卤化钙钛矿太阳能电池的缺陷容忍及缺陷钝化研究进展

doi:10.3866/PKU.WHXB202008048

Abstract

Abstract:

In less than a decade, metal halide perovskites (MHPs) have been demonstrated as promising solar cell materials because the photoelectric conversion efficiency (PCE) of the representative material CH₃NH₃PbI₃ rapidly increased from 3.8% in 2009 to 25.2% in 2009. However, defects play crucial roles in the rapid development of perovskite solar cells (PSCs) because they can influence the photovoltaic parameters of PSCs, such as the open circuit voltage, short-circuit current density, fill factor, and PCE. Among a series of superior optoelectronic properties, defect tolerance, i.e., the dominate defects are shallow and do not act as strong nonradiative recombination centers, is considered to be a unique property of MHPs, which is responsible for its surprisingly high PCE. Currently, the growth of PCE has gradually slowed, which is due to low concentrations of deep detrimental defects that can influence the performances of PSCs. To further improve the PCE and stability of PSCs, it is necessary to eliminate the impact of these minor detrimental defects in perovskites, including point defects, grain boundaries (GBs), surfaces, and interfaces, because nonradiative recombination centers seriously affect device performance, such as carrier generation and transport. Owing to its defect tolerance, most intrinsic point defects, such as V_I and V_MA, form shallow level traps in CH₃NH₃PbI₃. The structural and electronic characteristics of the charged point defect V_I_- are similar to those of the unknown donor center in a tetrahedral semiconductor. It is a harmful defect caused by a large atomic displacement and can be passivated to strengthen chemical bonds and prevent atom migration by the addition of Br atoms. Owing to the ionic nature of MHPs and high ion migration speed, there are a large number of deep detrimental defects that can migrate to the interfaces under an electric field and influence the performance of PSCs. In addition, the ionic nature of MHPs results in surface/interface dangling bonds terminated with cations or anions; thus, deep defects can be passivated through Coulomb interactions between charged ions and passivators. Hence, the de-active deep-level traps resulting from charged defects can be passivated via coordinate bonding or ionic bonding. Usually, surface-terminated anions or cations can be passivated by corresponding cations or anions through ionic bonding, and Lewis acids or bases can be passivated through coordinated bonding. In this review, we not only briefly summarize recent research progress in defect tolerance, including the soft phonon mode and polaron effect, but also strategies for defect passivation, including ionic bonding with cations or anions and coordinated bonding with Lewis acids or bases.

Key words: Defect tolerance, Defect passivation, Perovskite, Solar cell, Photoelectric conversion efficiency

Yuan Yin, Zhendong Guo, Gaoyuan Chen, Huifeng Zhang, Wan-Jian Yin. Recent Progress in Defect Tolerance and Defect Passivation in Halide Perovskite Solar Cells[J]. Acta Phys. -Chim. Sin. 2021, 37(4), 2008048. doi: 10.3866/PKU.WHXB202008048

Figures/Tables 7

References 88

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Passivators	Structures	Perovskite materials	Passivation functional groups	Target defects	V_OC	J_SC	FF	PCE	Ref.
Sodium chloride	NaCl	MAPbI₃	Na⁺	Anionic defects	23.5/24.4	1.05/1.06	0.76/0.78	18.8/20.2	60
Potassium iodide	KI	Cs_0.06FA_0.79MA_0.15Pb(I_0.85Br_0.15)₃	K⁺	Anionic defects	22.6/23.2	1.05/1.17	0.73/0.79	17.3/21.5	59
PEAI		MAPbI₃	PEA⁺	Anionic defects	19.8/18.6	0.99/1.08	0.70/0.73	13.6/14.9	61
BAI		MAPbI₃	Ammonium	Anionic defects	22.2/22.59	1.08/1.09	0.74/0.77	17.8/18.9	64
Octylammonium iodide		MAPbI₃	Ammonium	Anionic defects	21.8/22.6	1.06/1.11	0.79/0.82	18.4/20.6	65
Phenyl-C61-butyric acid methyl ester		MAPbI₃	Fullerene	PbI₃^- or V_I^-	12.7/20.3	0.98/0.98	0.59/0.75	7.3/14.9	81
C₆₀		MAPbI₃	Fullerene	PbI₃^- or V_I^-	18.4/19.6	1.04/1.07	0.72/0.69	13.6/14.5	83
Thiophene		MAPbI_3-xCl_x	Thiophene group	Pb²⁺	20.7/21.3	0.95/1.02	0.68/0.68	12.1/14.3	82
Pyridine		MAPbI_3-xCl_x	Pyridine group	Pb²⁺	20.7/24.1	0.95/1.05	0.68/0.72	12.1/15.5	85

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Recent Progress in Defect Tolerance and Defect Passivation in Halide Perovskite Solar Cells

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