离子液体的辐射效应研究进展

doi:10.3866/PKU.WHXB201406271

Abstract

Abstract:

Ionic liquids (ILs) are regarded as a new generation of green solvents in spent nuclear fuel reprocessing, because of their fascinating properties such as negligible vapor pressure, high thermal stability, and successful use in the extraction of metal ions. However, the full realization of their potential requires a comprehensive knowledge of radiation effects on ILs, as they would be exposed to high radiation dose during extraction of high-level radioactive nuclides. This review presents research on the radiation effects on ILs, including radiation effects on the structures and properties of ILs, pulse radiolysis and laser photolysis of ILs, identification of radiolytic products of ILs and their influence on the extraction of metal ions. Our vision for the further development of this field is also proposed.

Key words: Ionic liquid, Radiation effect, Extraction, Radiolytic product, Spent nuclear fuel reprocessing

WANG Shuo-Jue, AO Yin-Yong, ZHOU Han-Yang, YUAN Li-Yong, PENG Jing, ZHAI Mao-Lin. Research Progress in Radiation Effects on Ionic Liquids[J]. Acta Phys. -Chim. Sin. 2014, 30(9), 1597-1604. doi: 10.3866/PKU.WHXB201406271

References

(1) Herrmann,W. A.; Bohm, V. P.W. J. Organomet. Chem. 1999, 572 (1), 141. doi: 10.1016/S0022-328X(98)00941-3
(2) Le Boulaire, V.; Gree, R. Chem. Commun. 2000, No. 22, 2195.(3) Xiao, Y.; Malhotra, S. V. Tetrahedron Lett. 2004, 45 (45), 8339. doi: 10.1016/j.tetlet.2004.09.070
(4) Boxwell, C. J.; Dyson, P. J.; Ellis, D. J.;Welton, T. J. Am. Chem. Soc. 2002, 124 (32), 9334. doi: 10.1021/ja026361r
(5) Song, C. E.; Oh, C. R.; Roh, E. J.; Choo, D. J. Chem. Commun. 2000, No. 18, 1743.(6) Wasserscheid, P.;Waffenschmidt, H. J. Mol. Catal. A-Chem. 2000, 164 (1-2), 61. doi: 10.1016/S1381-1169(00)00259-4
(7) Wang, P.;Wenger, B.; Humphry-Baker, R.; Moser, J. E.; Teuscher, J.; Kantlehner,W.; Mezger, J.; Stoyanov, E. V.; Zakeeruddin, S. M.; Grätzel, M. J. Am. Chem. Soc. 2005, 127 (18), 6850. doi: 10.1021/ja042232u
(8) Wang, R.; Okajima, T.; Kitamura, F.; Ohsaka, T. Electroanal. 2004, 16 (1-2), 66.(9) Jiang, T. F.; Gu, Y. L.; Liang, B.; Li, J. B.; Shi, Y. P.; Ou, Q. Y. Anal. Chim. Acta 2003, 479 (2), 249. doi: 10.1016/S0003-2670(02)01537-4
(10) Zhang,W. Z.; He, L. J.; Gu, Y. L.; Liu, X.; Jiang, S. X. Anal. Lett. 2003, 36 (4), 827. doi: 10.1081/AL-120018802
(11) He, L. J.; Zhang,W. Z.; Zhao, L.; Liu, X.; Jiang, S. X. J. Chromatogr. A 2003, 1007 (1-2), 39. doi: 10.1016/S0021-9673(03)00987-7
(12) Dai, S.; Ju, Y. H.; Barnes, C. E. J. Chem. Soc.-Dalton Trans. 1999, No. 8, 1201.(13) Sengupta, A.; Mohapatra, P. K.; Iqbal, M.; Huskens, J.; Verboom,W. Dalton Trans. 2012, 41 (23), 6970. doi: 10.1039/c2dt12364a
(14) Papaiconomou, N.; Genand-Pinaz, S.; Leveque, J. M.; Guittonneau, S. Dalton Trans. 2013, 42 (6), 1979. doi: 10.1039/c2dt32631k
(15) Stepinski, D. C.; Jensen, M. P.; Dzielawa, J. A.; Dietz, M. L. Green Chem. 2005, 7 (3), 151. doi: 10.1039/b414756a
(16) Luo, H. M.; Dai, S.; Bonnesen, P. V.; Buchanan, A. C.; Holbrey, J. D.; Bridges, N. J.; Rogers, R. D. Anal. Chem. 2004, 76 (11), 3078. doi: 10.1021/ac049949k
(17) Visser, A. E.; Rogers, R. D. J. Solid State Chem. 2003, 171 (1-2), 109. doi: 10.1016/S0022-4596(02)00193-7
(18) Rao, C. J.; Venkatesan, K. A.; Tata, B. V. R.; Nagarajan, K.; Srinivasan, T. G.; Rao, P. R. V. Radiat. Phys. Chem. 2011, 80 (5), 643. doi: 10.1016/j.radphyschem.2011.01.012
(19) Bhatt, A. I.; May, I.; Volkovich, V. A.; Collison, D.; Helliwell, M.; Polovov, I. B.; Lewin, R. G. Inorg. Chem. 2005, 44 (14), 4934. doi: 10.1021/ic048199u
(20) Bhatt, A. I.; Duffy, N.W.; Collison, D.; May I.; Lewin, R. G. Inorg. Chem. 2006, 45 (4), 1677. doi: 10.1021/ic051750i
(21) Allen, D.; Baston, G.; Bradley, A. E.; Gorman, T.; Haile, A.; Hamblett, I.; Hatter, J. E.; Healey, M. J. F.; Hodgson, B.; Lewin, R.; Lovell, K. V.; Newton, B.; Pitner,W. R.; Rooney, D.W.; Sanders, D.; Seddon, K. R.; Sims, H. E.; Thied, R. C. Green Chem. 2002, 4 (2), 152. doi: 10.1039/b111042j
(22) Berthon, L.; Nikitenko, S. I.; Bisel, I.; Berthon, C.; Faucon, M.; Saucerotte, B.; Zorz, N.; Moisy, P. Dalton Trans. 2006, No. 21, 2526.(23) Bosse, E.; Berthon, L.; Zorz, N.; Monget, J.; Berthon, C.; Bisel, I.; Legand, S.; Moisy, P. Dalton Trans. 2008, No. 7, 924.(24) Le Rouzo, G.; Lamouroux, C.; Dauvois, V.; Dannoux, A.; Legand, S.; Durand, D.; Moisy, P.; Moutiers, G. Dalton Trans. 2009, No. 31, 6175.(25) Qi, M. Y.;Wu, G. Z.; Chen, S. M.; Liu, Y. D. Radiat. Res. 2007, 167 (5), 508. doi: 10.1667/RR0727.1
(26) Qi, M. Y.;Wu, G. Z.; Li, Q. M.; Luo, Y. S. Radiat. Phys. Chem. 2008, 77 (7), 877. doi: 10.1016/j.radphyschem.2007.12.007
(27) Huang,W.; Chen, S. M.; Liu, Y. S.; Fu, H. Y.;Wu, G. Z. Radiat. Phys. Chem. 2011, 80 (4), 573. doi: 10.1016/j.radphyschem.2010.12.012
(28) Huang,W.; Chen, S. M.; Fu, H. Y.;Wu, G. Z. Radiat. Res. 2010, 174 (5), 650. doi: 10.1667/RR2170.1
(29) Huang, L.; Huang,W.; Fu, H. Y.;Wu, G. Z.; Guo, Z. J.;Wu,W. S.; Chen, S. M. Chin. Sci. Bull. 2013, 58 (10), 1150. doi: 10.1007/s11434-012-5656-3
(30) Gao, S. Y.; Dou, H.; Ding, L. S.; Gong, P.; Luo, L.; Chen, D. Radiat. Prot. 2012, 32 (1), 21. [高思旖, 窦辉, 丁立生, 龚频, 罗亮, 陈达. 辐射防护, 2012, 32 (1), 21.] doi: 10.1088/0952-4746/32/1/N21
(31) Howett, S. E.; Joseph, J. M.; Noel, J. J.;Wren, J. C. J. Colloid Interface Sci. 2011, 361 (1), 338. doi: 10.1016/j.jcis.2011.05.034
(32) Cui, Z. P.;Wang, S. J.; Ao, Y. Y.; Peng, J.; Li, J. Q.; Zhai, M. L. Acta Phys. -Chim. Sin. 2013, 29 (3), 619. [崔振鹏, 王硕珏, 敖银勇, 彭静, 李久强, 翟茂林. 物化化学学报, 2013, 29 (3), 619.] doi: 10.3866/PKU.WHXB201212102
(33) Yuan, L. Y.; Peng, J.; Xu, L.; Zhai, M. L.; Li, J. Q.;Wei, G. S. Radiat. Phys. Chem. 2009, 78 (12), 1133. doi: 10.1016/j.radphyschem.2009.07.003
(34) Yuan, L. Y.; Peng, J.; Li, J. Q.; Zhai, M. L. Acta Phys. -Chim. Sin. 2010, 26 (4), 981. [袁立永, 彭静, 李久强, 翟茂林. 物化化学学报, 2010, 26 (4), 981.] doi: 10.3866/PKU.WHXB20100423
(35) Paul, A.; Mandal, P. K.; Samanta, A. Chem. Phys. Lett. 2005, 402 (4-6), 375. doi: 10.1016/j.cplett.2004.12.060
(36) Paul, A.; Mandal, P. K.; Samanta, A. J. Phys. Chem. B 2005, 109 (18), 9148. doi: 10.1021/jp0503967
(37) Yuan, L. Y.; Peng, J.; Zhai, M. L.; Li, J. Q.;Wei, G. S. Radiat. Phys. Chem. 2009, 78 (7-8), 737. doi: 10.1016/j.radphyschem.2009.03.064
(38) Shkrob, I. A.; Marin, T.W.; Chemerisov, S. D.; Hatcher, J. L.; Wishart, J. F. J. Phys. Chem. B 2011, 115 (14), 3889. doi: 10.1021/jp200305b
(39) Tarabek, P.; Liu, S. Y.; Haygarth, K.; Bartels, D. M. Radiat. Phys. Chem. 2009, 78 (3), 168. doi: 10.1016/j.radphyschem.2008.11.006
(40) Dhiman, S. B.; Goff, G. S.; Runde,W.; LaVerne, J. A. J. Phys. Chem. B 2013, 117 (22), 6782. doi: 10.1021/jp402502d
(41) Yuan, L. Y.; Peng, J.; Xu, L.; Zhai, M. L.; Li, J. Q.;Wei, G. S. Dalton Trans. 2008, No. 45, 6358.(42) Yuan, L. Y.; Peng, J.; Xu, L.; Zhai, M. L.; Li, J. Q.;Wei, G. S. J. Phys. Chem. B 2009, 113 (26), 8948. doi: 10.1021/jp9016079
(43) Yuan, L. Y.; Xu, C.; Peng, J.; Xu, L.; Zhai, M. L.; Li, J. Q.;Wei, G. S.; Shen, X. H. Dalton Trans. 2009, No. 38, 7873.(44) Sun, T. X.; Shen, X. H.; Chen, Q. D.; Ma, J. Y.; Zhang, S.; Huang, Y. Y. Radiat. Phys. Chem. 2013, 83, 74.(45) Ao, Y. Y.; Peng, J.; Yuan, L. Y.; Cui, Z. P.; Li, C.; Li, J. Q.; Zhai, M. L. Dalton Trans. 2013, 42 (12), 4299. doi: 10.1039/c2dt32418k
(46) Ao, Y. Y.; Zhou, H. Y.; Yuan,W. J.;Wang, S. J.; Peng, J.; Zhai, M. L.;Wang, J. Y.; Zhao, Z. Q.; Zhao, L.;Wei, Y. Z. Dalton Trans. 2014, 43 (14), 5580. doi: 10.1039/c3dt53297f
(47) Behar, D.; Gonzalez, C.; Neta, P. J. Phys. Chem. A 2001, 105 (32), 7607. doi: 10.1021/jp011405o
(48) Marcinek, A.; Zielonka, J.; Gebicki, J.; Gordon, C. M.; Dunkin, I. R. J. Phys. Chem. A 2001, 105 (40), 9305. doi: 10.1021/jp0117718
(49) Wishart, J. F.; Neta, P. J. Phys. Chem. B 2003, 107 (30), 7261. doi: 10.1021/jp027792z
(50) Rogers, R. D.; Seddon, K. R.;Wishart, J. F. Ionic Liquids III A: Fundamentals, Progress, Challenges, and Opportunities ; American Chemical Society:Washington, DC, 2005; pp 102-116.(51) Shkrob, I. A.; Chemerisov, S. D.;Wishart, J. F. J. Phys. Chem. B 2007, 111 (40), 11786. doi: 10.1021/jp073619x
(52) Shkrob, I. A.; Marin, T.W.; Chemerisov, S. D.;Wishart, J. F. J. Phys. Chem. B 2011, 115 (14), 3872. doi: 10.1021/jp2003062
(53) Shkrob, I. A.; Marin, T.W.; Chemerisov, S. D.;Wishart, J. F. J. Phys. Chem. B 2011, 115 (37), 10927. doi: 10.1021/jp206579j
(54) Shkrob, I. A.; Marin, T.W.; Luo, H.; Dai, S. J. Phys. Chem. B 2013, 117 (46), 14372. doi: 10.1021/jp4082432
(55) Shkrob, I. A.; Marin, T.W.; Hatcher, J. L.; Cook, A. R.; Szreder, T.;Wishart, J. F. J. Phys. Chem. B 2013, 117 (46), 14385. doi: 10.1021/jp408242b
(56) Shkrob, I. A.; Marin, T.W.; Bell, J. R.; Luo, H.; Dai, S. J. Phys. Chem. B 2013, 117 (46), 14400. doi: 10.1021/jp408253y
(57) Shkrob, I. A.; Marin, T.W. J. Phys. Chem. B 2013, 117 (47), 14797. doi: 10.1021/jp408252n
(58) Zhu, G. L.;Wu, G. Z.; Long, D.W.; Sha, M. L.; Yao, S. Nucl. Sci. Tech. 2007, 18 (1), 16. doi: 10.1016/S1001-8042(07)60011-6
(59) Grodkowski, J.; Neta, P. J. Phys. Chem. A 2002, 106 (39), 9030. doi: 10.1021/jp020806g
(60) Grodkowski, J.; Neta, P.;Wishart, J. F. J. Phys. Chem. A 2003, 107 (46), 9794. doi: 10.1021/jp035265p
(61) Wishart, J. F.; Lall-Ramnarine, S. I.; Raju, R.; Scumpia, A.; Bellevue, S.; Ragbir, R.; Engel, R. Radiat. Phys. Chem. 2005, 72 (2-3), 99. doi: 10.1016/j.radphyschem.2004.09.005
(62) Asano, A.; Yang, J. F.; Kondoh, T.; Norizawa, K.; Nagaishi, R.; Takahashi, K.; Yoshida, Y. Radiat. Phys. Chem. 2008, 77 (10-12), 1244. doi: 10.1016/j.radphyschem.2008.05.032
(63) Takahashi, K.; Sato, T.; Katsumura, Y.; Yang, J. F.; Kondoh, T.; Yoshida, Y.; Katoh, R. Radiat. Phys. Chem. 2008, 77 (10-12), 1239. doi: 10.1016/j.radphyschem.2008.05.042
(64) Zhu, G. L.; Xu, J. J.;Wu, G. Z.; Zhu, H. P.; Long, D.W.; Chen, S.; Yao, S. D. Int. J. Mol. Sci. 2006, 7 (12), 590. doi: 10.3390/i7120590
(65) Fu, H. Y.; Xing, Z. G.;Wu, G. Z.; Yao, S. D. Res. Chem. Intermediat. 2011, 37 (1), 79. doi: 10.1007/s11164-010-0226-2
(66) Shkrob, I. A.; Marin, T.W.; Chemerisov, S. D.; Hatcher, J.; Wishart, J. F. J. Phys. Chem. B 2012, 116 (30), 9043. doi: 10.1021/jp302151c
(67) Xu, C.; Yuan, L. Y.; Shen, X. H.; Zhai, M. L. Dalton Trans. 2010, 39 (16), 3897. doi: 10.1039/b925594j

[1]	Lei Wang, Panpan Zhang, Zhiyuan Guo, Jing Wang, Jie Ma, Zhi-yong Ji. Electrochemical lithium extraction by the faradaic materials: advances, challenges and enhancement approaches [J]. Acta Phys. -Chim. Sin., 2026, 42(1): 100127-.
[2]	Zeqiu Chen, Limiao Cai, Jie Guan, Zhanyang Li, Hao Wang, Yaoguang Guo, Xingtao Xu, Likun Pan. Advanced electrode materials in capacitive deionization for efficient lithium extraction [J]. Acta Phys. -Chim. Sin., 2025, 41(8): 100089-.
[3]	Guoze Yan, Bin Zuo, Shaoqing Liu, Tao Wang, Ruoyu Wang, Jinyang Bao, Zhongzhou Zhao, Feifei Chu, Zhengtong Li, Yamauchi Yusuke, Melhi Saad, Xingtao Xu. Opportunities and Challenges of Capacitive Deionization for Uranium Extraction from Seawater [J]. Acta Phys. -Chim. Sin., 2025, 41(4): 100032-.
[4]	Yameen Ahmed, Xiangxiang Feng, Yuanji Gao, Yang Ding, Caoyu Long, Mustafa Haider, Hengyue Li, Zhuan Li, Shicheng Huang, Makhsud I. Saidaminov, Junliang Yang. Interface Modification by Ionic Liquid for Efficient and Stable FAPbI₃ Perovskite Solar Cells [J]. Acta Phys. -Chim. Sin., 2024, 40(6): 2303057-.
[5]	Qiang Zhang, Yuanbiao Huang, Rong Cao. Imidazolium-Based Materials for CO₂ Electroreduction [J]. Acta Phys. -Chim. Sin., 2024, 40(4): 2306040-.
[6]	Huan Wang, Yunyan Wu, Yanfei Zhao, Zhimin Liu. Recent Progress on Ionic Liquid-Mediated CO₂ Conversion [J]. Acta Phys. -Chim. Sin., 2021, 37(5): 2010022-.
[7]	Wenqiong Chen, Yongji Guan, Jiao Zhang, Junjie Pei, Xiaoping Zhang, Youquan Deng. Atomistic Insight into Changes in the Vibrational Spectrum of Ionic Liquids under External Electric Field [J]. Acta Phys. -Chim. Sin., 2021, 37(10): 2001004-.
[8]	Zhiwei Wu, Weilu Ding, Yaqin Zhang, Yanlei Wang, Hongyan He. Interaction and Mechanism between Imidazolium Ionic Liquids and the Zwitterionic Amino Acid Tyr: a DFT Study [J]. Acta Phys. -Chim. Sin., 2021, 37(10): 2002021-.
[9]	Lu Liu, Yuping Xu, Xia Chen, Mei Hong, Jing Tong. Thermogravimetric Analysis of Enthalpy Variation of 1-Alkyl-3-methylimidazole Chloride [J]. Acta Physico-Chimica Sinica, 2020, 36(11): 2004014-.
[10]	Shurong Hui, Liwei Zhao, Qingshan Liu, Dayong Song. Basic Properties of [C₃mim][NTf₂]/DEC/[Li][NTf₂] Systems [J]. Acta Physico-Chimica Sinica, 2020, 36(11): 1910067-.
[11]	Yimin Hu, Jie Han, Rong Guo. Wormlike Micelle to Gel Transition Induced by Brij 30 in Ionic Liquid-Type Surfactant Aqueous Solution [J]. Acta Physico-Chimica Sinica, 2020, 36(10): 1909049-.
[12]	Kang YANG,Xiaorui SHUAI,Huachao YANG,Jianhua YAN,Kefa CEN. Electrochemical Performance of Activated Graphene Powder Supercapacitors Using a Room Temperature Ionic Liquid Electrolyte [J]. Acta Phys. -Chim. Sin., 2019, 35(7): 755-765.
[13]	Mingguang PAN,Yongsheng ZHAO,Xiaoqin ZENG,Jianxin ZOU. Moisture-Responsive Behavior in the Azophenolic Ionic Liquid Solution Accompanied by a Naked-Eye Color Change [J]. Acta Physico-Chimica Sinica, 2019, 35(6): 624-629.
[14]	Yanyan GONG,Haichun LIU,Duo ZHANG,Jing TONG. Thermodynamic Properties of the Ether-Based Functionalized Ionic Liquids [MOEMIm]Cl and [EOEMIm]Cl [J]. Acta Physico-Chimica Sinica, 2019, 35(11): 1224-1231.
[15]	Wenqiong CHEN,Yongji GUAN,Xiaoping ZHANG,Youquan DENG. Influence of External Electric Field on Vibrational Spectrum of Imidazolium-Based Ionic Liquids Probed by Molecular Dynamics Simulation [J]. Acta Phys. -Chim. Sin., 2018, 34(8): 912-919.

Research Progress in Radiation Effects on Ionic Liquids

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0