离子液体[Cnpy][NTf2] (n=2, 4, 5)的动力粘度和电导率

doi:10.3866/PKU.WHXB20112762

Acta Phys. -Chim. Sin. ›› 2011, Vol. 27 ›› Issue (12): 2762-2766.doi: 10.3866/PKU.WHXB20112762

• THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY • Previous Articles Next Articles

Dynamic Viscosity and Conductivity of Ionic Liquids [C_npy][NTf₂] (n=2, 4, 5)

LIU Qing-Shan¹, YAN Pei-Fang¹, YANG Miao¹, TAN Zhi-Cheng^1,2, LI Chang-Ping^1,3, WELZ-BIERMANN Urs¹

1. China Ionic Liquid Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, LiaoningProvince, P. R. China;
2. Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences,Dalian 116023, Liaoning Province, P. R. China;
3. College of Chemical Engineering and the Environment, Dalian University,Dalian 116622, Liaoning Province, P. R. China

Received:2011-04-20 Revised:2011-09-21 Published:2011-11-25
Contact: TAN Zhi-Cheng, LI Chang-Ping E-mail:tzc@dicp.ac.cn; licpbit@hotmai.com
Supported by:
The project was supported by the National Natural Science Foundation of China (21073189, 21006007, 20901076, 21176033) and Knowledge Innovation Program of DICP, Chinese Academic of Sciences (K2009D03).

Abstract

Abstract: Experimental dynamic viscosity and conductivity data of the air- and water-stable hydrophobic ionic liquids (ILs) N-alkylpyridinium bis(trifluoromethylsulfonyl)imide ([C_npy][NTf₂] n=2, 4, 5) were recorded at temperatures ranging from 298.15 to 338.15 K and from 283.15 to 338.15 K with an interval of 5 K. The dynamic viscosity and conductivity values of the [C_npy][NTf₂] (n=2, 4, 5) ILs were fitted using the Arrhenius equation and the Fulcher equation. The molar conductivity was calculated at temperatures ranging from 283.15 to 338.15 K from the conductivity and density data. The relationship between the dynamic viscosity and the molar conductivity was discussed in terms of Walden's rule.

Key words: Ionic liquids, Dynamic viscosity, Conductivity, Molar conductivity, Walden rule

LIU Qing-Shan, YAN Pei-Fang, YANG Miao, TAN Zhi-Cheng, LI Chang-Ping, WELZ-BIERMANN Urs. Dynamic Viscosity and Conductivity of Ionic Liquids [C_npy][NTf₂] (n=2, 4, 5)[J].Acta Phys. -Chim. Sin., 2011, 27(12): 2762-2766.

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Dynamic Viscosity and Conductivity of Ionic Liquids [C_npy][NTf₂] (n=2, 4, 5)

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Dynamic Viscosity and Conductivity of Ionic Liquids [C_npy][NTf₂] (n=2, 4, 5)