钙钛矿型复合氧化物CaVO3的制备及对氧还原反应的电催化性能

doi:10.3866/PKU.WHXB201510162

Abstract

Abstract:

The precursor powder of CaVO₃ was prepared by sol-gel method using vanadium pentoxide, calcium nitrate, citric acid, and oxalic acid as raw materials. The target product CaVO₃ was obtained by calcining the precursor powder in argon atmosphere at 1000 ℃. In order to determine the appropriate calcination temperature, thermal stability of the precursor powder was tested. The target product CaVO₃ was characterized by Fourier transform infrared (FTIR) spectrometry, thermogravimetry (TG), X-ray diffraction (XRD), and conductivity. In addition, the properties for oxygen reduction reaction (ORR) were also investigated, and the results showed that the electron transfer number of ORR on the modified electrode was 1.5-1.7, which indicating that ORR was a two-electron process.

Key words: Perovskite, Sol-gel method, Oxygen reduction reaction

Feng-Ying. CHEN,Li. XIAO,Cui-Xia. YANG,Lin. ZHUANG. Preparation and Electrocatalytic Properties of Perovskite Type Oxides CaVO₃ for Oxygen Reduction Reaction[J]. Acta Phys. -Chim. Sin. 2015, 31(12), 2310-2315. doi: 10.3866/PKU.WHXB201510162

References

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Preparation and Electrocatalytic Properties of Perovskite Type Oxides CaVO₃ for Oxygen Reduction Reaction

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Preparation and Electrocatalytic Properties of Perovskite Type Oxides CaVO₃ for Oxygen Reduction Reaction