Co3O4纳米立方体的可控合成及其CO氧化反应性能

doi:10.3866/PKU.WHXB201312032

Abstract

Abstract:

Co₃O₄ nanocubes that were exclusively terminated with {100} facets of edge size 10 nm were solvothermally fabricated in a mixed solution of ethanol and triethylamine. Analyses of the structural evolution of the intermediates at different intervals during the synthesis, together with an examination of the influences of the cobalt precursor and solvent on the product structure, showed that the formation of Co₃O₄ nanocubes followed a dissolution-recrystallization mechanism. After calcination at 200 ℃, the as-synthesized Co₃O₄ material retained a cubic morphology with the same edge size, but calcination at 400 ℃ resulted in the formation of spherical Co₃O₄ particles of diameter about 13 nm. The Co₃O₄ nanocubes exhibited inferior activity in room-temperature CO oxidation compared with Co₃O₄ nanoparticles ({111} facets), primarily as a result of the exposure of the less- reactive {100} facets, demonstrating the morphology effect of Co₃O₄ nanomaterials.

Key words: Co₃O₄, Solvothermal synthesis, Morphology-dependence, Nanocube, CO oxidation

LÜ Yong-Ge, LI Yong, TA Na, SHEN Wen-Jie. Morphology-Controlled Synthesis of Co₃O₄ Nanocubes and Their Catalytic Performance in CO Oxidation[J]. Acta Phys. -Chim. Sin. 2014, 30(2), 382-388. doi: 10.3866/PKU.WHXB201312032

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Morphology-Controlled Synthesis of Co₃O₄ Nanocubes and Their Catalytic Performance in CO Oxidation

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Morphology-Controlled Synthesis of Co₃O₄ Nanocubes and Their Catalytic Performance in CO Oxidation