碳化硅衍生碳/球形天然石墨复合材料的制备及其结构调控

doi:10.3866/PKU.WHXB201501212

Abstract

Abstract:

To meet the requirements of the energy storage materials for high energy density and high power density, porous silicon carbide/derived carbon-spherical natural graphite (SiC-CDCs@NG) composites were prepared. The composites were composed of tailored porous carbide-derived carbon and graphitized carbon with excellent conductivity and a high energy storage capacity. The composition, structure, morphology, pore structure, and specific surface area of the composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy, and N₂ adsorption/ desorption analysis. The composites exhibited a high and adjustable specific surface area and micro-pore volume, with a micro-pore size of between 0.5 and 0.7 nm. Varying the molar ratio of NG and Si allowed optimization of the micro-pore volume, pore size distribution, specific surface area, and composition and content of the CDCs shell and NG core.

Key words: Silicon carbide-derived carbon, Composite, Structure regulation, Specific surface area, Pore size distribution

DU Xue-Lian, CONG Ye, JIANG Lu, LI Xuan-Ke, CUI Zheng-Wei, DONG Zhi-Jun, YUAN Guan-Ming, ZHANG Jiang. Preparation and Structure Regulation of Silicon Carbide-Derived Carbon/ Spherical Natural Graphite Composites[J].Acta Phys. -Chim. Sin., 2015, 31(3): 583-588.

References

(1) Xu, B.; Cao, G. P. New Carbon Mater. 2008, 23 (1), 95. [徐斌, 曹高萍. 新型炭材料, 2008, 23 (1), 95.]
(2) Zhang, R. J.; Zhou, B. Journal of Yanshan University 2011, 35 (4), 283. [张瑞军, 周斌. 燕山大学学报, 2011, 35 (4), 283.]
(3) Tsaia,W. Y.; Gao, P. C.; Daffos, B.; Taberna, P. L.; Perez, C. R.; Gogotsi, Y.; Favier, F.; Simon, P. Electrochem. Commun. 2013, 34, 109. doi: 10.1016/j.elecom.2013.05.031
(4) Lee, S. M.; Kaneko, K. Carbon 2003, 41 (2), 374. doi: 10.1016/S0008-6223(02)00361-5
(5) Zhao, J. C.; Lai, C. Y.; Dai, Y.; Xie, J. Y. Mater. Lett. 2007, 61, 4639. doi: 10.1016/j.matlet.2007.02.071
(6) Xu, J.;Wu, C.; Yan, P. T.; Zhang, R. J.; Yue, X. Q.; Ge, S. H. Microporous Mesoporous Mat. 2014, 198, 74. doi: 10.1016/j.micromeso.2014.07.019
(7) Becker, P.; Glenk, F.; Kormann, M.; Etzold, B. J. M. Chem. Eng. J. 2010, 159 (1-3), 236. doi: 10.1016/j.cej.2010.02.011
(8) Ersoy, D. A.; McNallan, M. J.; Gogotsi, Y. G. Mater. Res. Innov. 2001, 5, 55. doi: 10.1007/s100190100136
(9) Zinovev, A. V.; Elam, J.W.; Moore, J. F.; Hryn, J. N.; Auciello, O.; Carlisle, J. A.; Pellin, M. J. Thin Solid Films 2004, 469 -470, 135.
(10) Jia, J.; Yang, X. Y.; Yan, Y.; Zhu, Y. Y.; Xing, B. L.; Zhou, A. G. Chem. Ind. Eng. Prog. 2014, 33 (10), 2681. [贾进, 杨晓阳, 闫艳, 朱元元, 邢宝林, 周爱国. 化工进展, 2014, 33 (10), 2681.]
(11) Urbonaite, S.;Wachtmeister, S.; Mirguet, C.; Coronel, E.; Zou, W. Y.; Csillag, S.; Svensson, G. Carbon 2007, 45 (10), 2047. doi: 10.1016/j.carbon.2007.05.022
(12) Hoffman, E. N.; Yushin, G.; EL-Raghy, T.; Gogotsi, Y.; Barsoum, M.W. Microporous Mesoporous Mat. 2008, 112, 526. doi: 10.1016/j.micromeso.2007.10.033
(13) Yachamaneni, S.; Yushin, G.; Yeon, S. H.; Gogotsi, Y.; Howell, C.; Sandeman, S.; Phillips, G.; Mikhalovsky, S. Biomaterials 2010, 31, 4789. doi: 10.1016/j.biomaterials.2010.02.054
(14) Leis, J.; Perkson, A.; Arulepp, M.; Kaarik, M.; Svensson, G. Carbon 2001, 39, 2043. doi: 10.1016/S0008-6223(01)00020-3
(15) Gogotsi, Y.;Welz, S.; Ersoy, D. A.; McNallan, M. J. Nature 2001, 411, 283. doi: 10.1038/35077031
(16) Seo, M. S.; Kim, J. H.; Kim, J. M.; Kang, S.; Ihm, J. S.; Kim, D. O. Carbon 2013, 60, 299. doi: 10.1016/j.carbon.2013.04.041
(17) Yeon, S. H.; Raddington, P.; Gogotsi, Y. G.; Fischer, J. E.; Vakifahmetoglu, C.; Colombo, P. Carbon 2010, 48, 201. doi:10.1016/j.carbon.2009.09.004
(18) Kormann, M.; Gerhard, H.; Popovska, N. Carbon 2009, 47, 242. doi: 10.1016/j.carbon.2008.10.002
(19) Welz, S.; McNallana, M. J.; Gogotsi, Y. J. Mater. Process. Technol. 2006, 179, 11. doi: 10.1016/j.jmatprotec.2006.03.103
(20) Sun, X. Z.; Zhang, X.; Huang, B.; Ma, Y.W. Acta Phys. -Chim. Sin. 2014, 30, 485. [孙现众, 张熊, 黄博, 马衍伟. 物理化学学报, 2014, 30, 485.] doi: 10.3866/PKU.WHXB201401131
(21) Zhai, X. L.; Song, Y.; Li, P.; Guo, Q. G.; Zhi, L. J. Chemical Research 2014, 25 (2), 112. [翟晓玲, 宋燕, 李鹏, 郭全贵, 智林杰. 化学研究, 2014, 25 (2), 112.]
(22) Zhong, H. X.; Zhao, C. B.; Luo, H.; Zhang, L. Z. Acta Phys. -Chim. Sin. 2012, 28, 2641. [仲皓想, 赵春宝, 骆浩, 张灵志. 物理化学学报, 2012, 28, 2641.] doi: 10.3866/PKU.WHXB201207181
(23) Liu, G. Y.; Zhou, A. N. Carbon 2006, 4, 27. [刘国阳, 周安宁. 炭素, 2006, 4, 27.]
(24) Sun, G.; Song,W.; Liu, X.; Qiao,W.; Long, D.; Ling, L. Mater. Lett. 2011, 65, 1392. doi: 10.1016/j.matlet.2011.02.011
(25) Jeong, M. G.; Yoon, S. H.; Chun, Y. S.; Lee, E. S.; Lim, D. S. Carbon 2014, 79, 19. doi: 10.1016/j.carbon.2014.07.016
(26) Sui, J.; Liu, X. F. Surf. Coat Technol. 2013, 235, 469.
(27) Liu, X. F.; Huang, Q. Z.; Su, Z. A.; Jiang, J. X. J. Chin. Ceram. Soc. 2004, 32 (7), 906. [刘兴防, 黄启忠, 苏哲安, 蒋建献. 硅酸盐学报, 2004, 32 (7), 906.]

[1]	Yao Chen, Cun Chen, Xuesong Cao, Zhenyu Wang, Nan Zhang, Tianxi Liu. Recent Advances in Defect and Interface Engineering for Electroreduction of CO₂ and N₂ [J]. Acta Phys. -Chim. Sin., 2023, 39(8): 2212053-0.
[2]	. Silver Nanoparticle-Modified 2D MOF Nanosheets for Photothermally Enhanced Silver Ion Release Antibacterial Treatment [J]. Acta Phys. -Chim. Sin., 2023, 39(7): 2211043-0.
[3]	Ru Wang, Zhikang Liu, Chao Yan, Long Qie, Yunhui Huang. Interface Strengthening of Composite Current Collectors for High-Safety Lithium-Ion Batteries [J]. Acta Phys. -Chim. Sin., 2023, 39(2): 2203043-0.
[4]	Wenqian He, Ya Di, Nan Jiang, Zunfeng Liu, Yongsheng Chen. Graphene-Oxide Seeds Nucleate Strong and Tough Hydrogel-Based Artificial Spider Silk [J]. Acta Phys. -Chim. Sin., 2022, 38(9): 2204059-.
[5]	Siying Zhu, Huiyang Li, Zhongli Hu, Qiaobao Zhang, Jinbao Zhao, Li Zhang. Research Progresses on Structural Optimization and Interfacial Modification of Silicon Monoxide Anode for Lithium-Ion Battery [J]. Acta Phys. -Chim. Sin., 2022, 38(6): 2103052-.
[6]	Jingsong Peng, Qunfeng Cheng. Nacre-Inspired Graphene-based Multifunctional Nanocomposites [J]. Acta Phys. -Chim. Sin., 2022, 38(5): 2005006-.
[7]	Xinrun Yu, Jun Ma, Chunbo Mou, Guanglei Cui. Percolation Structure Design of Organic-inorganic Composite Electrolyte with High Lithium-Ion Conductivity [J]. Acta Phys. -Chim. Sin., 2022, 38(3): 1912061-.
[8]	Jian Wang, Bo Yin, Tian Gao, Xingyi Wang, Wang Li, Xingxing Hong, Zhuqing Wang, Haiyong He. Reduced Graphene Oxide Modified Few-Layer Exfoliated Graphite to Enhance the Stability of the Negative Electrode of a Graphite-Based Potassium Ion Battery [J]. Acta Phys. -Chim. Sin., 2022, 38(2): 2012088-.
[9]	Mengdi Zhang, Bei Chen, Mingbo Wu. Research Progress in Graphene as Sulfur Hosts in Lithium-Sulfur Batteries [J]. Acta Phys. -Chim. Sin., 2022, 38(2): 2101001-.
[10]	Runlin Fan, Yuhang Peng, Hao Tian, Junsheng Zheng, Pingwen Ming, Cunman Zhang. Graphite-Filled Composite Bipolar Plates for Fuel Cells: Material, Structure, and Performance [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2009095-.
[11]	Xiaoqing Jia, Xiaoyu Bai, Zhezhe Ji, Yi Li, Yan Sun, Xueyue Mi, Sihui Zhan. Insight into the Effective Removal of Ciprofloxacin Using a Two-Dimensional Layered NiO/g-C₃N₄ Composite in Fe-Free Photo-Electro-Fenton System [J]. Acta Phys. -Chim. Sin., 2021, 37(8): 2010042-.
[12]	Yun Fan, Guodan Chen, Xiuan Xi, Jun Li, Qi Wang, Jingli Luo, Xianzhu Fu. Co-Generation of Ethylene and Electricity from Ethane by CeO₂/RP-PSCFM@CoFe Anode Materials in Proton Conductive Fuel Cells [J]. Acta Phys. -Chim. Sin., 2021, 37(7): 2009107-.
[13]	Yumeng Zhao, Lingxiao Ren, Aoxuan Wang, Jiayan Luo. Composite Anodes for Lithium Metal Batteries [J]. Acta Phys. -Chim. Sin., 2021, 37(2): 2008090-.
[14]	Qian Wang, Kai Wu, Hangchao Wang, Wen Liu, Henghui Zhou. Lithiophilic 3D SnS₂@Carbon Fiber Cloth for Stable Li Metal Anode [J]. Acta Phys. -Chim. Sin., 2021, 37(1): 2007092-.
[15]	Yunyun Ling, Yunsheng Xia. Gold Based Nanocomposites: Fabrication Strategies, Properties, and Tumor Theranostic Applications [J]. Acta Physico-Chimica Sinica, 2020, 36(9): 1912006-.

Preparation and Structure Regulation of Silicon Carbide-Derived Carbon/ Spherical Natural Graphite Composites

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0