硅胶键联MPc的制备及其在氧活化中的作用

doi:10.3866/PKU.WHXB19940715

Acta Phys. -Chim. Sin. ›› 1994, Vol. 10 ›› Issue (07): 654-657.doi: 10.3866/PKU.WHXB19940715

• Note • Previous Articles Next Articles

Preparation of SiO₂-ligated Metallo-phthalocyanine(MPc) and it's Role in the Activation of Dioxygen

Zhang Wei-De, Zhan Rui-Yun, Ye Xing-Kai, Wu Yue

Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022

Received:1993-02-13 Revised:1993-07-19 Published:1994-07-15
Contact:

Abstract

Abstract:

The metal phthalocyanines (MPc, M=Fe, Co, Cu) were supported on the surface of silica gel by chemical linking. They could not be washed out with organic solvents such as Py. UV-Vis diffuse reflectance spectra indicated that MPc s were supported on silica gel. ESR result showed that the supported CoPc and FePc could react with O_2 to produce O~-_2, but the supported CuPc could not.

Key words: Metal phthalocyanine, Supported, The activation of O₂, Catalyst

Zhang Wei-De, Zhan Rui-Yun, Ye Xing-Kai, Wu Yue. Preparation of SiO₂-ligated Metallo-phthalocyanine(MPc) and it's Role in the Activation of Dioxygen[J]. Acta Phys. -Chim. Sin. 1994, 10(07), 654-657. doi: 10.3866/PKU.WHXB19940715

[1]	Jiangyuan Qiu, Tao Yu, Junxin Chen, Wenxuan Li, Xiaoxuan Zhang, jinsheng Li, Rui Guo, Zaiyin Huang, Xuanwen Liu. Modulate surface potential well depth of Bi₁₂O₁₇Cl₂ by FeOOH in Bi₁₂O₁₇Cl₂@FeOOH heterojunction to boost piezoelectric charge transfer and piezo-self-Fenton catalysis [J]. Acta Phys. -Chim. Sin., 2026, 42(1): 100157-.
[2]	Lele Feng, Xueying Bai, Jifeng Pang, Hongchen Cao, Xiaoyan Liu, Wenhao Luo, Xiaofeng Yang, Pengfei Wu, Mingyuan Zheng. Single-atom Pd boosted Cu catalysts for ethanol dehydrogenation [J]. Acta Phys. -Chim. Sin., 2025, 41(9): 100100-.
[3]	Jingping Li, Suding Yan, Jiaxi Wu, Qiang Cheng, Kai Wang. Improving hydrogen peroxide photosynthesis over inorganic/organic S-scheme photocatalyst with LiFePO₄ [J]. Acta Phys. -Chim. Sin., 2025, 41(9): 100104-.
[4]	Ruizhi Duan, Xiaomei Wang, Panwang Zhou, Yang Liu, Can Li. The role of hydroxyl species in the alkaline hydrogen evolution reaction over transition metal surfaces [J]. Acta Phys. -Chim. Sin., 2025, 41(9): 100111-.
[5]	Fangxuan Liu, Ziyan Liu, Guowei Zhou, Tingting Gao, Wenyu Liu, Bin Sun. Hollow structured photocatalysts [J]. Acta Phys. -Chim. Sin., 2025, 41(7): 100071-.
[6]	Sumiya Akter Dristy, Md Ahasan Habib, Shusen Lin, Mehedi Hasan Joni, Rutuja Mandavkar, Young-Uk Chung, Md Najibullah, Jihoon Lee. Exploring Zn doped NiBP microspheres as efficient and stable electrocatalyst for industrial-scale water splitting [J]. Acta Phys. -Chim. Sin., 2025, 41(7): 100079-.
[7]	Xianghai Song, Xiaoying Liu, Zhixiang Ren, Xiang Liu, Mei Wang, Yuanfeng Wu, Weiqiang Zhou, Zhi Zhu, Pengwei Huo. Insights into the greatly improved catalytic performance of N-doped BiOBr for CO₂ photoreduction [J]. Acta Phys. -Chim. Sin., 2025, 41(6): 100055-.
[8]	Jingzhuo Tian, Chaohong Guan, Haobin Hu, Enzhou Liu, Dongyuan Yang. Waste plastics promoted photocatalytic H₂ evolution over S-scheme NiCr₂O₄/twinned-Cd_0.5Zn_0.5S homo-heterojunction [J]. Acta Phys. -Chim. Sin., 2025, 41(6): 100068-.
[9]	Xuejie Wang, Guoqing Cui, Congkai Wang, Yang Yang, Guiyuan Jiang, Chunming Xu. Research Progress on Carbon-based Catalysts for Catalytic Dehydrogenation of Liquid Organic Hydrogen Carriers [J]. Acta Phys. -Chim. Sin., 2025, 41(5): 100044-.
[10]	Jinwang Wu, Qijing Xie, Chengliang Zhang, Haifeng Shi. Rationally Designed ZnFe_1.2Co_0.8O₄/BiVO₄ S-Scheme Heterojunction with Spin-Polarization for the Elimination of Antibiotic [J]. Acta Phys. -Chim. Sin., 2025, 41(5): 100050-.
[11]	Xue Liu, Lipeng Wang, Luling Li, Kai Wang, Wenju Liu, Biao Hu, Daofan Cao, Fenghao Jiang, Junguo Li, Ke Liu. Research on Cu-Based and Pt-Based Catalysts for Hydrogen Production through Methanol Steam Reforming [J]. Acta Phys. -Chim. Sin., 2025, 41(5): 100049-.
[12]	Pei Li, Yuenan Zheng, Zhankai Liu, An-Hui Lu. Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation [J]. Acta Phys. -Chim. Sin., 2025, 41(4): 100034-.
[13]	Jiali Lei, Juan Wang, Wenhui Zhang, Guohong Wang, Zihui Liang, Jinmao Li. TiO₂/CdIn₂S₄ S-scheme heterojunction photocatalyst promotes photocatalytic hydrogen evolution coupled vanillyl alcohol oxidation [J]. Acta Phys. -Chim. Sin., 2025, 41(12): 100174-.
[14]	Ruiyun Liu, Ping Wang, Xuefei Wang, Feng Chen, Huogen Yu. Work-function-engineered Mo 4d electronic structure modulation in Mo₂C MXene cocatalyst for efficient photocatalytic H₂ evolution [J]. Acta Phys. -Chim. Sin., 2025, 41(11): 100137-.
[15]	Kangjuan Cheng, Chunxiao Liu, Youpeng Wang, Qiu Jiang, Tingting Zheng, Xu Li, Chuan Xia. Design of noble metal catalysts and reactors for the electrosynthesis of hydrogen peroxide [J]. Acta Phys. -Chim. Sin., 2025, 41(10): 100112-.

Preparation of SiO₂-ligated Metallo-phthalocyanine(MPc) and it's Role in the Activation of Dioxygen

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0

Preparation of SiO2-ligated Metallo-phthalocyanine(MPc) and it's Role in the Activation of Dioxygen

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0

Preparation of SiO₂-ligated Metallo-phthalocyanine(MPc) and it's Role in the Activation of Dioxygen