噻二嗪衍生物的合成及Pb2+在水/1,2-二氯乙烷界面转移的电化学性质

doi:10.3866/PKU.WHXB20110801

Abstract

Abstract:

The transfer of Pb²⁺ facilitated by interfacial complexation with 5-(4-phenoxyphenyl)-6H-1,3,4-thiadiazin-2-amine (PPTA) at the polarized water/1,2-dicholoroethane (1,2-DCE) interface was investigated by cyclic voltammetry. We synthesized the thiadiazine derivative, PPTA, firstly. The transfer was performed at different metal concentrations and scan rates, and the obtained voltammetric transfer peaks toward Pb²⁺ ion over other divalent cations (Zn²⁺, Co²⁺, Ni²⁺, Cd²⁺, Hg²⁺, and Cu²⁺) were reversible. The dependence of the half-wave potentials of the Pb²⁺ ion on the concentration of PPTA in the organic phase indicates that the ion transfer is facilitated by the formation of 1:2 (metal:ligand) complex in the organic phase with the association constant (lgβ₂) of (17.1±0.2).

Key words: Pb²⁺, Thiadiazine, Cyclic voltammetry, Ion transfer, ITIES

BASLAK Canan, BINGOL Haluk, COSKUN Ahmet, ATALAY Tevfik. Synthesis of a Novel Thiadiazine Derivative and Electrochemical Properties for Pb²⁺ Transfer across Water/1,2-Dichloroethane Interface[J]. Acta Phys. -Chim. Sin. 2011, 27(08), 1859-1862. doi: 10.3866/PKU.WHXB20110801

References

(1) Ferreira, E. S.; Garau, A.; Lippolis, V.; Pereira, C. M.; Silva, F. J. Electroanal. Chem. 2006, 587, 155.
(2) Katano, H.; Kuboyama, H.; Senda, M. J. Electroanal. Chem. 2000, 483, 117.
(3) Bingol, H.; Akgemci, E. G.; Ersoz, M.; Atalay, T. Electroanalysis 2007, 19, 1327.
(4) Shaaban, M. R.; Fuchigami, T. Tetrahedron Lett. 2002, 43, 273.
(5) Zhang, M.; Sun, P.; Chen, Y.; Li, F.; Gao, Z.; Shao, Y. Chin. Sci. Bull. 2003, 48, 1234.
(6) Tomaszewski, L.; Reymond, F.; Brevet, P. F.; Girault, H. H. J. Electroanal. Chem. 2000, 483, 135.
(7) Kasumov, V. T.; K?ksal, F. Spectrochim. Acta Part A 2005, 61, 225.
(8) Hatay, I.; Su, B.; Li, F.; Partovi-Nia, R.; Vrubel, H.; Hu, X.; Ersoz, M.; Girault, H. H. Angew. Chem. Int. Edit. 2009, 48, 5139.
(9) Alemu, H. Pure Appl. Chem. 2004, 76, 697.
(10) Herzog, G.; McMahon, B.; Lefoix, M.; Mullins, N. D.; Collins, C. J.; Moynihan, H. A.; Arrigan, D.W. M. J. Electroanal. Chem. 2008, 622, 109.
(11) Gobry, V.; Ulmeanu, S.; Reymond, F.; Bouchard, G.; Carrupt, P. A.; Testa, B.; Girault, H. H. J. Am. Chem. Soc. 1998, 123, 10684.
(12) Koryta, J. Electrochim. Acta 1979, 24, 293.
(13) Shao, Y.; Stewart, A. A.; Girault, H. H. J. Chem. Soc. Faraday Trans. 1991, 87, 2593.
(14) Lagger, G.; Tomaszewski, L.; Osborne, M. D.; Seddon, B. J.; Girault, H. H. J. Electroanal. Chem. 1998, 451, 29.
(15) Prasad, A. R.; Ramalingam, T.; Rao, A.B.; Diwan, P. V.; Sattur, P. B. Eur. J. Med. Chem. 1989, 24, 199.
(16) Fotouhi, L.; Mosavi, M.; Heravia, M. M.; Nematollahi, D. Tetrahedron Lett. 2006, 47, 8553.
(17) Rodr?guez-Fernandez, E.; Manzano, J. L.; Benito, J. J.; Hermosa, R.; Monte, E.; Criado, J. J. J. Inorg. Biochem. 2005, 99, 1558.
(18) El-Daway, M. A.; Omar, A. M. M. E.; Ismail, A. M.; Hazzaa, A. A. B. J. Pharm. Sci. 1983, 72, 45.
(19) Witvrouw, M.; Arranz, M. E.; Pannecouque, C.; Declercq, R.; Jonckheere, H.; Schmit, J. C.; Vandamme, A. M.; Diaz, J. A.; Ingate, S. T.; Desmyter, J.; Esnouf, R.; Van Meervelt, L.; Vega, S.; Balzarini, J.; Clercq, D. Antimicrob. Agents Chemother. 1998, 42, 618.
(20) Mahajan, R. K.; Sood, P.; Mahajan, M. P.; Singh, P. Anal. Sci. 2004, 20, 1423.
(21) Adamo, M. A.; Adlington, R. M.; Baldwin J. E.; Day, A. L. Tetrahedron 2004, 60, 841.
(22) Akgemci, E. G.; Bingol, H.; Ersoz, M.; Stibor, I. Electroanalysis 2008, 20, 1354.
(23) Marecek, V.; Samec, Z. J. Electroanal. Chem. 1985, 185, 263.
(24) Koryta, J. Electrochim. Acta 1984, 29, 445.
(25) Yuan, Y.; Gao, Z.; Guo, J.; Shao, Y. J. Electroanal. Chem. 2002, 526, 85.
(26) Katano, H.; Senda, M. Anal. Sci. 1996, 12, 683.
(27) Tetko, V.; Gasteiger, J.; Todeschini, R.; Mauri, A.; Livingstone, D.; Ertl, P.; Palyulin, V. A.; Radchenko, E. V.; Zefirov, N. S.; Makarenko, A. S.; Tanchuk, V. Y.; Prokopenko, V. V. J. Comput. Aid. Mol. Des. 2005, 19, 453.
(28) Steyaert, G.; Lisa, G.; Gaillard, P.; Boss, G.; Reymond, F.; Girault, H. H.; Carrupt, P. A.; Testa, B. J. Chem. Soc. Faraday Trans. 1997, 93, 401.
(29) Shao, Y.; Osborne, M. D.; Girault, H. H. J. Electroanal. Chem. 1991, 318, 101.
(30) Cheng, Y.; Schiffrin, D. J. J. Electroanal. Chem. 1997, 429, 37.

[1]	Zhenfeng Pang,Hanxi Guan,Lina Gao,Weicheng Cao,Jinglin Yin,Xueqian Kong. Fundamentals and Applications of NMR Hyperpolarization Techniques [J]. Acta Physico-Chimica Sinica, 2020, 36(4): 1906018-.
[2]	Hong-Mei QU,Ze-Peng CHONG,Xu CHEN,Yi-Can MEN,Hai-Jiao SHEN. Synthesis and Properties of a Series of Dinaphthosiloles [J]. Acta Phys. -Chim. Sin., 2017, 33(6): 1253-1260.
[3]	Xiao-Ying. WU,Li-Kun. YANG,Hui. YAN,Fang-Zu. YANG,Zhong-Qun. TIAN,Shao-Min. ZHOU. Electrochemical Nucleation of Au on n-Type Semiconductor Silicon Electrode Surface [J]. Acta Phys. -Chim. Sin., 2015, 31(9): 1708-1714.
[4]	PENG Zhong, YAN Wen-Yi, WANG Shao-Na, ZHENG Shi-Li, DU Hao, ZHANG Yi. Effect of Alkali Concentration, Oxygen Partial Pressure and Temperature on Oxygen Reduction Reaction on Pt Electrode in NaOH Solution [J]. Acta Phys. -Chim. Sin., 2014, 30(1): 67-74.
[5]	SHI Ji-Peng, YANG Fang-Zu, TIAN Zhong-Qun, ZHOU Shao-Min. Electrocrystallization of Cu-Sn Alloy on Copper Electrode Surface [J]. Acta Phys. -Chim. Sin., 2013, 29(12): 2579-2584.
[6]	WEN Yue-Hua, GAO Chen, CHENG Jie, PAN Jun-Qing, CAO Gao-Ping, YANG Yu-Sheng. Effect of Electrolyte on the Performance of Electrodes for an All Lead Flow Battery [J]. Acta Phys. -Chim. Sin., 2013, 29(11): 2354-2360.
[7]	SONG Han, WANG Na-Na, LI Yue, RUAN Wen-Juan. Synthesis, Characterization and Properties of Terminal Alkynylate Modified Salen-Type Complexes [J]. Acta Phys. -Chim. Sin., 2013, 29(11): 2300-2307.
[8]	ZHANG Chao, AO Jian-Ping, WANG Li, JIANG Tao, SUN Guo-Zhong, HE Qing, ZHOU Zhi-Qiang, SUN Yun. Electrodepositied Gallium on Gallium and Copper/Indium Substratess [J]. Acta Phys. -Chim. Sin., 2012, 28(08): 1913-1922.
[9]	JIN Rong-Rong, LI Li-Fang, XU Xue-Feng, LIAN Ying-Hui, ZHAO Fan. Layered Double Hydroxide Supported Palladium Nanoparticles for Electrocatalytic Oxidation of Hydrazine [J]. Acta Phys. -Chim. Sin., 2012, 28(08): 1929-1935.
[10]	HUANG Pei-Pei, SUN He-Yun, FAN Jia-Ni, SUN Zhong-Xi. Acid-Base Properties and Adsorption Behaviors of Heavy Metal Ions at the Surface of γ-Al₂O₃/SiO₂ Nano-Mixed System [J]. Acta Phys. -Chim. Sin., 2012, 28(06): 1425-1431.
[11]	WANG Yan-Yan, JIANG Yan-Xia, SUSHAAndrei, ROGACH Andrey, SUN Shi-Gang. Effect of pH and Au Nanoparticles on Cytochrome c Investigated by Electrochemistry and UV-Vis Absorption Spectroscopy [J]. Acta Phys. -Chim. Sin., 2012, 28(05): 1127-1133.
[12]	YAN Bing-Xi, LUO Sheng-Yun, SHEN Jie. Photoelectric Properties of Mo Doped TiO₂ Thin Films Deposited by DC Reactive Magnetron Sputtering [J]. Acta Phys. -Chim. Sin., 2012, 28(02): 381-386.
[13]	TU Xiao-Hua, CHU You-Qun, MA Chun-An. Electrochemical Behavior of Nitroaromatics on Pt Microelectrode in an Aprotic Medium [J]. Acta Phys. -Chim. Sin., 2011, 27(09): 2148-2152.
[14]	YUE Jun-Pei, YANG Fang-Zu, TIAN Zhong-Qun, ZHOU Shao-Min. Electrocrystallization of Pd-Ni Alloys on Glassy Carbon Electrode [J]. Acta Phys. -Chim. Sin., 2011, 27(06): 1446-1450.
[15]	WANG Lian-Yan, LU Feng, WU Fu-Quan, GU Ren-Ao, YAO Jian-Lin, ZHANG Hai-Lu, DENG Zong-Wu. Electrosynthesis and Characterization of Metal Chelate Imprinted Poly-o-Phenylenediamine Films [J]. Acta Phys. -Chim. Sin., 2011, 27(06): 1451-1456.

Synthesis of a Novel Thiadiazine Derivative and Electrochemical Properties for Pb²⁺ Transfer across Water/1,2-Dichloroethane Interface

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0

Synthesis of a Novel Thiadiazine Derivative and Electrochemical Properties for Pb2+ Transfer across Water/1,2-Dichloroethane Interface

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0

Synthesis of a Novel Thiadiazine Derivative and Electrochemical Properties for Pb²⁺ Transfer across Water/1,2-Dichloroethane Interface