双牺牲模板法制备一维管状Pt-Mn3O4-C复合物及其优越的甲醇电催化氧化性能

doi:10.3866/PKU.WHXB201503241

Abstract

Abstract:

A new Pt-based electrocatalyst with one-dimensional tubular Mn₃O₄-C as the catalyst support was synthesized by a dual-sacrificial template strategy. The morphology, structure, and composition of the Pt-Mn₃O₄- C composite were characterized by transmission electron microscopy, X-ray diffraction, and energy dispersive X-ray spectroscopy, respectively. The electrochemical performance of Pt-Mn₃O₄-C was investigated by cyclic voltammetry. The results show that Pt nanoparticles with an average size of 1.8 nm are uniformly dispersed on tubular Mn₃O₄-C, and Pt-Mn₃O₄-C exhibits superior electrocatalytic activity and higher stability for methanol oxidation than the commercial E-TEK Pt/C catalyst (20% (w, mass fraction) Pt). The excellent performance of Pt-Mn₃O₄-C is attributed to the uniform dispersion of Pt nanoparticles on Mn₃O₄-C and the synergetic catalytic effect of Pt and Mn₃O₄.

Key words: Pt nanoparticle, Tubular Mn₃O₄-C, Electrocatalyst, Methanol electrooxidation

LI Li, HE Xiao-Li, QIN Tao, DAI Fu-Tao, ZHANG Xiao-Hua, CHEN Jin-Hua. Dual-Sacrificial Template Synthesis of One-Dimensional Tubular Pt-Mn₃O₄-C Composite with Excellent Electrocatalytic Performance for Methanol Oxidation[J]. Acta Phys. -Chim. Sin. 2015, 31(5), 927-932. doi: 10.3866/PKU.WHXB201503241

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Dual-Sacrificial Template Synthesis of One-Dimensional Tubular Pt-Mn₃O₄-C Composite with Excellent Electrocatalytic Performance for Methanol Oxidation

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Dual-Sacrificial Template Synthesis of One-Dimensional Tubular Pt-Mn3O4-C Composite with Excellent Electrocatalytic Performance for Methanol Oxidation

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Dual-Sacrificial Template Synthesis of One-Dimensional Tubular Pt-Mn₃O₄-C Composite with Excellent Electrocatalytic Performance for Methanol Oxidation