AlN-Fe纳米复合薄膜:一种新型锂离子电池负极材料

doi:10.3866/PKU.WHXB201706162

Abstract

Abstract:

AlN-Fe nanocomposite thin films with different AlN-Fe ratio were prepared by pulsed laser deposition (PLD).They were investigated as new anode materials for lithium ion batteries for the first time.The AlN-Fe nanocomposite films with an AlN/Fe ratio of 2:1 show the best electrochemical performance.They exhibit a specific capacity of 510 mA·g^-1 after 100 cycles at a rate of 500 mA·g^-1.Further, the study of the electrochemical reaction mechanism of the AlN-Fe nanocomposite thin films with lithium reveals that AlN decomposes during the discharge process to form the LiAl alloy and Li₃N.During recharge, a part of Li₃N reacts with Fe to form Fe₃N, and the rest reacts with Al to form AlN.In subsequent cycles, all of Fe₃N, AlN, and Al react with Li reversibly, contributing to the reversible charge-discharge processes and to the superior electrochemical performance of AlN-Fe nanocomposite thin films.Thus, this study provides a new perspective to design advanced electrode materials for lithium-ion batteries.

Key words: Lithium-ion battery, Anode material, Aluminium nitride, Thin film, Pulsed laser Deposition

Xiao-Ye NIU,Xiao-Qin DU,Qin-Chao WANG,Xiao-Jing WU,Xin ZHANG,Yong-Ning ZHOU. AlN-Fe Nanocomposite Thin Film:A New Anode Material for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin. 2017, 33(12), 2517-2522. doi: 10.3866/PKU.WHXB201706162

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AlN-Fe Nanocomposite Thin Film:A New Anode Material for Lithium-Ion Batteries

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