; Chen K. J. ; Fu J. W. ; Liu M. Rare Met. 2020, 39 (6), 607. doi: 10.1007/s12598-020-01416-2
80	Leitner W. Angew. Chem. Int. Edit. 1995, 34 (20), 2207. doi: 10.1002/anie.199522071
81	Benson E. E. ; Kubiak C. P. ; Sathrum A. J. ; Smieja J. M. Chem. Soc. Rev. 2009, 38 (1), 89. doi: 10.1039/B804323J
82	Wu J. ; Huang Y. ; Ye W. ; Li Y. Adv. Sci. 2017, 4 (11), 1700194. doi: 10.1002/advs.201700194
83	Song Y. K. ; Xie W. F. ; Shao M. F. Acta Phys. -Chim. Sin. 2022, 38, 2101028.
	宋雨珂; 谢文富; 邵明飞. 物理化学学报, 2022, 38, 2101028. doi: 10.3866/PKU.WHXB202101028
84	Hao L. D. ; Sun Z. Y. Acta Phys. -Chim. Sin. 2021, 37 (7), 2009033.
	郝磊端; 孙振宇. 物理化学学报, 2021, 37 (7), 2009033. doi: 10.3866/PKU.WHXB202009033
85	Li L. ; Zhang C. W. ; Chen G. Y. J. ; Zhu B. ; Chai C. ; Xu Q. H. ; Tan E. K. ; Zhu Q. ; Lim K. L. ; Yao S. Q. Nat. Commun. 2014, 5 (1), 3276. doi: 10.1038/ncomms4276
86	Marques Mota F. ; Nguyen D. L. T. ; Lee J. E. ; Piao H. ; Choy J. H. ; Hwang Y. J. ; Kim D. H. ACS Catal. 2018, 8 (5), 4364. doi: 10.1021/acscatal.8b00647
87	Bosque I. ; Bach T. ACS Catal. 2019, 9 (10), 9103. doi: 10.1021/acscatal.9b01039
88	Rosen J. ; Hutchings G. S. ; Lu Q. ; Rivera S. ; Zhou Y. ; Vlachos D. G. ; Jiao F. ACS Catal. 2015, 5 (7), 4293. doi: 10.1021/acscatal.5b00840
89	Pan Y. ; Paschoalino W. J. ; Bayram S. S. ; Blum A. S. ; Mauzeroll J. Nanoscale 2019, 11 (40), 18595. doi: 10.1039/C9NR04464G
90	Ai G. ; Dai Y. ; Mao W. ; Zhao H. ; Fu Y. ; Song X. ; En Y. ; Battaglia V. S. ; Srinivasan V. ; Liu G. Nano Lett. 2016, 16 (9), 5365. doi: 10.1021/acs.nanolett.6b01434
91	Wu M. ; Li Y. ; Liu X. ; Yang S. ; Ma J. ; Dou S. SmartMat 2021, 2 (1), 5. doi: 10.1002/smm2.1015
92	Xia L. ; Zhou Y. ; Ren J. ; Wu H. ; Lin D. ; Xie F. ; Jie W. ; Lam K. H. ; Xu C. ; Zheng Q. Energ. Fuel. 2018, 32 (9), 9997. doi: 10.1021/acs.energyfuels.8b01453
93	Su Y. F. ; Zhang Q. Y. ; Chen L. ; Bao L. Y. ; Lu Y. ; Chen S. ; Wu F. Acta Phys. -Chim. Sin. 2021, 37 (3), 2005062.
	苏岳锋; 张其雨; 陈来; 包丽颖; 卢赟; 陈实; 吴锋. 物理化学学报, 2021, 37 (3), 2005062. doi: 10.3866/PKU.WHXB202005062
94	Zhang S. D. ; Liu Y. ; Qi M. Y. ; Cao A. M. Acta Phys. -Chim. Sin. 2021, 37 (11), 2011007.
	张思东; 刘园; 祁慕尧; 曹安民. 物理化学学报, 2021, 37 (11), 2011007. doi: 10.3866/PKU.WHXB202011007
95	Hu G. ; Sun Z. ; Shi C. ; Fang R. ; Chen J. ; Hou P. ; Liu C. ; Cheng H. M. ; Li F. Adv. Mater. 2017, 29 (11), 1603835. doi: 10.1002/adma.201603835
96	Hao J. N. ; Huang Y. J. ; He C. ; Xu W. J. ; Yuan L. B. ; Shu D. ; Song X. N. ; Meng T. Sci. Rep. 2018, 8 (1), 562. doi: 10.1038/s41598-017-18895-6
97	Zhong Y. ; Xia X. ; Deng S. ; Xie D. ; Shen S. ; Zhang K. ; Guo W. ; Wang X. ; Tu J. Adv. Mater. 2018, 30 (46), 1805165. doi: 10.1002/adma.201805165
98	Gao S. ; Fan H. ; Zhang S. J. Mater. Chem. A 2014, 2 (43), 18263. doi: 10.1039/C4TA03558E
99	Zhang C. ; Shen L. ; Shen J. ; Liu F. ; Chen G. ; Tao R. ; Ma S. ; Peng Y. ; Lu Y. Adv. Mater. 2019, 31 (21), 1808338. doi: 10.1002/adma.201808338
100	Xie Y. ; Fang L. ; Cheng H. ; Hu C. ; Zhao H. ; Xu J. ; Fang J. ; Lu X. ; Zhang J. J. Mater. Chem. A 2016, 4 (40), 15612. doi: 10.1039/C6TA06164H
101	Zhou L. ; Fu P. ; Wang Y. ; Sun L. ; Yuan Y. J. Mater. Chem. A 2016, 4 (19), 7222. doi: 10.1039/C6TA01662F
102	Shen S. ; Zhou R. ; Li Y. ; Liu B. ; Pan G. ; Liu Q. ; Xiong Q. ; Wang X. ; Xia X. ; Tu J. Small Methods 2019, 3 (12), 1900596. doi: 10.1002/smtd.201900596
103	Wang X. ; Ai W. ; Li N. ; Yu T. ; Chen P. J. Mater. Chem. A 2015, 3 (24), 12873. doi: 10.1039/C5TA01987G
104	Wei L. ; Karahan H. E. ; Zhai S. ; Yuan Y. ; Qian Q. ; Goh K. ; Ng A. K. ; Chen Y. J. Energy Chem. 2016, 25 (2), 191. doi: 10.1016/j.jechem.2015.12.001

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Progress in the Preparation and Application of Electrocatalysts Based on Microorganisms as Intelligent Templates

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