石墨烯化聚合物:一种兼具电子和离子传输通道的三维富碳高分子能源材料

doi:10.3866/PKU.WHXB201607132

Abstract

Abstract:

Graphene and its derivatives have attracted increasing attention during the last decade as efficient materials for the storage and conversion of energy. In most cases, however, these graphene materials possess large numbers of structural defects such as cavities, heteroatoms and functional groups, making them quite different from the precisely-defined "single carbon layer of graphite" observed for graphene. These materials also differ considerably in terms of their electrochemical properties because of their variable structures, which are strongly influenced by the methods used during their preparation. Structural analyses have indicated that these materials consist of graphene subunits, which are interconnected by organic linkers with properties lying between those of graphene and polymers, which we have defined as "graphenal polymers". The thermal crosslinking reactions of porous polymer networks fabricated from small organic molecules using a bottom-up strategy also result in graphene-like subunits, which are covalently interconnected by polymeric fractions. These materials cover a series of transitional intermediates belonging to the "graphenal polymers" family, where polymers and graphene sit at opposite ends of family spectrum. Moreover, the special structures and properties of these materials make them ideal electrode materials for the storage and conversion of energy via electronic and ionic transport pathways, allowing for a deeper evaluation of the structure-property relationships of different electrode materials.

Key words: Graphenal polymer, Carbon-rich polymer, Energy material, Electrochemistry, Energy storage and conversion

Jia-Xu LIANG,Zhi-Chang XIAO,Lin-Jie ZHI. Graphenal Polymers: 3D Carbon-Rich Polymers as Energy Materials with Electronic and Ionic Transport Pathways[J].Acta Phys. -Chim. Sin., 2016, 32(10): 2390-2398.

References

1	Winter M. ; Brodd R. J Chem. Rev. 2004, 104, 4245.
2	Bonaccorso F. ; Colombo L. ; Yu G. ; Stoller M. ; Tozzini V. ; Ferrari A. C. ; Ruoff R. S. ; Pellegrini V Science 2015, 347, 41.
3	Luo B. ; Zhi L Energy Environ. Sci. 2015, 8, 456.
4	Ambrosi A. ; Chua C. K. ; Bonanni A. ; Pumera M Chem. Rev. 2014, 114, 7150.
5	Liang M. ; Zhi L J. Mater. Chem. 2009, 19, 5871.
6	Liang M. ; Luo B. ; Zhi L Int. J. Energy Res. 2009, 33, 1161.
7	Li X. ; Song Q. ; Hao L. ; Zhi L Small 2014, 10, 2122.
8	Zhu Y. ; Murali S. ; Stoller M. D. ; Ganesh K. J. ; Ruoff R. S Science 2011, 332, 1537.
9	Xu Y. ; Lin Z. ; Zhong X. ; Huang X. ; Weiss N. O. ; Huang Y. ; Duan X Nat. Commun. 2014, 5, 4554.
10	Fan Z. ; Yan J. ; Zhi L. ; Zhang Q. ; Wei T. ; Feng J. ; Zhang M. ; Qian W. ; Wei F Adv. Mater. 2010, 22, 3723.
11	Fang Y. ; Luo B. ; Jia Y. ; Li X. ; Wang B. ; Song Q. ; Kang F. ; Zhi L Adv. Mater. 2012, 24, 6348.
12	Liang M. ; Wang J. ; Luo B. ; Qiu T. ; Zhi L Small 2012, 8, 1180.
13	Wang B. ; Li X. ; Zhang X. ; Luo B. ; Jin M. ; Liang M. ; Dayeh S. A. ; Picraux S. T. ; Zhi L ACS Nano 2013, 7, 1437.
14	Luo B. ; Wang B. ; Li X. ; Jia Y. ; Liang M. ; Zhi L Adv. Mater. 2012, 24, 3538.
15	Luo B. ; Wang B. ; Liang M. ; Ning J. ; Li X. ; Zhi L Adv. Mater. 2012, 24, 1405.
16	Wang J. ; Liang M. ; Fang Y. ; Qiu T. ; Zhang J. ; Zhi L Adv. Mater. 2012, 24, 2874.
17	Kong D. ; He H. ; Song Q. ; Wang B. ; Lv W. ; Yang Q. H. ; Zhi L Energy Environ. Sci. 2014, 7, 3320.
18	Luo B. ; Fang Y. ; Wang B. ; Zhou J. ; Song H. ; Zhi L Energy Environ. Sci. 2012, 5, 5226.
19	Zhou M. ; Li X. ; Wang B. ; Zhang Y. ; Ning J. ; Xiao Z. ; Zhang X. ; Chang Y. ; Zhi L Nano Lett. 2015, 15, 6222.
20	Wang B. ; Li X. ; Luo B. ; Yang J. ; Wang X. ; Song Q. ; Chen S. ; Zhi L Small 2013, 9, 2399.
21	Zhi L. ; Muellen K J. Mater. Chem. 2008, 18, 1472.
22	Zhi L. ; Wu J. ; Li J. ; Stepputat M. ; Kolb U. ; Müllen K Adv. Mater. 2005, 17, 1492.
23	Zhi L. J. ; Gorelik T. ; Friedlein R. ; Wu J. S. ; Kolb U. ; Salaneck W. R. ; Mullen K Small 2005, 1, 798.
24	Zhi L. J. ; Wu J. S. ; Li J. X. ; Kolb U. ; Mullen K Angew. Chem. Int. Ed. 2005, 44, 2120.
25	Cui G. ; Zhi L. ; Thomas A. ; Kolb U. ; Lieberwirth I. ; Muellen K Angew. Chem. Int. Ed. 2007, 46, 3464.
26	Wu D. ; Zhi L. ; Bodwell G. J. ; Cui G. ; Tsao N. ; Muellen K Angew. Chem. Int. Ed. 2007, 46, 5417.
27	Zhi L. ; Wang J. ; Cui G. ; Kastler M. ; Schmaltz B. ; Kolb U. ; Jonas U. ; Muellen K Adv. Mater. 2007, 19, 1849.
28	Liu R. ; Wu D. ; Feng X. ; Mullen K Angew. Chem. Int. Ed. 2010, 49, 2565.
29	Yang S. ; Feng X. ; Zhi L. ; Cao Q. ; Maier J. ; Muellen K Adv. Mater. 2010, 22, 838.
30	Feng X. ; Liang Y. ; Zhi L. ; Thomas A. ; Wu D. ; Lieberwirth I. ; Kolb U. ; Muellen K Adv. Funct. Mater. 2009, 19, 2125.
31	Liang Y. ; Feng X. ; Zhi L. ; Kolb U. ; Muellen K Chem. Commun. 2009, 809
32	Vilela F. ; Zhang K. ; Antonietti M Energy Environ. Sci. 2012, 5, 7819.
33	Song Q. ; Jia Y. ; Luo B. ; He H. ; Zhi L Small 2013, 9, 2460.
34	Zhuang X. ; Gehrig D. ; Forler N. ; Liang H. ; Wagner M. ; Hansen M. R. ; Laquai F. ; Zhang F. ; Feng X Adv. Mater. 2015, 27, 3789.
35	Xu C. ; Hedin N Mater. Today 2014, 17, 397.
36	Jiang J. X. ; Su F. ; Trewin A. ; Wood C. D. ; Campbell N. L. ; Niu H. ; Dickinson C. ; Ganin A. Y. ; Rosseinsky M. J. ; Khimyak Y. Z. ; Cooper A. I Angew. Chem. Int. Ed. 2007, 46, 8574.
37	Wood C. D. ; Tan B. ; Trewin A. ; Niu H. ; Bradshaw D. ; Rosseinsky M. J. ; Khimyak Y. Z. ; Campbell N. L. ; Kirk R. ; Stockel E. ; Cooper A. I Chem. Mater. 2007, 19, 2034.
38	Wood C. D. ; Tan B. ; Trewin A. ; Su F. ; Rosseinsky M. J. ; Bradshaw D. ; Sun Y. ; Zhou L. ; Cooper A. I Adv. Mater. 2008, 20, 1916.
39	Chen L. ; Honsho Y. ; Seki S. ; Jiang D J. Am. Chem. Soc. 2010, 132, 6742.
40	Li B. ; Guan Z. ; Yang X. ; Wang W. D. ; Wang W. ; Hussain I. ; Song K. ; Tan B. ; Li T J. Mater. Chem. A 2014, 2, 11930.
41	Luo Y. ; Li B. ; Wang W. ; Wu K. ; Tan B Adv. Mater. 2012, 24, 5703.
42	Kuhn P. ; Antonietti M. ; Thomas A Angew. Chem. Int. Ed. 2008, 47, 3450.
43	Kou Y. ; Xu Y. ; Guo Z. ; Jiang D Angew. Chem. Int. Ed. 2011, 50, 8753.
44	Chen Y. Z. ; Wang C. ; Wu Z. Y. ; Xiong Y. ; Xu Q. ; Yu S. H. ; Jiang H. L Adv. Mater. 2015, 27, 5010.
45	Sakaushi K. ; Antonietti M Accounts Chem. Res. 2015, 48, 1591.
46	Kuhn P. ; Forget A. ; Su D. ; Thomas A. ; Antonietti M J. Am. Chem. Soc. 2008, 130, 13333.
47	Hao L. ; Luo B. ; Li X. ; Jin M. ; Fang Y. ; Tang Z. ; Jia Y. ; Liang M. ; Thomas A. ; Yang J. ; Zhi L Energy Environ. Sci. 2012, 5, 9747.
48	Zhu X. ; Tian C. ; Mahurin S. M. ; Chai S. H. ; Wang C. ; Brown S. ; Veith G. M. ; Luo H. ; Liu H. ; Dai S J. Am. Chem. Soc. 2012, 134, 10478.
49	Su Y. ; Liu Y. ; Liu P. ; Wu D. ; Zhuang X. ; Zhang F. ; Feng X Angew. Chem. Int. Ed. 2015, 54, 1812.
50	Hao L. ; Ning J. ; Luo B. ; Wang B. ; Zhang Y. ; Tang Z. ; Yang J. ; Thomas A. ; Zhi L J. Am. Chem. Soc. 2015, 137, 219.

[1]	Ruifang Wei, Dongfeng Li, Heng Yin, Xiuli Wang, Can Li. Operando Electrochemical UV-Vis Absorption Spectroscopy with Microsecond Time Resolution [J]. Acta Phys. -Chim. Sin., 2023, 39(2): 2207035-0.
[2]	Tong Xu, Benyuan Ma, Jie Liang, Luchao Yue, Qian Liu, Tingshuai Li, Haitao Zhao, Yonglan Luo, Siyu Lu, Xuping Sun. Recent Progress in Metal-Free Electrocatalysts toward Ambient N₂ Reduction Reaction [J]. Acta Phys. -Chim. Sin., 2021, 37(7): 2009043-.
[3]	Qi Yuan, Hao Yang, Miao Xie, Tao Cheng. Theoretical Research on the Electroreduction of Carbon Dioxide [J]. Acta Phys. -Chim. Sin., 2021, 37(5): 2010040-.
[4]	Piao Jin, Zichao Guan, Yan Liang, Kai Tan, Xia Wang, Guangling Song, Ronggui Du. Photocathodic Protection on Stainless Steel by Heterostructured NiO/TiO₂ Nanotube Array Film with Charge Storage Capability [J]. Acta Phys. -Chim. Sin., 2021, 37(3): 1906033-.
[5]	Cheng Chang, Wei Chen, Ye Chen, Yonghua Chen, Yu Chen, Feng Ding, Chunhai Fan, Hong Jin Fan, Zhanxi Fan, Cheng Gong, Yongji Gong, Qiyuan He, Xun Hong, Sheng Hu, Weida Hu, Wei Huang, Yuan Huang, Wei Ji, Dehui Li, Lain-Jong Li, Qiang Li, Li Lin, Chongyi Ling, Minghua Liu, Nan Liu, Zhuang Liu, Kian Ping Loh, Jianmin Ma, Feng Miao, Hailin Peng, Mingfei Shao, Li Song, Shao Su, Shuo Sun, Chaoliang Tan, Zhiyong Tang, Dingsheng Wang, Huan Wang, Jinlan Wang, Xin Wang, Xinran Wang, Andrew T. S. Wee, Zhongming Wei, Yuen Wu, Zhong-Shuai Wu, Jie Xiong, Qihua Xiong, Weigao Xu, Peng Yin, Haibo Zeng, Zhiyuan Zeng, Tianyou Zhai, Han Zhang, Hui Zhang, Qichun Zhang, Tierui Zhang, Xiang Zhang, Li-Dong Zhao, Meiting Zhao, Weijie Zhao, Yunxuan Zhao, Kai-Ge Zhou, Xing Zhou, Yu Zhou, Hongwei Zhu, Hua Zhang, Zhongfan Liu. Recent Progress on Two-Dimensional Materials [J]. Acta Phys. -Chim. Sin., 2021, 37(12): 2108017-.
[6]	Peng Zhou,Jinzhi Sheng,Chongwei Gao,Jun Dong,Qinyou An,Liqiang Mai. Synthesis of V₂O₅/Fe₂V₄O₁₃ Nanocomposite Materials using In situ Phase Separation and the Electrochemical Performance for Sodium Storage [J]. Acta Physico-Chimica Sinica, 2020, 36(5): 1906046-.
[7]	Chunhe YANG,Aiwei TANG,Feng TENG,Kejian JIANG. Electrochemistry of Perovskite CH₃NH₃PbI₃ Crystals [J]. Acta Phys. -Chim. Sin., 2018, 34(11): 1197-1201.
[8]	Yi-Fan RUAN,Nan ZHANG,Yuan-Cheng ZHU,Wei-Wei ZHAO,Jing-Juan XU,Hong-Yuan CHEN. New Developments in Photoelectrochemical Bioanalysis [J]. Acta Phys. -Chim. Sin., 2017, 33(3): 476-485.
[9]	Wei-Xin SONG,Hong-Shuai HOU,Xiao-Bo JI. Progress in the Investigation and Application of Na₃V₂(PO₄)₃ for Electrochemical Energy Storage [J]. Acta Phys. -Chim. Sin., 2017, 33(1): 103-129.
[10]	Lin LIU,Zhi-Sheng LI,Hui-Dong HU,Wei-Li SONG. Insight into Macroscopic Metal-Assisted Chemical Etching for Silicon Nanowires [J]. Acta Phys. -Chim. Sin., 2016, 32(4): 1019-1028.
[11]	Jing-Mei LÜ,Xuan CHENG. Electrochemical Behavior of Porous and Flat Silicon Electrode Interfaces [J]. Acta Phys. -Chim. Sin., 2016, 32(3): 711-716.
[12]	Juan XU,Jia-Qin LIU,Jing-Wei LI,Yan WANG,Jun Lü,Yu-Cheng WU. Controlled Synthesis and Supercapacitive Performance of Heterostructured MnO₂/H-TiO₂ Nanotube Arrays [J]. Acta Phys. -Chim. Sin., 2016, 32(10): 2545-2554.
[13]	Qing-Gong ZHU,Xiao-Fu SUN,Xin-Chen KANG,Jun MA,Qing-Li QIAN,Bu-Xing HAN. Cu₂S on Cu Foam as Highly Efficient Electrocatalyst for Reduction of CO₂ to Formic Acid [J]. Acta Phys. -Chim. Sin., 2016, 32(1): 261-266.
[14]	XU Zhen, CHEN Yu, ZHANG Zhao, ZHANG Jian-Qing. Progress of Research on Underpotential Deposition—— I. Theory of Underpotential Deposition [J]. Acta Phys. -Chim. Sin., 2015, 31(7): 1219-1230.
[15]	LI Wen-You, HE Yun-Qiu, LI Yi-Ming. Photoelectric Properties of Graphene Oxide Film Prepared with the Electrochemical Method Using Varying Levels of Reduction [J]. Acta Phys. -Chim. Sin., 2015, 31(3): 457-466.

Graphenal Polymers: 3D Carbon-Rich Polymers as Energy Materials with Electronic and Ionic Transport Pathways

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0