含末端炔基的Salen型金属配合物的合成、表征及性质

doi:10.3866/PKU.WHXB201310091

Abstract

Abstract:

We synthesized two terminal alkynyl modified Salen ligands, H₂Lⁿ, and their metal complexes, MLⁿ (n=1, 2, M=Ni, Cu, Mn). The ligands and complexes were characterized by ¹H nuclear magnetic resonance (¹H NMR) spectroscopy, electrospray ionization mass spectrometry (ESI-MS), elemental analysis, Fourier transform infrared (FT-IR) spectroscopy, and ultraviolet visible (UV-Vis) spectroscopy. The redox properties of the compounds were investigated with cyclic voltammetry (CV). Imine redox peaks appeared in the CV curves of all the ligands except H₂L¹. The Ni and Cu complexes underwent two single electron redox processes in the scanning range. Mn complexes gave a pair of quasi-reversible voltammetric peaks, which corresponded to the redox process between Mn(III)/Mn(II). Molar conductivity measurements of the complexes showed that they were all weak electrolytes with certain conductivity.

Key words: Salen-type complex, Terminal alkynyl, Synthesis and characterization, Spectrum property, Cyclic voltammetry

SONG Han, WANG Na-Na, LI Yue, RUAN Wen-Juan. Synthesis, Characterization and Properties of Terminal Alkynylate Modified Salen-Type Complexes[J]. Acta Phys. -Chim. Sin. 2013, 29(11), 2300-2307. doi: 10.3866/PKU.WHXB201310091

References

(1) (a) Nasr-Esfahani, M.; Moghadam, M.; Valipour, G. Synth. Commun. 2009, 39, 3867.
(b) Voronova, K.; Purgel, M.; Udvardy, A.; Bényei, A. C.;Kathó, Á.; Joó, F. Organometals 2013, 32 (15), 4391
(c) Cheng, J. H.;Wei, K. Y.; Ma, X. F.; Zhou, X. G.; Xiang, H.F. J. Phys. Chem. C 2013, 117 (32), 16552.
(2) Tong, J.; Zhang, Y.; Li, Z.; Xia, C. J. Mol. Catal. A: Chem.2006, 249, 47. doi: 10.1016/j.molcata.2005.12.031
(3) Salavati-Niasari, M.; Davar, F.; Bazarganipour, M. Dalton Trans. 2010, 39, 7330. doi: 10.1039/b923416k
(4) Lee, S. H.; Xu, L.; Park, B. K.; Mironov, Y. V.; Kim, S. H.;Song, Y. J.; Kim, C.; Kim, Y.; Kim, S. K. Chem. -Eur. J. 2010,16, 4678. doi: 10.1002/chem.v16:15
(5) Vagin, S. I.; Reichardt, R.; Klaus, S.; Rieger, B. J. Am. Chem. Soc. 2010, 132, 14367. doi: 10.1021/ja106484t
(6) Zintl, M.; Molnar, F.; Urban, T.; Bernhart, V.; Preishuber-Puegl,P.; Rieger, B. Angew. Chem. Int. Edit. 2008, 47, 3458
(7) Decortes, A.; Kleij, A.W. ChemCatChem 2011, 3, 831. doi: 10.1002/cctc.v3.5
(8) Boogaerts, I. I. F.; Nolan, S. P. J. Am. Chem. Soc. 2010, 132,8858. doi: 10.1021/ja103429q
(9) Escudero-Adan, E. C.; Benet-Buchholz, J.; Kleij, A.W.Chem. -Eur. J. 2009, 15, 4233. doi: 10.1002/chem.v15:17
(10) Shi, X. L.; Zang, N.; Zhang, Y.; Duan, R.; Liu, M.; Ruan,W. J.;Zhu, Z. Z. Acta Chim. Sin. 2008, 66 (8), 930. [史秀丽, 臧娜, 张炎, 段苒, 刘美, 阮文娟, 朱志昂. 化学学报, 2008,66 (8), 930.]
(11) Guo, L. Q.; Shi, X. L.; Ruan,W. J.; Zhang, X. H.; Zhu, Z. A.Acta Phys. -Chem. Sin. 2010, 26 (5), 1195. [郭莉芹, 史秀丽,阮文娟, 张晓红, 朱志昂. 物理化学学报, 2010, 26 (5), 1195.]doi: 10.3866/PKU.WHXB20100336
(12) Liu, J.; Guo, L. Q.; Zhang, X. X.; Ruan,W. J.; Zhu, Z. A. Acta Phys. -Chim. Sin. 2012, 28 (2), 265. [刘佳, 郭莉芹, 张晓红, 阮文娟, 朱志昂. 物理化学学报, 2012, 28 (2), 265.] doi: 10.3866/PKU.WHXB201111251
(13) Lavastre, O.; Illitchev, I.; Jegou, G.; Dixneuf, P. H. J. Am. Chem. Soc. 2002, 124, 5278. doi: 10.1021/ja025764o
(14) Nielsen, M.; Larsen, N. B.; Gothelf, K. V. Langmuir 2002, 18,2795. doi: 10.1021/la015715+
(15) Nielsen, M.; Thomsen, A. H.; Jensen, T. R.; Jakobsen, H. J.;Skibsted, J.; Gothelf, K. V. Eur. J. Org. Chem. 2005, 2, 342.
(16) MunÕz-Hernandez, M. A.; Keizer, T. S.; Parkin, S.; Patrick, B.;Atwood, D. A. Organometallics 2000, 19, 4416. doi: 10.1021/om000058m
(17) Chen, Z. M.;Wu, Y. Q.; Gu, D. D. Spectrochim. Acta A 2007, 68 (3), 918.
(18) Chen, Z. M.; Huang, F. X.;Wu, Y. Q. Inorg. Chem. Commun.2006, 9 (1), 21.
(19) Felicio, R. C.; Cavalheiro, E. T. G.; Dockal, E. R. Polyhedron2001, 20, 261. doi: 10.1016/S0277-5387(00)00620-3
(20) Tas, E.; Kilic, A.; Konak, N. Yilmaz, I. Polyhedron 2008, 27 (3),1024.
(21) Anthonysamy, A.; Balasubramanian, S.; Usha, G.; Velmurugan,D. Transition Met. Chem. 2008, 33, 681. doi: 10.1007/s11243-008-9096-5
(22) Wang, J. H. Synthesis, Characterization and Properties of Salen-Type Complexes. Master Dissertation, Nankai University,Tianjin, 2009. [王建辉. Salen型席夫碱配合物合成、表征及性质研究[M]. 天津: 南开大学, 2009.]
(23) Chang, J.; Shannon, E. D.;William, C. S. J. Electroanal. Chem.2008, 622, 15. doi: 10.1016/j.jelechem.2008.04.023
(24) Deepalatha, S.; Sambasiva, R. P.; Venkatesan, R. Spectrochim. Acta A 2006, 64 (4), 823.
(25) Durackova,´Z.; Mendiola, M. A.; Sevilla, M. T. Bioelectrochem. Bioenerg. 1999, 48 (1), 109.
(26) Eva, F.; Elena, L. T.; Antonia, M. M. Polyhedron 2000, 19,441. doi: 10.1016/S0277-5387(99)00383-6
(27) Prasad, R.; Veerabhadram, G.; Sastry, K. S. J. Indian Chem. Soc. 2000, 77, 410.
(28) Zanello, P.; Cinquantini, A. Transition Met. Chem. 1985, 10,370. doi: 10.1007/BF00618845
(29) Zanello, P. Transition Met. Chem. 1984, 9, 176. doi: 10.1007/BF00618611
(30) Zhu, Z. A.; Ruan,W. J. Modern Physics Chemistry, 4th ed.;Science Press: Beijing, 2008; pp 236-237. [朱志昂, 阮文娟.近代物理化学. 第四版(下册). 北京: 科学出版社, 2008:236-237.]

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Synthesis, Characterization and Properties of Terminal Alkynylate Modified Salen-Type Complexes

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