非晶高熵FeCoCrMnBS氢氧化物构筑及其增强氧析出催化性能研究

doi:10.3866/PKU.WHXB202404023

Abstract

Abstract:

The efficient electrocatalysts towards the oxygen evolution reaction (OER) are vital for water splitting. Herein, a novel FeCoCrMnBS high-entropy (Oxy) hydroxide (HEH) is synthesized on a nickel foam (NF) surface via a facile approach. The FeCoCrMnBS HEH possesses a porous morphology composed of plentiful ultra-thin nanosheets with the amorphous structure. The obtained FeCoCrMnBS/NF electrode exhibits exceptional electrocatalytic OER activity in alkaline solution, requiring only 290 mV overpotential for 100 mA∙cm⁻². Moreover, this catalyst displays a long-term durability of over 120 h at 10 mA∙cm⁻². The enhanced catalytic performance benefits from the unique amorphous structure and the positive synergy effect between B and S, promoting the formation of SO₄²⁻ and thus weakening the adsorption of intermediates in OER on the catalyst surface. This work provides a new strategy for the design of desirable OER electrocatalysts.

Key words: High-entropy (Oxy) hydroxide, Doping, Amorphous structure, Oxygen evolution reaction

Xin Han, Zhihao Cheng, Jinfeng Zhang, Jie Liu, Cheng Zhong, Wenbin Hu. Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction[J]. Acta Phys. -Chim. Sin. 2025, 41(4), 100033. doi: 10.3866/PKU.WHXB202404023

Figures/Tables 5

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Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction

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