不同结构Cu2O多晶的合成及其对高氯酸铵热分解的催化作用

doi:10.3866/PKU.WHXB201401061

Abstract

Abstract:

Porous Cu₂O micro-spheres were synthesized without additives, using a homogeneous reactor. The effects of synthesis time and reactor rolling speed on the Cu₂O micro-spheres structure were investigated. Increasing the use of polyvinylpyrrolidone, the porous Cu₂O micro-spheres transformed into cubic twined crystals, and then into cubic-octahedral twined crystals. Cu₂O micro-crystals with different structures were used to catalyze the thermal decomposition of ammonium perchlorate (AP). The catalytic activity of porous Cu₂O micro-spheres was better than those of the cubic twined and cubic-octahedral twined crystals. The low temperature of AP decomposition decreased for 37.4 ℃ when catalyzed by the porous Cu₂O micro-spheres, and amount of AP decomposed at low temperature increased from 8.7% to 49.0%.

Key words: Cu₂O, Homogeneous reactor, Ammonium perchlorate, Thermal decomposition

LUO Xiao-Lin, YANG De-Suo, YUAN Chun-Lan, LUO Xu-Mei, CHEN Ya-Shao. Catalytic Performance of Polycrystalline Cu₂O with Different Structures on the Thermal Decomposition of Ammonium Perchlorate[J]. Acta Phys. -Chim. Sin. 2014, 30(3), 520-526. doi: 10.3866/PKU.WHXB201401061

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Catalytic Performance of Polycrystalline Cu₂O with Different Structures on the Thermal Decomposition of Ammonium Perchlorate

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Catalytic Performance of Polycrystalline Cu2O with Different Structures on the Thermal Decomposition of Ammonium Perchlorate

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Catalytic Performance of Polycrystalline Cu₂O with Different Structures on the Thermal Decomposition of Ammonium Perchlorate