聚乙烯亚胺修饰的氧化硅纳米管基吸附剂的制备及其CO2吸附应用

doi:10.3866/PKU.WHXB201402123

Abstract

Abstract:

Mesoporous ethane-silica nanotubes (E-SNTs) were synthesized using P123 as a template and 1,2-bis(trimethoxysilyl)ethane (BTME) as a silica source. E-SNTs were modified with polyethylenimine (PEI) as sorbents for CO₂ adsorption. These new composite sorbents were characterized by transmission electron microscopy (TEM), nitrogen adsorption/desorption, Fourier transform infrared (FTIR) spectroscopy, and thermal gravimetric analysis (TGA). We found that 75 ℃ is the optimal temperature for CO₂ adsorption. E-SNTs with a 50% (w) PEI loading (E-SNTs-50) exhibited a higher CO₂ adsorption capacity (3.32 mmol·g^-1) than the other materials. The E-SNTs-based sorbents show better CO₂ capture performance than the SBA-15-based sorbents. Additionally, CO₂ uptake was further enhanced to 3.75 mmol·g^-1 in the presence of moisture. Cyclic CO₂ adsorption-desorption test results indicated that the composite sorbents are stable and can be regenerated.

Key words: Mesoporoussilica nanotube, Polyethylenimine, Adsorption, CO₂ capture

YAO Man-Li, DONG Yan-Yan, XIE Jing, JIA Ai-Ping, XIE Guan-Qun, HU Geng-Shen, LUO Meng-Fei. Preparation of Polyethylenimine-Functionalized Silica Nanotubes and Their Application for CO₂ Adsorption[J]. Acta Phys. -Chim. Sin. 2014, 30(4), 789-796. doi: 10.3866/PKU.WHXB201402123

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Preparation of Polyethylenimine-Functionalized Silica Nanotubes and Their Application for CO₂ Adsorption

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Preparation of Polyethylenimine-Functionalized Silica Nanotubes and Their Application for CO₂ Adsorption