S型异质结In2O3/ZnIn2S4光催化5-羟甲基糠醛选择性氧化耦合产氢

doi:10.1016/j.actphy.2025.100166

摘要/Abstract

摘要：

发展可持续的光催化技术，以实现生物质向高附加值化学品和清洁燃料的高效转化，是应对全球能源与环境危机有效途径。本研究通过原位生长法构建了一种新型一维/二维(1D/2D)In₂O₃/ZnIn₂S₄ S型异质结光催化剂。该设计巧妙结合棒状In₂O₃与片状ZnIn₂S₄，促进定向电荷传输并提供高密度活性位点。因此，优化后的In₂O₃/ZnIn₂S₄异质结在420 nm LED光照下对5-羟甲基糠醛(HMF)转化率达81.6%，且对2,5-二甲酰基呋喃(DFF)和2,5-呋喃二甲酸(FDCA)的选择性高达78.2%。同时，该异质结表现出257.69 μmol g⁻¹ h⁻¹的产氢(H₂)速率。这些结果表明，S型异质结能有效实现空间电荷分离并提升光催化活性，为太阳能驱动的生物质增值与可持续产氢提供了可行策略。

关键词: 光催化, S型异质结, 5-羟甲基糠醛氧化, 析氢, In₂O₃/ZnIn₂S₄

Abstract:

Addressing the global energy and environmental crisis necessitates the development of sustainable photocatalytic technologies capable of efficiently converting biomass into high-value chemicals and clean fuels. In this study, we develop a novel one-dimensional/two-dimensional (1D/2D) In₂O₃/ZnIn₂S₄ S-scheme heterojunction photocatalyst through in situ growth process. This rationally designed architecture combines rod-like In₂O₃ with sheet-like ZnIn₂S₄ nanosheets, facilitating directional charge transport and providing a high density of active sites. Consequently, the optimized In₂O₃/ZnIn₂S₄ heterojunction achieved a 5-hydroxymethylfurfural (HMF) conversion rate of 81.6% with a high selectivity of 78.2% toward 2,5-diformylfuran (DFF) and 2,5-furandicarboxylic acid (FDCA). Furthermore, it exhibited a hydrogen (H₂) evolution rate of 257.69 μmol g⁻¹ h⁻¹ under 420 nm LED irradiation. These results demonstrate the efficacy of S-scheme heterojunctions in enabling spatial charge separation and boosting photocatalytic activity, offering a promising strategy for solar-driven biomass valorization and sustainable H₂ production.

Key words: Photocatalysis, S-scheme heterojunction, 5-hydroxymethylfurfural oxidation, Hydrogen evolution, In₂O₃/ZnIn₂S₄

骆泽, 朱玉坤, 罗雅丹, 任广敏, 王永红, 唐华. S型异质结In₂O₃/ZnIn₂S₄光催化5-羟甲基糠醛选择性氧化耦合产氢[J]. 物理化学学报, 2026, 42(3), 100166. doi: 10.1016/j.actphy.2025.100166

Ze Luo, Yukun Zhu, Yadan Luo, Guangmin Ren, Yonghong Wang, Hua Tang. Photocatalytic selective oxidation of 5-hydroxymethylfurfural coupled with H₂ evolution over In₂O₃/ZnIn₂S₄ S-scheme heterojunction[J]. Acta Phys. -Chim. Sin. 2026, 42(3), 100166. doi: 10.1016/j.actphy.2025.100166

链接本文: https://www.whxb.pku.edu.cn/CN/10.1016/j.actphy.2025.100166

https://www.whxb.pku.edu.cn/CN/Y2026/V42/I3/100166

图/表 5

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S型异质结In₂O₃/ZnIn₂S₄光催化5-羟甲基糠醛选择性氧化耦合产氢

Photocatalytic selective oxidation of 5-hydroxymethylfurfural coupled with H₂ evolution over In₂O₃/ZnIn₂S₄ S-scheme heterojunction

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