碳前驱体在全氟磺酸型碳基固体酸材料设计中的影响

doi:10.3866/PKU.WHXB201506012

Abstract

Abstract:

Perfluorosulfonic acid functionalized carbon-based solid acid catalysts were prepared by liquid deposition of perfluorosulfonic acid-polytetrafluoroethylene (PTFE) copolymer using carbon nanotubes, mesoporous carbon molecular sieves, and nitrogen-doped mesoporous carbon as precursors. The obtained catalysts were characterized by N₂ adsorption, thermogravimetric analysis (TG), transmission electron microscope (TEM), Fourier transform Infrared (FTIR) spectrometer, and potentiometric titration. Their catalytic behavior in the Friedel-Crafts (F-C) alkylation of anisole was also investigated. It was found that the surface area of the precursor and its interaction with perfluorosulfonic acid play important roles in the preparation of highly active catalysts. The highest activity as well as the best stability was observed over perfluorosulfonic acid functionalized nitrogen-doped mesoporous carbon.

Key words: Carbon-based solid acid, Perfluorosulfonic acid, Acidity, Stability, Friedel-Crafts alkylation

Cui-Can. LI,Meng-Xiao. ZHANG,Wei-Ming. HUA,Ying-Hong. YUE,Zi. GAO. Effect of the Carbon Precursor on the Design of Perfluorosulfonic Acid Functionalized Carbon Catalysts[J].Acta Phys. -Chim. Sin., 2015, 31(9): 1747-1752.

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Effect of the Carbon Precursor on the Design of Perfluorosulfonic Acid Functionalized Carbon Catalysts

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