功能化固态电解质膜改性锂金属负极的研究进展

doi:10.3866/PKU.WHXB202008092

Abstract

Abstract:

The ever-increasing demand for high-energy Li-ion batteries has acted as a powerful stimulus for the development of Li metal as an anode material. Li metal has long been regarded as a "Holy Grail" in Li-ion batteries due to its high discharge capacity (3860 mAh·g^-1) and low electric potential (-3.04 V). However, the formation of unstable solid electrolyte interphases (SEIs) and Li dendrites, as well as the resultant safety issues initiated by catastrophic dendrite growth, have greatly impeded further application. High ion conductivity, surface electron insulation, and favorable mechanical strength are essential properties for an ideal SEI film, which can allow for uniform Li deposition, providing a fast transfer path for Li ions and suppressing Li dendrite growth. Therefore, designing a functional SEI layer is an effective strategy to solve the problems encountered with Li metal anodes. So far, a variety of inorganic, organic, and inorganic/organic hybird SEI layers have been designed and fabricated. Inorganic SEIs are characterized by mechanical strength and ion conductivity; organic SEIs are flexible and have electron insulation properties. Inorganic/organic composite SEIs show favorable ion conductivity derived from the inorganic components, electron insulation properties originating from the organic components, and mechanical strength benefiting from the reinforcing effect between the inorganic and organic components. Oxides, metal sulfides, lithium nitride (Li₃N) and its derivates, lithium halide (LiX, X = F, Cl), two-dimensional (2D) layered structure materials, lithium phosphate and "Janus" composite are the representative examples of inorganic SEIs. The design principle of various SEI layers is based on the inhibition of Li dendrite formation and growth. Therefore, it is a prerequisite to better understand the relevant intrinsic mechanisms. Despite past investigations, further studies are still required to fully elucidate the related mechanisms by providing more broadly accepted evidence combined with theoretical calculations and offer reliable guidance for the design of multifunctional SEI layers, boosting the performance of Li metal anodes. In this review, on the basis of the mechanisms underlying Li dendrite formation and growth, strategies for constructing various functional SEI films, highlights in structure and property of the films, and their effects on the performance of Li metal anodes are summarized. Moreover, some challenges encountered with the practical applications of Li metal anodes and the future direction for the development of Li metal anodes are addressed. This review can reveal possible strategies for the commercialization of high-energy, safe and stable Li-ion batteries.

Key words: Li metal anode, Li dendrite growth, Functional SEI film, Uniform Li deposition, High-energy battery

Huaming Qian, Xifei Li. Progress in Functional Solid Electrolyte Interphases for Boosting Li Metal Anode[J]. Acta Phys. -Chim. Sin. 2021, 37(2), 2008092. doi: 10.3866/PKU.WHXB202008092

Figures/Tables 10

Fig 1

Fig 2

Fig 3

Fig 4

Fig 5

Fig 6

Fig 7

Fig 8

Fig 9

Table 1

The role of different kinds of SEI film with various structure and component in regulating Li deposition."

Type of SEI film			Ion conductivity	Mechanical strength	Electron insulation	Highlights	Ref.
Inorganic SEI	Oxides	MgO nanosheet	√	√		Uniform Li ion transfer towards interface	61
		ALD Al₂O₃	√	√		Uniform and dense SEI	4
		ALD ZrO₂	√	√		Uniform and dense SEI	62
						Anti oxidation and hightemperature
		SiO₂	√	√		Chemical stability	63
	Metal sulfide	Li₂S/LiI	√	√		Self-healing ability	64
		Li₂S/Li₂Se	√	√		Superior ion conductivity	65
		MoS₂ sheet	√	√		Uniform Li plating within the sheet structure	66
	Nitrides	Li₃N particles	√	√		3D network Li deposits	67
		g-C₃N₄ nanosheet	√	√		Abundant nucleation sites High modulus	68
		[LiNBH]_n	√	√	√	Li deposition under the SEI layer	69
		Li₃N/Zn/ZnLi_x/Li₂O	√	√		Well interface contact with solid electrolyte	70
Inorganic SEI	Halides	LiF/Cu	√	√		Preferential Li deposition at the grain boundary	73
		CeF₃	√	√		Li deposition along specific crystal facet	74
		LiCl/Ge/GeO_xLi₂CO₃/	√	√		Favorable waterproofness	75
		LiOH/Li₂O
		LiF/F-doped	√	√		Uniform Li plating between	76
		carbon layer				LiF and Li metal
		LiF/graphene	√	√		Stable in air at room temperature	77
		Cu/LiF@Li/	√	√		Uniform Li plating	78
		carbon fiber				Large Li storage space
		Metal chloride perovskite	√	√		Fast lithium ion shuttle under a low energy barrier	79
		2D layered Layered graphene	√	√		In situ covalent binding	80
		structure Ti₃C₂T_x multilayered	√	√		Fast Li ion transfer	81, 82
		structure				Li growth along horizontal direction
		Phosphates Li₃PO₄, Li₂HPO₄	√	√		High modulus	84
						Interfacial compatibility	86
		“Janus” Li_0.33La_0.56TiO₃/Al₂O₃	√	√		Gradient lithiophilicity Uniform	87,
		composites ZnO/Carbon nanotubes				Li plating near the substrate	88
Organic SEI	Covalent Organic Frameworks		√	√		Shortened transport path for Li ion	90
	Cross-linked	Sill Putty		√	√	Dynamic response characteristic	6
	polymer	PDMS/DFB		√	√	3D network Self-healing ability	91
		MSP/Oligomer	√	√	√	Li plating near the matrix	92
						High-density Li deposits
Inorganic/organic	Graphene oxide/LiF/P(SF-DOL)		√	√		In situ dense and uniform film Buffer layer	97
composite SEI	Li₃N/Styrene-butadiene copolymer		√	√		Promising flexibility	98
	Li₃N/LiN_xO_y/PECA		√	√		In situ formed composite film	99
	LiCl/Organic framework composed of Si—O —Si bond		√	√		Even and fast Li plating	100
	Li₆(Si₂O₇)/Polymer containing Si—O—Si bond		√	√		Reduced side reactions with H₂O and O₂	101
	Mesoporous SiO₂/PVDF		√	√		Facilitated Li diffusion Uniform Li deposition	102

Table 1

References 107

1	Zhang Y. ; Zuo T. T. ; Popovic J. ; Lim K. ; Yin Y. X. ; Maier J. ; Guo Y. G. Mater. Today 2020, 33, 56. doi: 10.1016/j.mattod.2019.09.018
2	Liu J. ; Bao Z. ; N; Cui Y. ; Dufek E. J. ; Goodenough J. B. ; Khalifah P. ; Li Q. Y. ; Liaw B. Y. ; Liu P. ; Manthiram A. ; et al Nat. Energy 2019, 4, 180. doi: 10.1038/s41560-019-0338-x
3	Adair K. R. ; Iqbal M. ; Wang C. H. ; Zhao Y. ; Banis M. N. ; Li R. Y. ; Zhang L. ; Yang R. ; Lu S. G. ; Sun X. L. Nano Energy 2018, 54, 375. doi: 10.1016/j.nanoen.2018.10.002
4	Chen L. ; Connell J. G. ; Nie A. ; Huang Z. N. ; Zavadil K. R. ; Klavetter K. C. ; Yuan Y. F. ; Sharifi-Asl S. ; Shahbazian-Yassar R. ; Libera J. A. J. Mater. Chem. A 2017, 5, 12297. doi: 10.1039/C7TA03116E
5	Jin S. ; Sun Z. W. ; Guo Y. L. ; Qi Z. K. ; Guo C. K. ; Kong X. H. ; Zhu Y. W. ; Ji H. X. Adv. Mater. 2017, 29, 1700783. doi: 10.1002/adma.201700783
6	Liu K. ; Pei A. ; Lee H. R. ; Kong B. ; Liu N. ; Lin D. C. ; Liu Y. Y. ; Liu C. ; Hsu P. C. ; Bao Z. N. ; et al J. Am. Chem. Soc. 2017, 139, 4815. doi: 10.1021/jacs.6b13314
7	An Y. L. ; Zhang Z. ; Fei H. F. ; Xu X. Y. ; Xiong S. L. ; Feng J. K. ; Ci L. J. J. Power Sources 2017, 363, 193. doi: 10.1016/j.jpowsour.2017.07.101
8	Wang M. Q. ; Peng Z. ; Luo W. W. ; Zhang Q. ; Li Z. D. ; Zhu Y. ; Lin H. ; Cai L. T. ; Yao X. Y. ; Ouyang C. Y. ; et al Adv. Sci. 2020, 7, 2000237. doi: 10.1002/advs.202000237
9	Liu F. F ; Zhang Z. W. ; Ye S. F. ; Yao Y. ; Yu Y. Acta Phys. -Chim. Sin. 2021, 37, 2006021.
	刘凡凡; 张志文; 叶淑芬; 姚雨; 余彦. 物理化学学报, 2021, 37, 2006021. doi: 10.3866/PKU.WHXB202006021
10	Zhang X. ; Yang Y. A. ; Zhou Z. Chem. Soc. Rev. 2020, 49, 3040. doi: 10.1039/c9cs00838a
11	Xie J. ; Lu Y. C. Nat. Commun. 2020, 11, 2499. doi: 10.1038/s41467-020-16259-9
12	Zhang R. ; Li N. W. ; Cheng X. B. ; Yin Y. X. ; Zhang Q. ; Guo Y. G. Adv. Sci. 2017, 4, 1600445. doi: 10.1002/advs.201600445
13	Liang X. ; Pang Q. ; Kochetkov I. R. ; Sempere M. S. ; Huang H. ; Sun X. Q. ; Nazar L. F. Nat. Energy 2017, 2, 17119. doi: 10.1038/nenergy.2017.119
14	Lin D. C ; Liu Y. Y. ; Cui Y. Nat. Nanotechnol. 2017, 12, 194. doi: 10.1038/NNANO.2017.16
15	Wu F. X. ; Maier J. ; Yu Y. Chem. Soc. Rev. 2020, 49, 1569. doi: 10.1039/c7cs00863e
16	Lee D. ; Sun S. ; Kwon J. ; Park H. ; Jang M. ; Park E. ; Son B. ; Jung Y. ; Song T. ; Paik U. Adv. Mater. 2020, 32, e1905573. doi: 10.1002/adma.201905573
17	Zhai P. B. ; Liu L. X. ; Gu X. K. ; Wang T. S. ; Gong Y. J. Adv. Energy Mater. 2020, 2001257. doi: 10.1002/aenm.202001257
18	Kim M. S. ; Ryu J. H. ; Deepika; ; Lim Y. R. ; Nah I. W. ; Lee K. R. ; Archer L. A. ; Cho W. I. Nat. Energy 2018, 3, 889. doi: 10.1038/s41560-018-0237-6
19	Brissot C. ; Rosso M. ; Chazalviel J. N. ; Lascaud S. J. Power Sources 1999, 925, 81- 82. doi: 10.1016/S0378-7753(98)00242-0
20	Han F. D. ; Westover A. S. ; Yue J. ; Fan X. L. ; Wang F. ; Chi M. F. ; Leonard D. N. ; Dudney N. J. ; Wang H. ; Wang C. S. Nat. Energy 2019, 4, 187. doi: 10.1038/s41560-018-0312-z
21	Chen X. R. ; Yao Y. X. ; Yan C. ; Zhang R. ; Cheng X. B. ; Zhang Q. Angew. Chem. Int. Ed. 2020, 59, 7743. doi: 10.1002/anie.202000375
22	Peled E. ; Golodnitsky D. ; Ardel G. J. Electrochem. Soc. 1997, 144, L208. doi: 10.1149/1.1837858
23	Peled E. ; Menkin S. J. Electrochem. Soc. 2017, 164, A1703. doi: 10.1149/2.1441707jes
24	Yu X. W. ; Manthiram A. Energy Environ. Sci. 2018, 11, 527. doi: 10.1039/C7EE02555F
25	Zhang W. D. ; Zhuang H. L. L. ; Fan L ; Gao L. N. ; Lu Y. Y. Sci. Adv. 2018, 4, eaar4410. doi: 10.1126/sciadv.aar4410
26	Tikekar M. D. ; Choudhury S. ; Tu Z. Y. ; Archer L. A. Nat. Energy 2016, 1, 16114. doi: 10.1038/NENERGY.2016.114
27	Shi F. F. ; Pei A. ; Boyle D. T. ; Xie J. ; Yu X. Y. ; Zhang X. K. ; Cui Y. Proc. Natl. Acad. Sci. U.S.A. 2018, 115, 8529. doi: 10.1073/pnas.1806878115
28	Cheng X. B. ; Zhang R. ; Zhao C. Z. ; Zhang Q. Chem. Rev. 2017, 117, 10403. doi: 10.1021/acs.chemrev.7b00115
29	Han B. ; Feng D. Y. ; Li S. ; Zhang Z. ; Zou Y. C. ; Gu M. ; Meng H. ; Wang C. Y. ; Xu K. ; Zhao Y. S. ; et al Nano Lett. 2020, 20, 4029. doi: 10.1021/acs.nanolett.0c01400
30	Liu D. H. ; Bai Z. Y. ; Li M. ; Yu A. P. ; Luo D. ; Liu W. W. ; Yang L. ; Lu J. ; Amine K. ; Chen Z. W. Chem. Soc. Rev. 2020, 49, 5407. doi: 10.1039/c9cs00636b
31	Bai P. ; Li J. ; Brushett F. R. ; Bazant M. Z. Energy Environ. Sci. 2016, 9, 3221. doi: 10.1039/c6ee01674j
32	Wang X. F. ; Pawar G. ; Li Y. J. ; Ren X. D. ; Zhang M. Z. ; Lu B. Y. ; Banerjee A. ; Liu P. ; Dufek E. J. ; Zhang J. G. ; et al Nat. Mater. 2020, 1. doi: 10.1038/s41563-020-0729-1
33	Li Y. B. ; Huang W. ; Li Y. Z. ; Chiu W. ; Cui Y. ACS Nano 2020, 14, 9263. doi: 10.1021/acsnano.0c05020
34	Wang X. F. ; Zhang M. H. ; Alvarado J. ; Wang S. ; Sina M. ; Lu B. Y. ; Bouwer J. ; Xu W. ; Xiao J. ; Zhang J. G. ; et al Nano Lett. 2017, 17, 7606. doi: 10.1021/acs.nanolett.7b03606
35	Zachman M. J. ; Tu Z. Y. ; Choudhury S. ; Archer L. A. ; Kourkoutis L. F. Nature 2018, 560, 345. doi: 10.1038/s41586-018-0397-3
36	Wang W. W. ; Gu Y. ; Yan H. ; Li S. ; He J. W. ; Xu H. Y. ; Wu Q. H. ; Yan J. W. ; Mao B. W. Chem 2020, 6, 1. doi: 10.1016/j.chempr.2020.07.014
37	Zhang W. D. ; Shen Z. ; Li S. Y. ; Fan L. ; Wang X. Y. ; Chen F. ; Zang X. X. ; Wu T. ; Ma F. Y. ; Lu Y. Y. Adv. Funct. Mater. 2020, 2003800. doi: 10.1002/adfm.202003800
38	Zhao J. M. ; Cano M. ; Giner-Casares J. J. ; Luque R. ; Xu G. B. Energy Environ. Sci. 2020, 13, 2618. doi: 10.1039/D0EE01184C
39	Huang W. ; Wang H. S. ; Boyle D. T. ; Li Y. Z. ; Cui Y. ACS Energy Lett. 2020, 5, 1128. doi: 10.1021/acsenergylett.0c00194
40	Adair K. R. ; Banis M. N. ; Zhao Y. ; Bond T. ; Li R. Y. ; Sun X. L. Adv. Mater. 2020, 32, 2002550. doi: 10.1002/adma.202002550
41	Zhou Y. F. ; Su M. ; Yu X. F. ; Zhang Y. Y. ; Wang J. G. ; Ren X. D. ; Cao R. G. ; Xu W. ; Baer D. R. ; Du Y. G. ; et al Nat. Nanotechnol. 2020, 15, 224. doi: 10.1038/s41565-019-0618-4
42	Chang H. J. ; Ilott A. J. ; Trease N. M. ; Mohammadi M. ; Jerschow A. ; Grey C. P. J. Am. Chem. Soc. 2015, 137, 15209. doi: 10.1021/jacs.5b09385
43	Li H. ; Chao D. L. ; Chen B. ; Chen X. ; Chuah C. ; Tang Y. H. ; Jiao Y. ; Jaroniec M. ; Qiao S. Z. J. Am. Chem. Soc. 2020, 142, 2012. doi: 10.1021/jacs.9b11774
44	Chen Y. M. ; Wang Z. Q. ; Li X. Y. ; Yao X. H. ; Wang C. ; Li Y. T. ; Xue W. J. ; Yu D. W. ; Kim S. Y. ; Yang F. ; et al Nature 2020, 578, 251. doi: 10.1038/s41586-020-1972-y
45	Ding F. ; Xu W. ; Graff G. L. ; Zhang J. ; Sushko M. L. ; Chen X. L. ; Shao Y. Y. ; Engelhard M. H. ; Nie Z. M. ; Xiao J. ; et al J. Am. Chem. Soc. 2013, 135, 4450. doi: 10.1021/ja312241y
46	Yang S. J. ; Xu X. Q. ; Cheng X. B. ; Wang X. M. ; Chen J. X. ; Xiao Y. ; Yuan H. ; Liu H. ; Chen A. B. ; Zhu W. C. ; et al Acta Phys. -Chim. Sin. 2021, 37, 2007058.
	杨世杰; 徐向群; 程新兵; 王鑫萌; 陈金秀; 肖也; 袁洪; 刘鹤; 陈爱兵; 朱万诚; 等. 物理化学学报, 2021, 37, 2007058. doi: 10.3866/PKU.WHXB202007058
47	Qian J. F. ; Henderson W. A. ; Xu W. ; Bhattacharya P. ; Engelhard M. ; Borodin O. ; Zhang J. G. Nat. Commun. 2015, 6, 6362. doi: 10.1038/ncomms7362
48	Yu Z. A. ; Cui Y. ; Bao Z. N. Cell Rep. Phys. Sci. 2020, 1, 100119. doi: 10.1016/j.xcrp.2020.100119
49	Gao S. L. ; Sun F. Y. ; Liu N. ; Yang H. B. ; Cao P. F. Mater. Today 2020. doi: 10.1016/j.mattod.2020.06.011
50	Fu C. Y. ; Venturi V. ; Kim J. ; Ahmad Z. ; Ells A. W. ; Viswanathan V. ; Helms B. A. Nat. Mater. 2020, 19, 758. doi: 10.1038/s41563-020-0655-2
51	Lin C. F. ; Kozen A. C. ; Noked M. ; Liu C. Y. ; Rubloff G. W. Adv. Mater. Interfaces. 2016, 3, 1600426. doi: 10.1002/admi.201600426
52	Lee J. I. ; Shin M. ; Hong D. ; Park S. Adv. Energy Mater. 2019, 9, 1803722. doi: 10.1002/aenm.201803722
53	Zhang F. ; Shen F. ; Fan Z. Y. ; Ji X. ; Zhao B. ; Sun Z. T. ; Xuan Y. Y. ; Han X. G. Rare Met. 2018, 37, 510. doi: 10.1007/s12598-018-1054-6
54	Gao Y. ; Zhao Y. M. ; Li Y. C. ; Huang Q. Q. ; Mallouk T. E. ; Wang D. H. J. Am. Chem. Soc. 2017, 139, 15288. doi: 10.1021/jacs.7b06437
55	Jang E. K. ; Ahn J. ; Yoon S. ; Cho K. Y. Adv. Funct. Mater. 2019, 29, 1905078. doi: 10.1002/adfm.201905078
56	Chai J. C. ; Chen B. B. ; Xian F. ; Wang P. ; Du H. P. ; Zhang J. J. ; Liu Z. H. ; Zhang H. R. ; Dong S. M. ; Zhou X. H. ; et al Small 2018, 14, 1802244. doi: 10.1002/smll.201802244
57	Bai W. L. ; Zhang Z. ; Chen X. ; Wei X. ; Zhang Q. ; Xu Z. X. ; Liu Y. S. ; Chang B. B. ; Wang K. X. ; Chen J. S. Energy Storage Mater. 2020, 31, 373. doi: 10.1016/j.ensm.2020.06.036
58	Shen Z. Y. ; Zhang W. D. ; Li S. Y. ; Mao S. L. ; Wang X. Y. ; Chen F. ; Lu Y. Y. Nano Lett. 2020, 20, 6606. doi: 10.1021/acs.nanolett.0c02371
59	Zhu J. G. ; Li P. K. ; Chen X. ; Legut D. ; Fan Y. C. ; Zhang R. F. ; Lu Y. Y. ; Cheng X. B. ; Zhang Q. Energy Storage Mater. 2019, 16, 426. doi: 10.1016/j.ensm.2018.06.023
60	Han X. G. ; Gong Y. H. ; Fu K. K. ; He X. F. ; Hitz G. T. ; Dai J. Q. ; Pearse A. ; Liu B. Y. ; Wang H. ; Rubloff G. ; et al Nat. Mater. 2017, 16, 572. doi: 10.1038/NMAT4821
61	Zhou Y. G. ; Zhang X. ; Ding Y. ; Bae J. ; Guo X. L. ; Zhao Y. ; Yu G. H. Adv. Mater. 2020, 32, 2003920. doi: 10.1002/adma.202003920
62	Alaboina P. K. ; Rodrigues S. ; Rottmayer M. ; Cho S. J. ACS Appl. Mater. Interfaces 2018, 10, 32801. doi: 10.1021/acsami.8b08585
63	Kim J. Y. ; Kim A. Y. ; Liu G. C. ; Woo J. Y. ; Kim H. ; Lee J. K. ACS Appl. Mater. Interfaces 2018, 10, 8692. doi: 10.1021/acsami.7b18997
64	Nan Y. ; Li S. M. ; Zhu M. Q. ; Li B. ; Yang S. B. ACS Appl. Mater. Interfaces 2019, 11, 28878. doi: 10.1021/acsami.9b07942
65	Liu F. F. ; Wang L. F. ; Zhang Z. W. ; Shi P. C. ; Feng Y. Z. ; Yao Y. ; Ye S. F. ; Wang H. Y. ; Wu X. J. ; Yu Y. Adv. Funct. Mater. 2020, 30, 2001607. doi: 10.1002/adfm.202001607
66	Cha E. ; Patel M. D. ; Park J. ; Hwang J. ; Prasad V. ; Cho K. ; Choi W. Nat. Nanotechnol. 2018, 13, 337. doi: 10.1038/s41565-018-0061-y
67	Park K. ; Goodenough J. B. Adv. Energy Mater. 2017, 7, 1700732. doi: 10.1002/aenm.201700732
68	Guo Y. P. ; Niu P. ; Liu Y. Y. ; Ouyang Y. ; Li D. ; Zhai T. Y. ; Li H. Q. ; Cui Y. Adv. Mater. 2019, 31, 1900342. doi: 10.1002/adma.201900342
69	Wang Z. J. ; Wang Y. Y. ; Zhang Z. H. ; Chen X. W. ; Lie W. ; He Y. B. ; Zhou Z. ; Xia G. L. ; Guo Z. P. Adv. Funct. Mater. 2020, 30, 2002414. doi: 10.1002/adfm.202002414
70	Zhong Y. R. ; Xie Y. J. ; Hwang S. ; Wang Q. ; Cha J. J. ; Su D. ; Wang H. L. Angew. Chem. Int. Ed. 2020, 59, 14003. doi: 10.1002/anie.202004477
71	Huang Z. M. ; Meng J. T. ; Xie M. L. ; Shen Y. ; Huang Y. H. J. Mater. Chem. A 2020, 8, 14198. doi: 10.1039/D0TA05147K
72	Xu S. M. ; Duan H. ; Shi J. L. ; Zuo T. T. ; Hu X. C. ; Lang S. Y. ; Yan M. ; Liang J. Y. ; Yang Y. G. ; Kong ; et al Nano Res. 2020, 13, 430. doi: 10.1007/s12274-020-2625-z
73	Yan C. ; Cheng X. B. ; Yao Y. X. ; Shen X. ; Li B. Q. ; Li W. J. ; Zhang R. ; Huang J. Q. ; Li H. ; Zhang Q. Adv. Mater. 2018, 30, 1804461. doi: 10.1002/adma.201804461
74	Liu Y. Y. ; Xiong S. Z. ; Deng J. K. ; Jiao X. X. ; Song B. R. ; Matic A. ; Song J. X. Sci. China Mater. 2020, 63, 1036. doi: 10.1007/s40843-019-1277-3
75	Liao K. M. ; Wu S. C. ; Mu X. W. ; Lu Q. ; Han M. ; He P. ; Shao Z. P. ; Zhou H. S. Adv. Mater. 2018, 30, 1705711. doi: 10.1002/adma.201705711
76	Yu Y. ; Huang G. ; Wang J. Z. ; Li K. ; Ma J. L. ; Zhang X. B. Adv. Mater. 2020, 2004157. doi: 10.1002/adma.202004157
77	Shen X. W. ; Li Y. T. ; Qian T. ; Liu J. ; Zhou J. Q. ; Yan C. L. ; Goodenough J. B. Nat. Commun. 2019, 10, 900. doi: 10.1038/s41467-019-08767-0
78	Shen X. ; Cheng X. B. ; Shi P. ; Huang J. Q. ; Zhang X. Q. ; Yan C. ; Li T. ; Zhang Q. J. Energy Chem. 2019, 37, 29. doi: 10.1016/j.jechem.2018.11.016
79	Yin Y. C. ; Wang Q. ; Yang J. T. ; Li F. ; Zhang G. Z. ; Jiang C. H. ; Mo H. S. ; Yao J. S. ; Wang K. H. ; Zhou F. ; et al Nat. Commun. 2020, 11, 1761. doi: 10.1038/s41467-020-15643-9
80	Bai M. H. ; Xie K. Y. ; Yuan K. ; Zhang K. ; Li N. ; Shen C. ; Lai Y. Q. ; Vajtai R. ; Ajayan P. ; Wei B. Q. Adv. Mater. 2018, 30, 1801213. doi: 10.1002/adma.201801213
81	Zhang D. ; Wang S. ; Li B. ; Gong Y. J. ; Yang S. B. Adv. Mater. 2019, 31, 1901820. doi: 10.1002/adma.201901820
82	Chen X. ; Shang M. W. ; Niu J. J. Nano Lett. 2020, 20, 2639. doi: 10.1021/acs.nanolett.0c00201
83	Tang W. ; Yin X. S. ; Kang S. J. ; Chen Z. X. ; Tian B. B. ; Teo S. L. ; Wang X. W. ; Chi X. ; Loh K. P. ; Lee H. W. ; et al Adv. Mater. 2018, 30, 1801745. doi: 10.1002/adma.201801745
84	Li N. W. ; Yin Y. X. ; Yang C. P. ; Guo Y. G. Adv. Mater. 2016, 28, 1853. doi: 10.1002/adma.201504526
85	Bai M. H. ; Xie K. Y. ; Hong B. ; Yuan K. ; Li Z. B. ; Huang Z. M. ; Shen C. ; Lai Y. Q. Solid State Ionics 2019, 333, 101. doi: 10.1016/j.ssi.2019.01.016
86	Zhang Z. H. ; Chen S. J. ; Yang J. ; Wang J. Y. ; Yao L. L. ; Yao X. Y. ; Cui P. ; Xu X. X. ACS Appl. Mater. Interfaces 2018, 10, 2556. doi: 10.1021/acsami.7b16176
87	Lai Y. M. ; Zhao Y. ; Cai W. P. ; Song J. ; Jia Y. T. ; Ding B. ; Yan J. H. Small 2019, 15, 1905171. doi: 10.1002/smll.201905171
88	Zhang H. M. ; Liao X. B. ; Guan Y. P. ; Xiang Y. ; Li M. ; Zhang W. F. ; Zhu X. Y. ; Ming H. ; Lu L. ; Qiu J. Y. ; et al Nat. Commun. 2018, 9, 3729. doi: 10.1038/s41467-018-06126-z
89	Zhang X. ; Zhang Q. M. ; Wang X. G. ; Wang C. Y. ; Chen Y. N. ; Xie Z. J. ; Zhou Z. Angew. Chem. Int. Ed. 2018, 57, 12814. doi: 10.1002/anie.201807985
90	Chen D. D. ; Huang S. ; Zhong L. ; Wang S. J. ; Xiao M. ; Han D. M. ; Meng Y. Z. Adv. Funct. Mater. 2019, 30, 1907717. doi: 10.1002/adfm.201907717
91	Cui X. M. ; Chu Y. ; Qin L. M. ; Pan Q. M. ACS Sustain. Chem. Eng. 2018, 6, 11097. doi: 10.1021/acssuschemeng.8b02564
92	Lee Y. G. ; Ryu S. ; Sugimoto T. ; Yu T. ; Chang W. S. ; Yang Y. ; Jung C. ; Woo J. ; Kang S. G. ; Han H. N. ; et al Chem. Mater. 2017, 29, 5906. doi: 10.1021/acs.chemmater.7b01304
93	Wang C. H. ; Yang Y. F. ; Liu X. J. ; Zhong H. ; Xu H. ; Xu Z. B. ; Shao H. X. ; Ding F. ACS Appl. Mater. Interfaces 2017, 9, 13694. doi: 10.1021/acsami.7b00336
94	Li G. X. ; Gao Y. ; He X. ; Huang Q. Q. ; Chen S. R. ; Kim S. H. ; Wang D. H. Nat. Commun. 2017, 8, 850. doi: 10.1038/s41467-017-00974-x
95	Yan C. ; Cheng X. B. ; Tian Y. ; Chen X. ; Zhang X. Q. ; Li W. J. ; Huang J. Q. ; Zhang Q. Adv. Mater. 2018, 30, e1707629. doi: 10.1002/adma.201707629
96	Liu S. F. ; Xia X. H. ; Deng S. J. ; Xie D. ; Yao Z. J. ; Zhang L. Y. ; Zhang S. Z. ; Wang X. L. ; Tu J. P. Adv. Mater. 2019, 31, 1806470. doi: 10.1002/adma.201806470
97	Gao Y. ; Yan Z. F. ; Gray J. L. ; He X. ; Wang D. W. ; Chen T. H. ; Huang Q. Q. ; Li Y. G. C. ; Wang H. Y. ; Kim S. H. ; et al Nat. Mater. 2019, 18, 384. doi: 10.1038/s41563-019-0305-8
98	Liu Y. Y. ; Lin D. C. ; Yuen P. Y. ; Liu K. ; Xie J. ; Dauskardt R. H. ; Cui Y. Adv. Mater. 2017, 29, 1605531. doi: 10.1002/adma.201605531
99	Hu Z. L. ; Zhang S. ; Dong S. M. ; Li W. J. ; Li H. ; Cui G. L. ; Chen L. Q. Chem. Mater. 2017, 29, 4682. doi: 10.1021/acs.chemmater.7b00091
100	Zhao Q. ; Tu Z. Y. ; Wei S. Y. ; Zhang K. H. ; Choudhury S. ; Liu X. T. ; Archer L. A. Angew. Chem. Int. Ed. 2018, 57, 992. doi: 10.102/anie.201711598
101	Liang W. ; Lian F. ; Meng N. ; Lu J. H. ; Ma L. J. ; Zhao C. Z. ; Zhang Q. Energy Storage Mater. 2020, 28, 350. doi: 10.1016/j.ensm.2020.03.022
102	Wu C. ; Guo F. H. ; Zhuang L. ; Ai X. P. ; Zhong F. P. ; Yang H. X. ; Qian J. F. ACS Energy Lett. 2020, 5, 1644. doi: 10.1021/acsenergylett.0c00804
103	Zhao Y. ; Goncharova L. V. ; Sun Q. ; Li X. ; Lushington A. ; Wang B. Q. ; Li R. Y. ; Dai F. ; Cai M. ; Sun X. L. Small Methods 2018, 2, 1700417. doi: 10.1002/smtd.201700417
104	Sun Y. P. ; Amirmaleki M. ; Zhao Y. ; Zhao C. T. ; Liang J. N. ; Wang C. H. ; Adair K. R. ; Li J. J. ; Cui T. ; Wang G. R. ; et al Adv. Energy Mater. 2020, 10, 2001139. doi: 10.1002/aenm.202001139
105	Wood D. L. ; Li J. L. ; An S. J. Joule 2019, 3, 2884. doi: 10.1016/j.joule.2019.11.002
106	Zhao Y. ; Goncharova L. V. ; Zhang Q. ; Kaghazchi P. ; Sun Q. ; Lushington A. ; Wang B. Q. ; Li R. Y. ; Sun X. L. Nano Lett. 2017, 17, 5653. doi: 10.1021/acs.nanolett.7b02464
107	Xie J. ; Wang J. Y. ; Lee H. R. ; Yan K. ; Li Y. Z. ; Shi F. F. ; Huang W. ; Pei A. ; Chen G. ; Subbaraman R. ; et al Sci. Adv. 2018, 4, eaat5168. doi: 10.1126/sciadv.aat5168

[1]	Danmiao Kang, Noam Hart, Muye Xiao, John P. Lemmon. Short Circuit of Symmetrical Li/Li Cell in Li Metal Anode Research [J]. Acta Phys. -Chim. Sin., 2021, 37(2): 2008013-.
[2]	Jun Guan, Nianwu Li, Le Yu. Artificial Interphase Layers for Lithium Metal Anode [J]. Acta Phys. -Chim. Sin., 2021, 37(2): 2009011-.
[3]	Fanyang Huang, Yulin Jie, Xinpeng Li, Yawei Chen, Ruiguo Cao, Genqiang Zhang, Shuhong Jiao. Correlation between Li Plating Morphology and Reversibility of Li Metal Anode [J]. Acta Phys. -Chim. Sin., 2021, 37(1): 2008081-.
[4]	Fanfan Liu, Zhiwen Zhang, Shufen Ye, Yu Yao, Yan Yu. Challenges and Improvement Strategies Progress of Lithium Metal Anode [J]. Acta Phys. -Chim. Sin., 2021, 37(1): 2006021-.
[5]	Muqin Wang, Zhe Peng, Huan Lin, Zhendong Li, Jian Liu, Zhongmin Ren, Haiyong He, Deyu Wang. A Framework with Enriched Fluorinated Sites for Stable Li Metal Cycling [J]. Acta Phys. -Chim. Sin., 2021, 37(1): 2007016-.

Progress in Functional Solid Electrolyte Interphases for Boosting Li Metal Anode

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 10

References 107

Related Articles 5

Metrics

Recommended 0